The present disclosure describes fluid sets for printing, methods of textile printing, and textile printing systems. In one example, a fluid set for printing can include a pretreat composition, a fixer composition, and a white ink composition. The pretreat composition can include water and an emulsion of a silicone polymer having amino groups. The fixer composition can include a liquid vehicle and a cationic polymer. The white ink composition can include a liquid vehicle, a white pigment dispersion, and a polymeric binder.

The present disclosure describes fluid sets for printing, methods of textile printing, and textile printing systems. In one example, a fluid set for printing can include a pretreat composition, a fixer composition, and a white ink composition. The pretreat composition can include water and an emulsion of a silicone polymer having amino groups. The fixer composition can include a liquid vehicle and a cationic polymer. The white ink composition can include a liquid vehicle, a white pigment dispersion, and a polymeric binder.

The present invention provides a method of inkjet printing, comprising: (i) inkjet printing an inkjet ink on to a substrate, wherein the ink comprises: an N-vinyl monomer selected from N-vinyl caprolactam, N-vinyl pyrrolidone, N-vinyl piperidone, N-vinyl carbazole, N-vinyl formamide, N-vinyl indole, N-vinyl imidazole, N-vinyl acetamide, and mixtures thereof; one or more difunctional monomers; and a radical photoinitiator; and (ii) curing the ink by exposing the printed ink to a UV radiation source, wherein the UV radiation source moves relative to the substrate at a speed of 70 m/min or more.

The present invention provides a method of inkjet printing, comprising: (i) inkjet printing an inkjet ink on to a substrate, wherein the ink comprises: an N-vinyl monomer selected from N-vinyl caprolactam, N-vinyl pyrrolidone, N-vinyl piperidone, N-vinyl carbazole, N-vinyl formamide, N-vinyl indole, N-vinyl imidazole, N-vinyl acetamide, and mixtures thereof; one or more difunctional monomers; and a radical photoinitiator; and (ii) curing the ink by exposing the printed ink to a UV radiation source, wherein the UV radiation source moves relative to the substrate at a speed of 70 m/min or more.

Opaque grey ink jet ink composition, comprising: a solvent comprising one or more organic solvent compound(s); b) a binder, comprising one or more binding resin(s); wherein the ink jet ink composition further comprises: one or more black pigment(s) and/or one or more black dye(s); one or more white pigment(s); wherein the one or more black pigment(s) and/or the one or more black dye(s) is(are) present in a total amount from 0.01% to 9% by weight, of the total weight of the ink jet ink composition; wherein the one or more white pigment(s) is(are) present in a total amount from 0.5% to 30% by weight, of the total weight of the ink jet ink composition; and wherein the ratio:amount by weight of the one or more black pigment(s) and/or the one or more black dye(s)/amount by weight of the one or more white pigment(s) is from 0.001 to 1.

Opaque grey ink jet ink composition, comprising: a solvent comprising one or more organic solvent compound(s); b) a binder, comprising one or more binding resin(s); wherein the ink jet ink composition further comprises: one or more black pigment(s) and/or one or more black dye(s); one or more white pigment(s); wherein the one or more black pigment(s) and/or the one or more black dye(s) is(are) present in a total amount from 0.01% to 9% by weight, of the total weight of the ink jet ink composition; wherein the one or more white pigment(s) is(are) present in a total amount from 0.5% to 30% by weight, of the total weight of the ink jet ink composition; and wherein the ratio:amount by weight of the one or more black pigment(s) and/or the one or more black dye(s)/amount by weight of the one or more white pigment(s) is from 0.001 to 1.

The present invention relates to a water-based ink that exhibits excellent ejection properties, and can be prevented from suffering from reduction in a dot size of the ink during a drying step thereof even when printed on a low-water absorbing recording medium, and is capable of obtaining printed characters or images having excellent uniformity, as well as an ink-jet printing method using the water-based ink. The water-based ink includes a pigment, a water-insoluble polymer, an acetylene glycol-based nonionic surfactant (A) having HLB of not less than 0 and not more than 5, a nonionic surfactant (B) having HLB of not less than 6 and not more than 20, a polyether-modified silicone (C) having a kinematic viscosity of not less than 30 mm.sup.2/s and not more than 190 mm.sup.2/s as measured at 25° C. and an organic solvent (D), in which a weighted mean value of a boiling point of the organic solvent (D) is not lower than 150° C. and not higher than 230° C.

Provided is a metallic image forming method by which a metallic image that assumes sufficient metallic feeling can be acquired. The metallic image forming method is a method of forming a metallic image on a recording medium through use of an ink containing metal particles and includes an ink application step of applying an ink onto a recording medium having an underlayer formed thereon such that the ink overlaps at least a part of the underlayer, the underlayer having a black color or an opposite color with respect to diffusion light of the ink.

The present disclosure provides a white ink including an aqueous ink vehicle, from 5 wt % to 50 wt % of a white metal oxide pigment having an average particulate size from 100 nm to 2,000 nm, from 0.02 wt % to 2 wt % of an anionic low molecular weight polymer having a weight average molecular weight of 3,000 Mw to 50,000 Mw and an acid number higher than 100 mg KOH/g based on dry polymer weight, and from 2 wt % to 30 wt % of latex particulates having a glass transition temperature from 0 C to 130 C. Furthermore, the white metal oxide pigment is dispersed by a non-ionic or predominantly non-ionic dispersant having an acid number not higher than 100 mg KOH/g based on dry polymer weight.

The present disclosure provides a white ink including an aqueous ink vehicle, from 5 wt % to 50 wt % of a white metal oxide pigment having an average particulate size from 100 nm to 2,000 nm, from 0.02 wt % to 2 wt % of an anionic low molecular weight polymer having a weight average molecular weight of 3,000 Mw to 50,000 Mw and an acid number higher than 100 mg KOH/g based on dry polymer weight, and from 2 wt % to 30 wt % of latex particulates having a glass transition temperature from 0 C to 130 C. Furthermore, the white metal oxide pigment is dispersed by a non-ionic or predominantly non-ionic dispersant having an acid number not higher than 100 mg KOH/g based on dry polymer weight.