Composite particles contained in an ink are particles of a composite of a polyester resin including a sulfonic acid group and a basic dye. The polyester resin has a glass transition point of 40° C. to 70° C. The polyester resin includes a first repeating unit derived from a polyvalent carboxylic acid having the sulfonic acid group, a second repeating unit derived from a polyvalent carboxylic acid having no sulfonic acid group, and a third repeating unit derived from a polyhydric alcohol. The content ratio of the first repeating unit relative to the total amount of the first repeating unit and the second repeating unit is at least 1.5 mol % and no greater than 20.0 mol %. The mass ratio of the polyester resin to the basic dye is at least 1.0 and no greater than 10.0.

A system for applying a first and a second coating composition is provided herein. The system includes a first high transfer efficiency applicator defining a first nozzle orifice and a second high transfer efficiency applicator defining a second nozzle orifice. The system further includes a first reservoir a second reservoir. The system further includes a substrate defining a first target area and a second target area. The first high transfer efficiency applicator is configured to receive the first coating composition from the first reservoir and configured to expel the first coating composition through the first nozzle orifice to the first target area of the substrate. The second high transfer efficiency applicator is configured to receive the second coating composition from the second reservoir and configured to expel the second coating composition through the second nozzle orifice to the second target area of the substrate.

A system for applying a first and a second coating composition is provided herein. The system includes a first high transfer efficiency applicator defining a first nozzle orifice and a second high transfer efficiency applicator defining a second nozzle orifice. The system further includes a first reservoir a second reservoir. The system further includes a substrate defining a first target area and a second target area. The first high transfer efficiency applicator is configured to receive the first coating composition from the first reservoir and configured to expel the first coating composition through the first nozzle orifice to the first target area of the substrate. The second high transfer efficiency applicator is configured to receive the second coating composition from the second reservoir and configured to expel the second coating composition through the second nozzle orifice to the second target area of the substrate.

A black ink composition for inkjet printing that contains a water-soluble organic solvent, a resin emulsion, a dispersing agent, and at least four types of sublimation dyes. At least three of the sublimation dye types are C.I. disperse yellow, C.I. disperse red, and C.I. disperse blue, and at least one of the sublimation dye types has a maximum absorption wavelength in the wavelength band of 640 nm to less than 680 nm as measured from a visible spectral absorption of a solution obtained by dissolving the dye in acetone. An ink set for inkjet printing that includes the black ink composition for inkjet printing, and a method for printing on hydrophobic fibers that uses the composition and the ink set.

A black ink composition for inkjet printing that contains a water-soluble organic solvent, a resin emulsion, a dispersing agent, and at least four types of sublimation dyes. At least three of the sublimation dye types are C.I. disperse yellow, C.I. disperse red, and C.I. disperse blue, and at least one of the sublimation dye types has a maximum absorption wavelength in the wavelength band of 640 nm to less than 680 nm as measured from a visible spectral absorption of a solution obtained by dissolving the dye in acetone. An ink set for inkjet printing that includes the black ink composition for inkjet printing, and a method for printing on hydrophobic fibers that uses the composition and the ink set.

An ink jet ink for textile printing contains a reactive dye, where 1.2% by mass or more and 2.3% by mass or less of C.I. Reactive Blue 49 based on the total amount of the ink is contained as the reactive dye.

An ink jet ink for textile printing contains a reactive dye, where 1.2% by mass or more and 2.3% by mass or less of C.I. Reactive Blue 49 based on the total amount of the ink is contained as the reactive dye.

Provided is an ink jet recording method by which even when an ink jet recording apparatus having a small size and high durability is used, excellent sticking recoverability is obtained and a high-quality image suppressed from causing unevenness can be recorded. The ink jet recording method includes recording an image with an ink jet recording apparatus including: a plurality of aqueous inks; a first ink storage portion; a second ink storage portion; a plurality of tubes; a recording head; and a recovery mechanism. The ratio (η.sub.2/η.sub.1) of the viscosity η.sub.2 (mPa.Math.s) of the second ink to the viscosity η.sub.1 (mPa.Math.s) of the first ink is 0.7 or more to 1.5 or less, and the first ink contains a first water-soluble organic solvent having a specific dielectric constant of 40.0 or more.

Provided is an ink jet recording method by which even when an ink jet recording apparatus having a small size and high durability is used, excellent sticking recoverability is obtained and a high-quality image suppressed from causing unevenness can be recorded. The ink jet recording method includes recording an image with an ink jet recording apparatus including: a plurality of aqueous inks; a first ink storage portion; a second ink storage portion; a plurality of tubes; a recording head; and a recovery mechanism. The ratio (η.sub.2/η.sub.1) of the viscosity η.sub.2 (mPa.Math.s) of the second ink to the viscosity η.sub.1 (mPa.Math.s) of the first ink is 0.7 or more to 1.5 or less, and the first ink contains a first water-soluble organic solvent having a specific dielectric constant of 40.0 or more.

A method of forming a coating composition for application to a substrate utilizing a high efficiency transfer applicator. The method includes identifying at least one of an Ohnesorge number (Oh) for the coating composition, a Reynolds number (Re) for the coating composition, or a Deborah number (De) for the coating composition. The method includes obtaining at least one of a viscosity (η) of the coating composition, a surface tension (σ) of the coating composition, a density (ρ) of the coating composition, a relaxation time (λ) of the coating composition, a nozzle diameter (D) of the high efficiency transfer applicator, or an impact velocity (v) of the high efficiency transfer applicator. The method includes forming the coating composition having at least one of the viscosity (η), the surface tension (σ), or the density (ρ). The coating composition is configured to be applied to the substrate utilizing the high efficiency transfer applicator having at least one of the nozzle diameter (D) or the impact velocity (v).