The present application relates to the technical field of floor surface decoration materials, and particularly provides a multi-coating radiation-cured pre-coating film and a preparation method therefor. The first aspect of the present application provides the multi-coating radiation-cured pre-coating film, which sequentially comprises a flexible transparent film layer and a radiation-cured coating from bottom to top, wherein the radiation-cured coating sequentially comprises a radiation-cured elastic primer layer and a radiation-cured wear-resistant finish paint layer from bottom to top, the at least one radiation-cured elastic primer layer and the at least one radiation-cured wear-resistant finish paint layer are arranged, and the radiation-cured elastic primer layer equentially comprises a radiation-cured elastic wear-resistant primer layer and a radiation-cured elastic matte/bright primer layer from bottom to top.

The present application relates to the technical field of floor surface decoration materials, and particularly provides a multi-coating radiation-cured pre-coating film and a preparation method therefor. The first aspect of the present application provides the multi-coating radiation-cured pre-coating film, which sequentially comprises a flexible transparent film layer and a radiation-cured coating from bottom to top, wherein the radiation-cured coating sequentially comprises a radiation-cured elastic primer layer and a radiation-cured wear-resistant finish paint layer from bottom to top, the at least one radiation-cured elastic primer layer and the at least one radiation-cured wear-resistant finish paint layer are arranged, and the radiation-cured elastic primer layer equentially comprises a radiation-cured elastic wear-resistant primer layer and a radiation-cured elastic matte/bright primer layer from bottom to top.

Disclosed herein are self-healing oligomers according to the structure [UPy-(D.sub.m-U-D.sub.m)(.sub.2+q)]-[A(G)(.sub.n−1)-D.sub.m].sub.k-Z; wherein UPy, D, m, U, q, A, G, n, k, and Z are defined and described further herein, and wherein the oligomer possesses at least 3 urethane linking groups and comprises a backbone derived from a polyether polyol, a polyester polyol, a poly(dimethylsiloxane), a disulfide polyol, or combinations thereof. Also described and claimed are various compositions containing such oligomers as part of a self-healing component, wherein such compositions also include an optional reactive monomer and/or oligomer component and a photoinitiator component. Yet further described and claimed are articles cured from the compositions elsewhere described using the oligomers elsewhere described.

[Problem] To provide a radiation curable resin composition that is suitable as a primary material of an optical fiber and has a fast curing rate by irradiation with radiation.

[Solution] A radiation polymerizable composition for forming a primary coating layer of an optical fiber, the radiation polymerizable composition comprising: (A) a urethane oligomer comprising a structure represented by formula (I) below:

##STR00001## wherein R is a vinyl group and * is a bond; (B) one or more compounds of: (i) maleic anhydride, (ii) a compound represented by formula (II):

##STR00002## wherein R.sup.1 is a single bond or an alkanediyl group comprising 1 to 6 carbon atoms, and R.sup.2 is a hydrogen atom, a hydroxy group, or a group represented by predetermined formula (II-1) or formula (II-2), or (iii) a compound represented by formula (III):

##STR00003## wherein R.sup.5 is an alkanediyl group comprising 1 to 6 carbon atoms; and (C) a radiation polymerization initiator.

[Problem] To provide a radiation curable resin composition that is suitable as a primary material of an optical fiber and has a fast curing rate by irradiation with radiation.

[Solution] A radiation polymerizable composition for forming a primary coating layer of an optical fiber, the radiation polymerizable composition comprising: (A) a urethane oligomer comprising a structure represented by formula (I) below:

##STR00001## wherein R is a vinyl group and * is a bond; (B) one or more compounds of: (i) maleic anhydride, (ii) a compound represented by formula (II):

##STR00002## wherein R.sup.1 is a single bond or an alkanediyl group comprising 1 to 6 carbon atoms, and R.sup.2 is a hydrogen atom, a hydroxy group, or a group represented by predetermined formula (II-1) or formula (II-2), or (iii) a compound represented by formula (III):

##STR00003## wherein R.sup.5 is an alkanediyl group comprising 1 to 6 carbon atoms; and (C) a radiation polymerization initiator.

A two-component coating composition comprising at least one water-dispersible polymer mixture (A) which has at least one mercapto-reactive group selected from the group of epoxide and Michael acceptor, and also at least one water-emulsifiable thiol (B) comprising, as formation components, (Ba) at least one compound having at least two mercapto groups, (Bb) at least one compound having at least one mercapto-reactive group and at least one dispersing group, wherein the formation component (Ba) has a Hansch parameter of at least 2.0.

Curable compositions comprising a urethane multifunctional (meth)acrylate, a photo initiator system, a moisture-cure initiator, and an oligomer, where the oligomer is represented by the formula (I) where each X.sup.1 is independently alkylene; each X.sup.2 is independently alkylene, polyether, polyester, or polyurethane; R.sup.1 is a (meth)acrylate; R.sup.2 is urethane or isocyanate; and R.sup.3 alkylene (meth)acrylate, polyester (meth)acrylate, polyether, polyester, polyurethane, or nothing, and where the ratio of (meth)acrylate to isocyanate in the oligomer is 1:1 to 1:2. Methods of making curable compositions, methods of sealing a substrate, and methods of adhering two substrates are provided.

##STR00001##

Curable compositions comprising a urethane multifunctional (meth)acrylate, a photo initiator system, a moisture-cure initiator, and an oligomer, where the oligomer is represented by the formula (I) where each X.sup.1 is independently alkylene; each X.sup.2 is independently alkylene, polyether, polyester, or polyurethane; R.sup.1 is a (meth)acrylate; R.sup.2 is urethane or isocyanate; and R.sup.3 alkylene (meth)acrylate, polyester (meth)acrylate, polyether, polyester, polyurethane, or nothing, and where the ratio of (meth)acrylate to isocyanate in the oligomer is 1:1 to 1:2. Methods of making curable compositions, methods of sealing a substrate, and methods of adhering two substrates are provided.

##STR00001##

A nail sticker, a composition for the nail sticker and a method for preparing the composition are disclosed. Raw materials of the composition include a sizing material, which is made of the following raw materials in parts by weight: 45-85 parts of a UV thermosetting resin, 2-9 parts of a photoinitiator, 1.5-2 parts of a curing agent, 0.1-1 part of a thermal promoter, and 0.1-1 part of a leveling agent. The synchronization of the release of essential oil molecules with light/thermal curing promotes the essential oil molecules to be diffused to the interior of the sizing material more uniformly in a wider range, and during the curing and film forming of the nail sticker, an aroma spreads as tantalizing as that of baked food.

The present invention relates to a protective film for a windshield of a vehicle, which can be installed on a curved portion of the windshield of the vehicle without a thermoforming process, thereby improving the workability of a worker, and improving impact resistance to effectively protect the windshield of the vehicle.