The present invention relates to a water-based ink containing at least pigment-containing water-insoluble crosslinked polymer particles (A), a polymer emulsion (B) and water, in which a water-insoluble crosslinked polymer constituting the crosslinked polymer particles (A) is obtained by subjecting a polymer that contains a constitutional unit derived from a carboxylic acid monomer having an acid value of not less than 200 mgKOH/g and a constitutional unit derived from a hydrophobic monomer, to crosslinking reaction with an epoxy compound, and a polymer constituting the polymer emulsion (B) contains a constitutional unit derived from a carboxylic acid monomer and a constitutional unit derived from a hydrophobic monomer. The water-based ink of the present invention is excellent in ejection stability and fastness of the printed characters or images while maintaining good optical density.

The present invention relates to a water-based ink containing at least pigment-containing water-insoluble crosslinked polymer particles (A), a polymer emulsion (B) and water, in which a water-insoluble crosslinked polymer constituting the crosslinked polymer particles (A) is obtained by subjecting a polymer that contains a constitutional unit derived from a carboxylic acid monomer having an acid value of not less than 200 mgKOH/g and a constitutional unit derived from a hydrophobic monomer, to crosslinking reaction with an epoxy compound, and a polymer constituting the polymer emulsion (B) contains a constitutional unit derived from a carboxylic acid monomer and a constitutional unit derived from a hydrophobic monomer. The water-based ink of the present invention is excellent in ejection stability and fastness of the printed characters or images while maintaining good optical density.

A pigment printing ink jet ink composition includes a pigment, a resin particle, an organic solvent, and water. The organic solvent includes an amide compound represented by the following general formula (1). ##STR00001## In the general formula (1), R.sup.1 represents a straight chain or branched alkyl group having 1 to 6 carbon atoms, and R.sup.2 and R.sup.3 each independently present hydrogen atoms or a straight chain or branched alkyl group having 1 to 4 carbon atoms.

A pigment printing ink jet ink composition includes a pigment, a resin particle, an organic solvent, and water. The organic solvent includes an amide compound represented by the following general formula (1). ##STR00001## In the general formula (1), R.sup.1 represents a straight chain or branched alkyl group having 1 to 6 carbon atoms, and R.sup.2 and R.sup.3 each independently present hydrogen atoms or a straight chain or branched alkyl group having 1 to 4 carbon atoms.

A method for obtaining copper arsenic chalcogen derived nanoparticles, including selecting a first precursor material from the group comprising copper, arsenic, antimony, bismuth, and mixtures thereof, selecting a second material from the group comprising sulfur, selenium, tellurium, and mixtures thereof, and then reacting both precursors in a solvent medium at conditions conducive to the formation of copper arsenic chalcogen derived nanoparticles.

A method for obtaining copper arsenic chalcogen derived nanoparticles, including selecting a first precursor material from the group comprising copper, arsenic, antimony, bismuth, and mixtures thereof, selecting a second material from the group comprising sulfur, selenium, tellurium, and mixtures thereof, and then reacting both precursors in a solvent medium at conditions conducive to the formation of copper arsenic chalcogen derived nanoparticles.

A recording method includes applying a white ink containing a white material and a first resin onto a predetermined region of a recording medium, and applying a reaction liquid containing a reaction agent onto at least the predetermined region. Further, the recording method includes applying a clear ink containing a second resin onto at least the predetermined region, and the application of the white ink and the clear ink are performed while the white ink and the clear ink are both wet; and/or the white ink further contains the second resin. When either the first resin and water, or the second resin and water, is mixed with an aqueous solution of magnesium sulfate, the average particle size of the first resin increases more than the second resin.

A recording method includes applying a white ink containing a white material and a first resin onto a predetermined region of a recording medium, and applying a reaction liquid containing a reaction agent onto at least the predetermined region. Further, the recording method includes applying a clear ink containing a second resin onto at least the predetermined region, and the application of the white ink and the clear ink are performed while the white ink and the clear ink are both wet; and/or the white ink further contains the second resin. When either the first resin and water, or the second resin and water, is mixed with an aqueous solution of magnesium sulfate, the average particle size of the first resin increases more than the second resin.

The ink jet printing method includes applying an aqueous coloring ink composition onto a printing surface of a printing medium by being ejected from an ink jet head. The printing surface of the printing medium contains natural fibers and synthetic fibers.

A method for producing infra-red inert substrates, including molded polymeric articles, films, fibers and coatings and other organic and inorganic materials, by incorporating into the substrate or onto the surface of the substrate an effective amount of a dispersed bis-oxodihydroindolylen-benzodifuranone colorant. The thus obtained, also claimed substrates so produced are reflective and transparent to much of the near infra red radiation not reflected. There are multiple applications for cases of devices comprising electronic components, outdoor construction elements, outdoor furniture, automotive, marine or aerospace parts, laminates, artificial leather or textile materials, as well as in polychrome printing processes and optical fibers. The thus obtained substrates can also be subjected to laser welding. New bis-oxo-dihydroindolylen-benzodifuranone compounds are also claimed.