The present invention relates to a liquid composition for ink-jet printing which is capable of forming a protective film on a liquid ejection head of an ink-jet type to enhance insulating properties for the liquid ejection head, an image-forming method, a method of forming the protective film, a storing method, and a use of the liquid composition. The present invention provides [1] a liquid composition for ink-jet printing which contains not less than 0.01% by mass and not more than 1.50% by mass of a compound represented by the following formula (1) or a salt thereof, not less than 0.05% by mass and not more than 35% by mass of a compound represented by the following formula (2), and water, [2] an ink-jet image-forming method including the step of ejecting the liquid composition for ink-jet printing according to the above [1] from a liquid ejection head of an ink-jet type including an ejection energy-generating element to form characters or images, [3] a method of forming a protective film on a liquid ejection head of an ink-jet type including an ejection energy-generating element, including the step of applying a voltage to the ejection energy-generating element under such a condition that the ejection energy-generating element is allowed to contact with the liquid composition according to the above [1], [4] a method of storing a liquid ejection head of an ink-jet type including an ejection energy-generating element, including the steps of applying a voltage to the ejection energy-generating element under such a condition that the ejection energy-generating element is allowed to contact with the liquid composition according to the above [1], and filling the liquid ejection head with an ink after the step of applying a voltage, and [5] a use of the liquid composition according to the above [1], as a filling liquid or an ink;
R.sup.1—O-(AO).sub.j(CH.sub.2CH.sub.2O).sub.n—B—COOH  (1), and
R.sup.2—O-(AO).sub.k(CH.sub.2CH.sub.2O).sub.m—H  (2).

The present invention relates to a liquid composition for ink-jet printing which is capable of forming a protective film on a liquid ejection head of an ink-jet type to enhance insulating properties for the liquid ejection head, an image-forming method, a method of forming the protective film, a storing method, and a use of the liquid composition. The present invention provides [1] a liquid composition for ink-jet printing which contains not less than 0.01% by mass and not more than 1.50% by mass of a compound represented by the following formula (1) or a salt thereof, not less than 0.05% by mass and not more than 35% by mass of a compound represented by the following formula (2), and water, [2] an ink-jet image-forming method including the step of ejecting the liquid composition for ink-jet printing according to the above [1] from a liquid ejection head of an ink-jet type including an ejection energy-generating element to form characters or images, [3] a method of forming a protective film on a liquid ejection head of an ink-jet type including an ejection energy-generating element, including the step of applying a voltage to the ejection energy-generating element under such a condition that the ejection energy-generating element is allowed to contact with the liquid composition according to the above [1], [4] a method of storing a liquid ejection head of an ink-jet type including an ejection energy-generating element, including the steps of applying a voltage to the ejection energy-generating element under such a condition that the ejection energy-generating element is allowed to contact with the liquid composition according to the above [1], and filling the liquid ejection head with an ink after the step of applying a voltage, and [5] a use of the liquid composition according to the above [1], as a filling liquid or an ink;
R.sup.1—O-(AO).sub.j(CH.sub.2CH.sub.2O).sub.n—B—COOH  (1), and
R.sup.2—O-(AO).sub.k(CH.sub.2CH.sub.2O).sub.m—H  (2).

An aqueous ink jet ink composition according to the present embodiment is an aqueous ink jet ink composition for use in an ink jet recording method that includes ejecting ink from an ink jet head. The ink jet head includes nozzles that have a side wall surface, and the side wall surface has a scalloped shape in which a scallop width S1 and a notch depth S2 satisfy S1/S2≥4. The aqueous ink jet ink composition includes a self-dispersed pigment and a solvent that includes a compound represented by formula (1) below.
R.sub.1—O—R.sub.2—OH  (1) In formula (1), R.sub.1 represents a hydrogen atom, a methyl group, or an ethyl group, and R.sub.2 represents a divalent saturated hydrocarbon group having 5 or fewer carbon atoms or represents a group represented by formula (2) below.
R.sub.3—O—R.sub.4  (2) In formula (2), R.sub.3 and R.sub.4 each independently represent a divalent saturated hydrocarbon group having 2 or 3 carbon atoms.

An aqueous ink jet ink composition according to the present embodiment is an aqueous ink jet ink composition for use in an ink jet recording method that includes ejecting ink from an ink jet head. The ink jet head includes nozzles that have a side wall surface, and the side wall surface has a scalloped shape in which a scallop width S1 and a notch depth S2 satisfy S1/S2≥4. The aqueous ink jet ink composition includes a self-dispersed pigment and a solvent that includes a compound represented by formula (1) below.
R.sub.1—O—R.sub.2—OH  (1) In formula (1), R.sub.1 represents a hydrogen atom, a methyl group, or an ethyl group, and R.sub.2 represents a divalent saturated hydrocarbon group having 5 or fewer carbon atoms or represents a group represented by formula (2) below.
R.sub.3—O—R.sub.4  (2) In formula (2), R.sub.3 and R.sub.4 each independently represent a divalent saturated hydrocarbon group having 2 or 3 carbon atoms.

An ink jet textile printing ink contains 5% by mass to 20% by mass of a water-soluble dye, water, a water-soluble organic solvent, and active carbon particles. The active carbon particles include particles having a particle size of 50 nm to 1000 nm, and the active carbon particles having the particle size of 50 nm to 1000 nm are contained in a proportion of 500 to 300000 particles per milliliter. Also, the active carbon particles may include particles having a particle size of 50 nm to 200 nm, and the active carbon particles having a particle size of 50 nm to 200 nm may be contained in a proportion of 2000 to 30000 particles per milliliter. The active carbon particles may have an average particle size in the range of 100 nm to 600 nm.

An ink jet textile printing ink contains 5% by mass to 20% by mass of a water-soluble dye, water, a water-soluble organic solvent, and active carbon particles. The active carbon particles include particles having a particle size of 50 nm to 1000 nm, and the active carbon particles having the particle size of 50 nm to 1000 nm are contained in a proportion of 500 to 300000 particles per milliliter. Also, the active carbon particles may include particles having a particle size of 50 nm to 200 nm, and the active carbon particles having a particle size of 50 nm to 200 nm may be contained in a proportion of 2000 to 30000 particles per milliliter. The active carbon particles may have an average particle size in the range of 100 nm to 600 nm.

A radiation-curable ink jet composition comprises a polymerizable compound component including a monofunctional monomer component and a multifunctional monomer component. The content of the monofunctional monomer component is 87 mass % or more based on the total amount of the polymerizable compound component, the monofunctional monomer component includes a monofunctional acrylate containing a polycyclic hydrocarbon group, and the weighted average of the glass transition temperatures of homopolymers of the respective polymerizable compounds is 42° C. or more when the mass ratios of the contents of the respective polymerizable compounds are weighted.

A radiation-curable ink jet composition comprises a polymerizable compound component including a monofunctional monomer component and a multifunctional monomer component. The content of the monofunctional monomer component is 87 mass % or more based on the total amount of the polymerizable compound component, the monofunctional monomer component includes a monofunctional acrylate containing a polycyclic hydrocarbon group, and the weighted average of the glass transition temperatures of homopolymers of the respective polymerizable compounds is 42° C. or more when the mass ratios of the contents of the respective polymerizable compounds are weighted.

Provided is an aqueous ink for ink jet that can record an image excellent in a color developability by suppressing a bronze phenomenon derived from a carbon black. The aqueous ink for ink jet contains: a self-dispersible carbon black; and a resin particle formed of an acrylic resin. The carbon black has a DBP oil absorption of 120 mL/100 g or more, the acrylic resin particle has a glass transition temperature of 30° C. or more, and a mass ratio of a content (% by mass) of the resin particle to a content (% by mass) of the carbon black is 0.10 times or more to 2.0 times or less.

Provided is an aqueous ink for ink jet that can record an image excellent in a color developability by suppressing a bronze phenomenon derived from a carbon black. The aqueous ink for ink jet contains: a self-dispersible carbon black; and a resin particle formed of an acrylic resin. The carbon black has a DBP oil absorption of 120 mL/100 g or more, the acrylic resin particle has a glass transition temperature of 30° C. or more, and a mass ratio of a content (% by mass) of the resin particle to a content (% by mass) of the carbon black is 0.10 times or more to 2.0 times or less.