An adhesive composition is comprised of a film forming polymer, (ii) a lower crystallinity polynitroso compound, (e.g., poly-(1,4-phenylyenazine-N,N-dioxide)), (iii) a higher crystallinity polynitroso compound (e.g., poly-(1,4-phenylyenazine-N,N-dioxide)), and (iv) a carrier liquid. The composition is useful in bonding metal and rubber to make, for example, components to damp noise, vibration or harshness.

An adhesive composition is comprised of a film forming polymer, (ii) a lower crystallinity polynitroso compound, (e.g., poly-(1,4-phenylyenazine-N,N-dioxide)), (iii) a higher crystallinity polynitroso compound (e.g., poly-(1,4-phenylyenazine-N,N-dioxide)), and (iv) a carrier liquid. The composition is useful in bonding metal and rubber to make, for example, components to damp noise, vibration or harshness.

An adhesive composition is comprised of a film forming polymer, (ii) a lower crystallinity polynitroso compound, (e.g., poly-(1,4-phenylyenazine-N,N-dioxide)), (iii) a higher crystallinity polynitroso compound (e.g., poly-(1,4-phenylyenazine-N,N-dioxide)), and (iv) a carrier liquid. The composition is useful in bonding metal and rubber to make, for example, components to damp noise, vibration or harshness.

A two part adhesive system is provided with the first part being a substrate-adhesive containing at least one of a urethane, an acrylic, or an epoxy based adhesive and the second part being an elastomer-primer comprising a halogenated polyolefin and, optionally a nitroso compound. Further provided is a method of post-vulcanization bonding of an elastomer to a substrate employing the adhesive outlined above.

A two part adhesive system is provided with the first part being a substrate-adhesive containing at least one of a urethane, an acrylic, or an epoxy based adhesive and the second part being an elastomer-primer comprising a halogenated polyolefin and, optionally a nitroso compound. Further provided is a method of post-vulcanization bonding of an elastomer to a substrate employing the adhesive outlined above.

A water-based adhesive film-forming cover composition including: (i) at least one film forming polymer; (ii) at least one lower crystallinity first polynitroso compound; (iii) at least one higher crystallinity second polynitroso compound; (iv) at least one crosslinking agent; and (v) water as a carrier liquid; a bonding system including a combination of: (a) a water-based primer component; and (b) the above water-based cover component; a process for manufacturing the above bonding system; and a process of manufacturing a bonded article with the above bonding system. A bonded article, having a bonding line made from the above bonding system disposed between metal and rubber substrates, exhibits excellent stability against an aqueous urea-solution at temperatures of up to about 95? C.

A water-based adhesive film-forming cover composition including: (i) at least one film forming polymer; (ii) at least one lower crystallinity first polynitroso compound; (iii) at least one higher crystallinity second polynitroso compound; (iv) at least one crosslinking agent; and (v) water as a carrier liquid; a bonding system including a combination of: (a) a water-based primer component; and (b) the above water-based cover component; a process for manufacturing the above bonding system; and a process of manufacturing a bonded article with the above bonding system. A bonded article, having a bonding line made from the above bonding system disposed between metal and rubber substrates, exhibits excellent stability against an aqueous urea-solution at temperatures of up to about 95? C.

A chlorosulfonated polyethylene latex, which is safe for living bodies and the environment and can be used as a latex component in a resorcin-formalin-latex adhesive, contains an aqueous dispersion medium, chlorosulfonated polyethylene, and an emulsifying agent of a polyoxyalkylene alkyl ether sulfate of formula (I) below and a fatty acid salt. The latex is excellent in standing stability and mechanical stability. In formula (I), R.sup.1, R.sup.2, n, and M represent an alkyl group of 6 to 20 carbon atoms, hydrogen or a methyl group, an integer of 2 to 40, and an alkali metal, respectively.
R.sup.1O(CH.sub.2CHR.sup.2O).sub.nSO.sub.3M(I)

A chlorosulfonated polyethylene latex, which is safe for living bodies and the environment and can be used as a latex component in a resorcin-formalin-latex adhesive, contains an aqueous dispersion medium, chlorosulfonated polyethylene, and an emulsifying agent of a polyoxyalkylene alkyl ether sulfate of formula (I) below and a fatty acid salt. The latex is excellent in standing stability and mechanical stability. In formula (I), R.sup.1, R.sup.2, n, and M represent an alkyl group of 6 to 20 carbon atoms, hydrogen or a methyl group, an integer of 2 to 40, and an alkali metal, respectively.
R.sup.1O(CH.sub.2CHR.sup.2O).sub.nSO.sub.3M(I)

A chlorosulfonated polyethylene latex, which is safe for living bodies and the environment and can be used as a latex component in a resorcin-formalin-latex adhesive, contains an aqueous dispersion medium, chlorosulfonated polyethylene, and an emulsifying agent of a polyoxyalkylene alkyl ether sulfate of formula (I) below and a fatty acid salt. The latex is excellent in standing stability and mechanical stability. In formula (I), R.sup.1, R.sup.2, n, and M represent an alkyl group of 6 to 20 carbon atoms, hydrogen or a methyl group, an integer of 2 to 40, and an alkali metal, respectively.
R.sup.1O(CH.sub.2CHR.sup.2O).sub.nSO.sub.3M(I)