Patent classifications
C09K8/06
HIGH TEMPERATURE VISCOELASTIC SURFACTANT (VES) FLUIDS COMPRISING NANOPARTICLE VISCOSITY MODIFIERS
In accordance with one or more embodiments, this disclosure describes a viscoelastic fluid for a subterranean formation comprising: viscoelastic surfactant comprising the general formula:
##STR00001##
where R.sub.1 is a saturated or unsaturated hydrocarbon group of from 17 to 29 carbon atoms, R.sub.2 and R.sub.3, are each independently selected from a straight chain or branched alkyl or hydroxyalkyl group of from 1 to 6 carbon atoms; R.sub.4 is selected from H, hydroxyl, alkyl or hydroxyalkyl groups of from 1 to 4 carbon atoms; k is an integer of from 2-20; m is an integer of from 1-20; and n is an integer of from 0-20; brine solution; and at least one nanoparticle viscosity modifier comprising a particle size of 0.1 to 500 nanometers, or 0.1 to 100 nanometers.
HIGH TEMPERATURE VISCOELASTIC SURFACTANT (VES) FLUIDS COMPRISING NANOPARTICLE VISCOSITY MODIFIERS
In accordance with one or more embodiments, this disclosure describes a viscoelastic fluid for a subterranean formation comprising: viscoelastic surfactant comprising the general formula:
##STR00001##
where R.sub.1 is a saturated or unsaturated hydrocarbon group of from 17 to 29 carbon atoms, R.sub.2 and R.sub.3, are each independently selected from a straight chain or branched alkyl or hydroxyalkyl group of from 1 to 6 carbon atoms; R.sub.4 is selected from H, hydroxyl, alkyl or hydroxyalkyl groups of from 1 to 4 carbon atoms; k is an integer of from 2-20; m is an integer of from 1-20; and n is an integer of from 0-20; brine solution; and at least one nanoparticle viscosity modifier comprising a particle size of 0.1 to 500 nanometers, or 0.1 to 100 nanometers.
Filter Cake Removal Compositions and Methods of Making and Using Same
A breaker composition comprising: (i) an acid precursor, (ii) a delaying agent and (iii) an aqueous fluid wherein the breaker composition has an effective operating temperature range of from about 25° C. to about 180° C. A wellbore servicing system comprising (a) an aqueous-based drilling fluid, wherein the aqueous-based drilling fluid forms water-wet solids in the wellbore; and (b) a breaker composition comprising (i) an acid precursor, (ii) a delaying agent and (iii) an aqueous fluid. A method of dissolving a filtercake comprising contacting the filtercake with a breaker solution comprising (i) an acid precursor, (ii) a delaying agent and (iii) an aqueous fluid wherein the filtercake comprises calcium carbonate.
Filter Cake Removal Compositions and Methods of Making and Using Same
A breaker composition comprising: (i) an acid precursor, (ii) a delaying agent and (iii) an aqueous fluid wherein the breaker composition has an effective operating temperature range of from about 25° C. to about 180° C. A wellbore servicing system comprising (a) an aqueous-based drilling fluid, wherein the aqueous-based drilling fluid forms water-wet solids in the wellbore; and (b) a breaker composition comprising (i) an acid precursor, (ii) a delaying agent and (iii) an aqueous fluid. A method of dissolving a filtercake comprising contacting the filtercake with a breaker solution comprising (i) an acid precursor, (ii) a delaying agent and (iii) an aqueous fluid wherein the filtercake comprises calcium carbonate.
Stabilization and reduction of TCT of brines containing monovalent iodides
A composition for use in a wellbore activity, the composition comprising a stabilized monovalent iodide brine, the stabilized monovalent iodide brine comprises a monovalent salt system, the monovalent salt system comprises a monovalent iodide; a primary iodide stabilizer, the primary iodide stabilizer operable to remove free iodine, prevent the formation of free iodine, and suppress TCT; and an aqueous fluid, where the stabilized monovalent iodide brine has a density greater than 10 lb/gal, where the stabilized monovalent iodide brine has a TCT of less than or equal to 70 deg F.
Stabilization and reduction of TCT of brines containing monovalent iodides
A composition for use in a wellbore activity, the composition comprising a stabilized monovalent iodide brine, the stabilized monovalent iodide brine comprises a monovalent salt system, the monovalent salt system comprises a monovalent iodide; a primary iodide stabilizer, the primary iodide stabilizer operable to remove free iodine, prevent the formation of free iodine, and suppress TCT; and an aqueous fluid, where the stabilized monovalent iodide brine has a density greater than 10 lb/gal, where the stabilized monovalent iodide brine has a TCT of less than or equal to 70 deg F.
Downhole methods
A method for the fracking or stimulation of a hydrocarbon-bearing formation, said method comprising the steps of: providing a wellbore in need of stimulation; inserting a plug in the wellbore at a predetermined location; inserting a perforating tool and a spearhead or breakdown acid into the wellbore; positioning the tool at said predetermined location; perforating the wellbore with the tool thereby creating a perforated area; allowing the spearhead acid to come into contact with the perforated area for a predetermined period of time sufficient to prepare the formation for fracking or stimulation; removing the tool from the wellbore; and initiating the fracking of the perforated area using a fracking fluid. Also disclosed is a corrosion inhibiting composition for use with the acid composition.
Downhole methods
A method for the fracking or stimulation of a hydrocarbon-bearing formation, said method comprising the steps of: providing a wellbore in need of stimulation; inserting a plug in the wellbore at a predetermined location; inserting a perforating tool and a spearhead or breakdown acid into the wellbore; positioning the tool at said predetermined location; perforating the wellbore with the tool thereby creating a perforated area; allowing the spearhead acid to come into contact with the perforated area for a predetermined period of time sufficient to prepare the formation for fracking or stimulation; removing the tool from the wellbore; and initiating the fracking of the perforated area using a fracking fluid. Also disclosed is a corrosion inhibiting composition for use with the acid composition.
Fluorous additives for use in a fluorous-based treatment fluid
A treatment fluid comprises: a liquid fluorinated compound; and at least one additive, wherein the additive: (A) comprises carbon and at least one fluorine functional group; and (B) is soluble or dispersible in the liquid fluorinated compound. A method of treating a portion of a well comprises: forming the treatment fluid; and introducing the treatment fluid into the well.
Method of Increasing the Density of a Well Treatment Brine
A method of increasing the density of a saturated or near saturated salt (initial) brine, such as a monovalent or divalent salt solution, consists of first lowering the true crystallization temperature (TCT) of the saturated or near saturated salt brine to the eutectic point using a glycol and then adding dry salt to the brine of lower TCT to provide a brine of increased density. The TCT may be lowered by the addition of glycol to the saturated or near saturated salt brine. The dry salt is the same salt as the salt of the saturated or near saturated salt brine. The amount of dry salt added to the brine of lower TCT is an amount sufficient to render a saturated or near saturated brine. The density of the resulting brine is higher than the density of the saturated or near saturated salt (initial) brine.