Described herein is a pressure sensitive adhesive comprising a high molecular weight fluorinated polymer having a Tg less than about 0 C. and a number average molecular weight greater than about 20 kilograms/mole; and a low molecular weight fluorinated polymer derived from an ethylenically unsaturated fluorinated monomer, wherein the low molecular weight fluorinated polymer has a Tg greater than about 15 C. and a number average molecular weight less than about 18 kilograms/mole. Also described herein are articles comprising the pressure sensitive adhesive composition.

Described herein is a pressure sensitive adhesive comprising a high molecular weight fluorinated polymer having a Tg less than about 0 C. and a number average molecular weight greater than about 20 kilograms/mole; and a low molecular weight fluorinated polymer derived from an ethylenically unsaturated fluorinated monomer, wherein the low molecular weight fluorinated polymer has a Tg greater than about 15 C. and a number average molecular weight less than about 18 kilograms/mole. Also described herein are articles comprising the pressure sensitive adhesive composition.

Described herein is a pressure sensitive adhesive comprising a high molecular weight fluorinated polymer having a Tg less than about 0 C. and a number average molecular weight greater than about 20 kilograms/mole; and a low molecular weight fluorinated polymer derived from an ethylenically unsaturated fluorinated monomer, wherein the low molecular weight fluorinated polymer has a Tg greater than about 15 C. and a number average molecular weight less than about 18 kilograms/mole. Also described herein are articles comprising the pressure sensitive adhesive composition.

Copolymers of one or more halogenated olefins and one or more halogenated co-monomers selected from the group consisting of halogenated alkenyl ethers, halogenated alkenyl esters, and halogenated (meth)acrylates are useful in various end-use applications wherein the presence of halogen (e.g., fluorine) in the copolymer imparts one or more desirable properties, as compared to analogous copolymers not containing halogen.

A separator for a non-aqueous secondary battery, the separator including: a porous substrate; and an adhesive porous layer provided on one or both sides of the porous substrate and including a polyvinylidene fluoride-based resin, the adhesive porous layer would exhibit a ratio of an area intensity of a -phase-crystal-derived peak of the polyvinylidene fluoride-based resin to a sum of an area intensity of an -phase-crystal-derived peak of the polyvinylidene fluoride-based resin and the area intensity of the -phase-crystal-derived peak of the polyvinylidene fluoride-based resin of from 10% to 100% when an x-ray diffraction spectrum is obtained by performing measurement by an x-ray diffraction method.

A separator for a non-aqueous secondary battery, the separator including: a porous substrate; and an adhesive porous layer provided on one or both sides of the porous substrate and including a polyvinylidene fluoride-based resin, the adhesive porous layer would exhibit a ratio of an area intensity of a -phase-crystal-derived peak of the polyvinylidene fluoride-based resin to a sum of an area intensity of an -phase-crystal-derived peak of the polyvinylidene fluoride-based resin and the area intensity of the -phase-crystal-derived peak of the polyvinylidene fluoride-based resin of from 10% to 100% when an x-ray diffraction spectrum is obtained by performing measurement by an x-ray diffraction method.

A separator for a non-aqueous secondary battery, the separator including: a porous substrate; and an adhesive porous layer provided on one or both sides of the porous substrate and including a polyvinylidene fluoride-based resin, the adhesive porous layer would exhibit a ratio of an area intensity of a -phase-crystal-derived peak of the polyvinylidene fluoride-based resin to a sum of an area intensity of an -phase-crystal-derived peak of the polyvinylidene fluoride-based resin and the area intensity of the -phase-crystal-derived peak of the polyvinylidene fluoride-based resin of from 10% to 100% when an x-ray diffraction spectrum is obtained by performing measurement by an x-ray diffraction method.

An adhesive suitable for use in security documents (for example, currency, passports, tickets, etc.) includes a plurality of polymers, that collectively exhibit tackification, resistance to aqueous agents, and solvent resistance, and a cross-linker selected to be activated to chemically react with one or more polymers of the plurality of polymers, at a temperature in a predetermined range of temperatures.

An adhesive suitable for use in security documents (for example, currency, passports, tickets, etc.) includes a plurality of polymers, that collectively exhibit tackification, resistance to aqueous agents, and solvent resistance, and a cross-linker selected to be activated to chemically react with one or more polymers of the plurality of polymers, at a temperature in a predetermined range of temperatures.

A separator for a rechargeable battery includes a porous substrate and an adhesive layer on at least one surface thereof. The adhesive layer includes a first binder, a second binder, and a filler. The first binder includes a structural unit derived from vinylidene fluoride and a structural unit derived from hexafluoropropylene. The structural unit derived from hexafluoropropylene is included in an amount of about 10 wt % or less based on a total weight of the first binder. A weight average molecular weight of the first binder ranges from about 800,000 to about 1,500,000. The second binder includes a structural unit derived from vinylidene fluoride and a structural unit derived from hexafluoropropylene. The structural unit derived from hexafluoropropylene is included in an amount of 10 wt % or less based on a total weight of the second binder. A weight average molecular weight of the second binder is 600,000 or less.