A reactive dye of formula

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wherein M is hydrogen, an alkali metal or one equivalent of an alkaline earth metal, Z.sub.1 is vinyl, β-sulfatoethyl or the radical —NHCO—(CH.sub.2).sub.3—SO.sub.2—CH.sub.2CH.sub.2Cl; R.sub.1 denotes H or sulfo; and R.sub.2 is H, methyl, methoxy or sulfo, n is the number 3; Y is vinyl or a radical —CH.sub.2—CH.sub.2-U and U is —Cl or —OSO.sub.3H,
is suitable for dyeing and printing cellulosic or amide-group-containing fibre materials.

Described herein are printing inks that are safe for direct contact with food. The inks contain colorants and other substances which comply with regulations governing the amounts of substances determined to be safe in the event one or more of the ink-containing substances were to migrate into foods or beverages, The inks exhibit resistance to removal. Also described are sets of inks. The inks provide wide color gamut.

Described herein are printing inks that are safe for direct contact with food. The inks contain colorants and other substances which comply with regulations governing the amounts of substances determined to be safe in the event one or more of the ink-containing substances were to migrate into foods or beverages, The inks exhibit resistance to removal. Also described are sets of inks. The inks provide wide color gamut.

An aqueous ink jet composition includes a first component which is at least one selected from the group consisting of C.I. Solvent Yellow 160: 1, C.I. Disperse Yellow 82, and C.I. Disperse Yellow 184; a second component which is a dispersant having at least one chemical structure of a sulfo group and a salt thereof; and a third component which has a coumarin skeleton and at least one chemical structure of a sulfo group and a salt thereof.

An aqueous ink jet composition includes a first component which is at least one selected from the group consisting of C.I. Solvent Yellow 160: 1, C.I. Disperse Yellow 82, and C.I. Disperse Yellow 184; a second component which is a dispersant having at least one chemical structure of a sulfo group and a salt thereof; and a third component which has a coumarin skeleton and at least one chemical structure of a sulfo group and a salt thereof.

In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprises up to 80 wt. % oligomeric curable material; up to 80 wt. % monomeric curable material; up to 10 wt. % photoinitiator; up to 1 wt. % non-curable absorber material; and up to 10 wt. % one or more additional components, based on the total weight of the ink, and wherein the total amount of the foregoing components is equal to 100 wt. %. Additionally, the photoinitiator is operable to initiate curing of the oligomeric curable material and/or the monomeric curable material when the photoinitiator is exposed to incident curing radiation having a peak wavelength λ. Moreover, the ink has a penetration depth (D.sub.p), a critical energy (E.sub.c), and a print through depth (D.sub.PT) at the wavelength λ of less than or equal to 2×D.sub.p.

In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprises up to 80 wt. % oligomeric curable material; up to 80 wt. % monomeric curable material; up to 10 wt. % photoinitiator; up to 1 wt. % non-curable absorber material; and up to 10 wt. % one or more additional components, based on the total weight of the ink, and wherein the total amount of the foregoing components is equal to 100 wt. %. Additionally, the photoinitiator is operable to initiate curing of the oligomeric curable material and/or the monomeric curable material when the photoinitiator is exposed to incident curing radiation having a peak wavelength λ. Moreover, the ink has a penetration depth (D.sub.p), a critical energy (E.sub.c), and a print through depth (D.sub.PT) at the wavelength λ of less than or equal to 2×D.sub.p.

Provided are an ink composition for ink jet printing, and an image forming method and a recorded material using the ink composition for ink jet printing. The ink composition for ink jet printing includes: a colorant represented by the following Formula 1; resin particles; a water-soluble organic solvent; and water. In Formula 1, Y.sup.1 and Y.sup.2 each independently represent a non-metal atomic group which forms an aliphatic ring or a heterocycle, M.sup.+ represents a proton or a monovalent alkali metal cation or organic cation, L.sup.1 represents a methine chain consisting of 5 or 7 methine groups, and a methine group at a center of the methine chain has a specific substituent. ##STR00001##

A water-based ink for ink-jet recording includes dyes and water. The dyes include a blue dye having a hue angle of 220° to 280°; a yellow dye having a hue angle of 70° to 120°; and a copper phthalocyanine dye. A mass ratio (C/B) of a content (C) of the copper phthalocyanine dye to a content (B) of the blue dye in an entire amount of the water-based ink is equal to or more than 0.5, and a total content of the dyes in the entire amount of the water-based ink is equal to or more than 6% by mass.

A water-based ink for ink-jet recording includes dyes and water. The dyes include a blue dye having a hue angle of 220° to 280°; a yellow dye having a hue angle of 70° to 120°; and a copper phthalocyanine dye. A mass ratio (C/B) of a content (C) of the copper phthalocyanine dye to a content (B) of the blue dye in an entire amount of the water-based ink is equal to or more than 0.5, and a total content of the dyes in the entire amount of the water-based ink is equal to or more than 6% by mass.