This dealcoholization room-temperature curable organopolysiloxane composition contains (A) a diorganopolysiloxane having a silicon atom-bonded hydroxy group and/or a hydrolyzable silyl group at both ends of the molecular chain, and has a coefficient of viscosity of 20-1,000,000 mPa.Math.s, (B) an organopolysiloxane which is a partial (co-)hydrolysis-condensation product of a hydrolyzable organosilane compound having one or more silicon atom-bonded alkenyl groups and 1-3 silicon atom-bonded alkoxy groups, per molecule, (C) a hydrolyzable organosilane compound having one or more phenylene backbones and two or more amino groups, per molecule, and/or a partial hydrolysis-condensation product thereof. The dealcoholization room-temperature curable organopolysiloxane composition has good curability and storage stability even when the composition does not contain a metal catalyst, is less toxic to the human body and is environmentally friendly, is cost-competitive, and has good rubber physical properties and adhesiveness after being cured.

The present invention relates to a hydrosilylation-curable silicone composition comprising: a maleate compound, and a hydrosilylation inhibitor other than the maleate compound, wherein the content of the maleate compound is in an amount of 50 to 6,000 ppm and the content of the hydrosilylation inhibitor is in an amount of 200 to 20,000 ppm, with respect to the present composition in terms of mass units, respectively. The hydrosilylation-curable silicone composition exhibits good storage stability, and can be cured to form a cured product that suffers no surface wrinkling.

A two part curable composition comprising organosiloxane polymer; water; an organosilane such as hexamethyldisilazane (HMDS) or vinyltrimethoxysilane; crosslinker; adhesion promoter and catalyst; and optionally comprising plasticizer; colorant and filler. The first part can comprise organosiloxane polymer and water. The second part can comprise crosslinker; adhesion promoter and catalyst. Either or both parts can optionally further comprise an organosilane such as hexamethyldisilazane (HMDS) or vinyltrimethoxysilane; plasticizer; colorant and filler. Cured reaction products of the two part curable organosiloxane composition has good adhesion to metallic sealing surfaces and good resistance engine oil and other automotive fluids. Cured reaction products of the two part curable organosiloxane composition can surprisingly retain physical properties after long-term exposure to temperatures between 200° C. and 250° C. and can retain physical properties after exposure to temperatures between 250° C. to 300° C. for short periods.

One-part room-temperature curable compositions (RTV-1 compositions) based on organosilicon compounds are less toxic compared to conventional compositions containing organotin compounds and, at the same time, have excellent curing properties, a skin formation time which allows proper handling and tooling, and excellent storage stability. The compositions contain: at least one organosilicon compound containing condensable groups; at least one curing agent having the formula R′Si(OOCR″).sub.3, wherein R′ is C.sub.3-C.sub.6 alkyl, and R″ is C.sub.1-C.sub.6 alkyl; at least one organotitanium compound curing catalyst; and at least one filler.

A curing reactive silicone gel is provided. The curing reactive silicone gel is obtained by primarily curing a composition containing the following components in a gel form and further having secondarily curing reactivity. (A) an organopolysiloxane having at least two curing reactive groups in one molecule; (B) optionally, an organohydrogenpolysiloxane; and (C) a curing agent.

This room temperature-curable composition contains: (A) a prescribed polyoxyalkylene compound which has two reactive silicon groups (silyl groups having 1 hydroxy group or 1-3 organo-oxy groups) per molecule, with one reactive silicon group at each molecular chain terminal, and in which the main chain is a prescribed polyoxyalkylene-based polymer; (B) an inorganic filler; (C) a hydrolyzable (organo)silane compound and/or a partial hydrolytic condensation product thereof as a curing agent; (D) a silane coupling agent; and (E) a curing catalyst. Produced by this configuration is a cured product which exhibits excellent silicone oil resistance, excellent curing properties and good elongation and adhesive properties.

A curable water-swelling water stop material including: 100 parts by mass of a resin component which includes 40 to 100 parts by mass of a curable resin having a hydrolysable alkoxysilyl group and 0 to 60 parts by mass of a polyether polyol; 0.3 to 25 parts by mass of an aminosilane coupling agent; 20 to 250 parts by mass of a water-absorbent resin; and 0 to 160 parts by mass of an extender pigment, in which the hydrolysable alkoxysilyl group having a structure represented by Formula (1) —X—CH.sub.2—SiR.sup.1.sub.Y(OR.sup.2).sub.3-Y, in which X is a bonding functional group having a heteroatom with an unshared electron pair and bonding to a methylene group bonding to a silicon atom of a hydrolysable silicon group, R.sup.1 and R.sup.2 are C.sub.1-C.sub.3 alkyl groups respectively, and Y is 0, 1 or 2.

A silicone-polyacrylate copolymer has the formula X.sub.g[Z.sub.jY.sub.o].sub.c, where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polyacrylate moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0≤j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-polyacrylate copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-polyacrylate copolymer and a condensation-reaction catalyst.

The invention described herein generally pertains to a composition that includes a silyl-terminated polymer having silyl groups linked to a polymer backbone via triazole. The silyl-terminated polymer is a reaction product of a functionalized polymer backbone and a functionalized silane. The polymer backbone includes a first functional group, which may be one of an azide or an alkyne. The functionalized silane includes a second functional group may also be one of an azide or an alkyne, but is also different from the first functional group. The functionalized polymer backbone is reacted with the functionalized silane in the presence of a metal catalyst.

The invention described herein generally pertains to a composition that includes a silyl-terminated polymer having silyl groups linked to a polymer backbone via triazole. The silyl-terminated polymer is a reaction product of a functionalized polymer backbone and a functionalized silane. The polymer backbone includes a first functional group, which may be one of an azide or an alkyne. The functionalized silane includes a second functional group may also be one of an azide or an alkyne, but is also different from the first functional group. The functionalized polymer backbone is reacted with the functionalized silane in the presence of a metal catalyst.