Patent classifications
C09D11/324
Preparation and applications of biocompatible conductive inks based on cellulose nanofibrils for 3D printing of conductive biomedical devices and for use as models for study of neurodegenerative disorders and connection between brain/neurons and communication or other electronic devices
The present invention relates to preparation and use of nanocellulose fibrils or crystals such as disintegrated bacterial nanocellulose, tunicate-derived nanocellulose, or plant-derived nanocellulose, together with carbon nanotubes, as a biocompatible and conductive ink for 3D printing of electrically conductive patterns. Biocompatible conductive bioinks described in this invention were printed in the form of connected lines onto wet or dried nanocellulose films, bacterial cellulose membrane, or tunicate decellularized tissue. The devices were biocompatible and showed excellent mechanical properties and good electrical conductivity through printed lines (3.8.Math.10.sup.1 S cm.sup.1). Such scaffolds were used to culture neural cells. Neural cells attached selectively on the printed pattern and formed connective networks. The devices prepared by this invention are suited as bioassays to screen drugs against neurodegenerative diseases such as Alzheimer's and Parkinson's, study brain function, and/or be used to link the human brain with electronic and/or communication devices. They can also be implanted to replace neural tissue or stimulate guiding of neural cells. They can also be used to stimulate the heart by using electrical signaling or to repair myocardial infarction and/or damage related thereto.
Preparation and applications of biocompatible conductive inks based on cellulose nanofibrils for 3D printing of conductive biomedical devices and for use as models for study of neurodegenerative disorders and connection between brain/neurons and communication or other electronic devices
The present invention relates to preparation and use of nanocellulose fibrils or crystals such as disintegrated bacterial nanocellulose, tunicate-derived nanocellulose, or plant-derived nanocellulose, together with carbon nanotubes, as a biocompatible and conductive ink for 3D printing of electrically conductive patterns. Biocompatible conductive bioinks described in this invention were printed in the form of connected lines onto wet or dried nanocellulose films, bacterial cellulose membrane, or tunicate decellularized tissue. The devices were biocompatible and showed excellent mechanical properties and good electrical conductivity through printed lines (3.8.Math.10.sup.1 S cm.sup.1). Such scaffolds were used to culture neural cells. Neural cells attached selectively on the printed pattern and formed connective networks. The devices prepared by this invention are suited as bioassays to screen drugs against neurodegenerative diseases such as Alzheimer's and Parkinson's, study brain function, and/or be used to link the human brain with electronic and/or communication devices. They can also be implanted to replace neural tissue or stimulate guiding of neural cells. They can also be used to stimulate the heart by using electrical signaling or to repair myocardial infarction and/or damage related thereto.
THERMAL INKJET DYE SUBLIMATION INKS
A thermal inkjet dye sublimation ink consists of a disperse dye colorant dispersion, a co-solvent system, an additive, and a balance of water. The colorant dispersion is present in an amount ranging from about 1 wt % actives to about 7 wt % actives. The co-solvent system is present in a total amount ranging from about 12 wt % to about 25 wt %. The co-solvent system consists of glycerol present in an amount ranging from about 9 wt % to about 16 wt %, ethoxylated glycerol present in an amount ranging from 0 wt % to about 5 wt %, and a water soluble or water miscible organic solvent present in an amount ranging from 0 wt % to about 7 wt %. The additive is selected from the group consisting of a surfactant, a chelating agent, a buffer, a biocide, and combinations thereof.
THERMAL INKJET DYE SUBLIMATION INKS
A thermal inkjet dye sublimation ink consists of a disperse dye colorant dispersion, a co-solvent system, an additive, and a balance of water. The colorant dispersion is present in an amount ranging from about 1 wt % actives to about 7 wt % actives. The co-solvent system is present in a total amount ranging from about 12 wt % to about 25 wt %. The co-solvent system consists of glycerol present in an amount ranging from about 9 wt % to about 16 wt %, ethoxylated glycerol present in an amount ranging from 0 wt % to about 5 wt %, and a water soluble or water miscible organic solvent present in an amount ranging from 0 wt % to about 7 wt %. The additive is selected from the group consisting of a surfactant, a chelating agent, a buffer, a biocide, and combinations thereof.
Aqueous carbon nanoparticle ink composition for resistors
Aqueous ink compositions and methods for fabricating a resistive material for a printed circuit are provided. The aqueous ink composition may include an aqueous solvent, one or more carbon nanoparticles, and one or more cellulose nanocrystals. The one or more carbon nanoparticles may include carbon nanotubes, such as multi-walled nanotubes, and the one or more cellulose nanocrystals may include cellulose nanocrystals functionalized with carboxylate groups.
Three-dimensional printing method
Disclosed herein is a three-dimensional printing method comprising: applying a build material; applying on, at least, a portion of the build material, a low tint fusing agent composition comprising metal oxide nanoparticles dispersed in a liquid vehicle; and exposing the build material to radiations to fuse the portion of the build material in contact with the low tint fusing agent composition in order to form a layer of a 3D object. Also disclosed herein is an article obtained according to the three-dimensional printing method described herein. Such articles comprises a core substrate made of a polymeric build material that has been fused with a core fusing agent composition; a first layer, applied on the surface of the core substrate, comprising a polymeric build material fused with a low tint fusing agent composition including metal oxide nanoparticles dispersed in a liquid vehicle; and a second layer, applied over the surface of the first layer, comprising a polymeric build material fused with a colored ink composition and a core fusing agent or with a low tint fusing agent composition colored ink composition.
Three-dimensional printing method
Disclosed herein is a three-dimensional printing method comprising: applying a build material; applying on, at least, a portion of the build material, a low tint fusing agent composition comprising metal oxide nanoparticles dispersed in a liquid vehicle; and exposing the build material to radiations to fuse the portion of the build material in contact with the low tint fusing agent composition in order to form a layer of a 3D object. Also disclosed herein is an article obtained according to the three-dimensional printing method described herein. Such articles comprises a core substrate made of a polymeric build material that has been fused with a core fusing agent composition; a first layer, applied on the surface of the core substrate, comprising a polymeric build material fused with a low tint fusing agent composition including metal oxide nanoparticles dispersed in a liquid vehicle; and a second layer, applied over the surface of the first layer, comprising a polymeric build material fused with a colored ink composition and a core fusing agent or with a low tint fusing agent composition colored ink composition.
Water-based ink for ink-jet recording
There is provided a water-based ink for ink-jet recording including: a self-dispersible black pigment; a resin-dispersed chromatic pigment including a resin-dispersed magenta pigment and a resin-dispersed cyan pigment; and water. A ratio (Col/Bk) of a solid content mass (Col) of the resin-dispersed chromatic pigment to a solid content mass (Bk) of the self-dispersible black pigment is in a range of 0.24 to 0.73 and a mean particle diameter of the self-dispersible black pigment is greater than a mean particle diameter of the resin-dispersed chromatic pigment.
Water-based ink for ink-jet recording
There is provided a water-based ink for ink-jet recording including: a self-dispersible black pigment; a resin-dispersed chromatic pigment including a resin-dispersed magenta pigment and a resin-dispersed cyan pigment; and water. A ratio (Col/Bk) of a solid content mass (Col) of the resin-dispersed chromatic pigment to a solid content mass (Bk) of the self-dispersible black pigment is in a range of 0.24 to 0.73 and a mean particle diameter of the self-dispersible black pigment is greater than a mean particle diameter of the resin-dispersed chromatic pigment.
RADIATION-CURABLE INK JET COMPOSITION AND RECORDING METHOD
A radiation-curable ink jet composition comprises a polymerizable compound component including a monofunctional monomer component and a multifunctional monomer component. The content of the monofunctional monomer component is 87 mass % or more based on the total amount of the polymerizable compound component, the monofunctional monomer component includes a monofunctional acrylate containing a polycyclic hydrocarbon group, and the weighted average of the glass transition temperatures of homopolymers of the respective polymerizable compounds is 42 C. or more when the mass ratios of the contents of the respective polymerizable compounds are weighted.