A composition for treating a formation includes a surfactant including an amphiphilic block copolymer having a first block and a second block and an acid. The amphiphilic block copolymer is a reaction product of a first monomer and a second monomer via a reversible addition-fragmentation chain transfer polymerization (RAFT) in a two-step reaction using a chain transfer agent (CTA) and a radical initiator. The surfactant favors adsorption onto a surface of the formation such that a temporary barrier is formed, thereby attenuating a reaction rate between the acid and the formation.

Methods for manufacturing lost circulation material particulates that may be for use in treating a subterranean formation are provided. In some embodiments, the methods include providing at a well-site a feed vessel that contains a liquid material, the liquid material including a monomer and an initiator; providing an injection device disposed underneath the feed vessel for directing at least a portion of the liquid material from the feed vessel to a reaction chamber, wherein the reaction chamber includes a fluid; discharging at least a portion of the liquid material from the feed vessel to the reaction chamber through an orifice disposed on the injection device; and forming LCM particulates at least in part by allowing at least a portion of the liquid material to polymerize in the fluid in the reaction chamber.

Methods for manufacturing lost circulation material particulates that may be for use in treating a subterranean formation are provided. In some embodiments, the methods include providing at a well-site a feed vessel that contains a liquid material, the liquid material including a monomer and an initiator; providing an injection device disposed underneath the feed vessel for directing at least a portion of the liquid material from the feed vessel to a reaction chamber, wherein the reaction chamber includes a fluid; discharging at least a portion of the liquid material from the feed vessel to the reaction chamber through an orifice disposed on the injection device; and forming LCM particulates at least in part by allowing at least a portion of the liquid material to polymerize in the fluid in the reaction chamber.

The problem of lost circulation is pertinent to the oil industry. To prevent fluid loss, a lost circulation material (LCM), or more generally, a plugging material, can be used to effectively plug the fractures in the rock formation. If the fractures are in the production zone, it is also ideal to unplug them when the drilling operation is complete. Therefore, a material engineered to degrade after a desired period would be useful. In examples, a plugging material has been developed by gelling an oil-based fluid using a low molecular weight gelator, dibenzylidene sorbitol (DBS). DBS gels are robust and show plugging behavior. DBS is shown to chemically degrade in presence of an acid. Hence, a self-degrading gel can be synthesized by incorporating an acid into the system. Further, by varying the type and concentration of the acid, the degradation time of the gel can be controlled.

A silicon oxide Janus nanosheets relatively permeability modifier (RPM) for carbonate and sandstone formations. The silicon oxide Janus nanosheets RPM may be used to treat a water and hydrocarbon producing carbonate or sandstone formation to reduce water permeability in the formation and increase the production of hydrocarbons. The silicon oxide Janus nanosheets RPM for carbonate formations includes a first side having negatively charged functional groups and a second side having alkyl groups. The silicon oxide Janus nanosheets RPM for sandstone formations includes a first side having positively charged functional groups and a second side having alkyl groups. The negatively charged functional groups may include a negatively charged oxygen group groups and hydroxyl groups. The positively charged functional groups may include amino groups and an amine. Methods of reducing water permeability using the silicon oxide Janus nanosheets RPM and methods of manufacturing the silicon oxide Janus nanosheets RPM are also provided.

A silicon oxide Janus nanosheets relatively permeability modifier (RPM) for carbonate and sandstone formations. The silicon oxide Janus nanosheets RPM may be used to treat a water and hydrocarbon producing carbonate or sandstone formation to reduce water permeability in the formation and increase the production of hydrocarbons. The silicon oxide Janus nanosheets RPM for carbonate formations includes a first side having negatively charged functional groups and a second side having alkyl groups. The silicon oxide Janus nanosheets RPM for sandstone formations includes a first side having positively charged functional groups and a second side having alkyl groups. The negatively charged functional groups may include a negatively charged oxygen group groups and hydroxyl groups. The positively charged functional groups may include amino groups and an amine. Methods of reducing water permeability using the silicon oxide Janus nanosheets RPM and methods of manufacturing the silicon oxide Janus nanosheets RPM are also provided.

A composition for treating a formation includes a surfactant including an amphiphilic block copolymer having a first block and a second block and an acid. The amphiphilic block copolymer is a reaction product of a first monomer and a second monomer via a reversible addition-fragmentation chain transfer polymerization (RAFT) in a two-step reaction using a chain transfer agent (CTA) and a radical initiator. The surfactant favors adsorption onto a surface of the formation such that a temporary barrier is formed, thereby attenuating a reaction rate between the acid and the formation.

A method includes treating a reservoir with a damaged near wellbore region (NWR), including introducing a liquid foam treatment into a wellbore proximate to the damaged NWR, where the liquid foam treatment has a solution medium and nanobubbles, transmitting an acoustic wave towards the damaged NWR such that the nanobubbles collapse, causing fluid flow pathways to form for hydrocarbon production. A system includes a solution generation tool for generating a liquid foam treatment, where the liquid foam treatment has a solution medium and nanobubbles, where the nanobubbles migrate along a concentration gradient, and an acoustic signal generator transmits an acoustic signal. The system also includes a downhole tool signally coupled to the acoustic signal generator fluidly coupled to the solution generation tool, and the downhole tool transmits an acoustic wave into an NWR and introduces the liquid foam treatment into the wellbore proximate to the NWR.

A method includes treating a reservoir with a damaged near wellbore region (NWR), including introducing a liquid foam treatment into a wellbore proximate to the damaged NWR, where the liquid foam treatment has a solution medium and nanobubbles, transmitting an acoustic wave towards the damaged NWR such that the nanobubbles collapse, causing fluid flow pathways to form for hydrocarbon production. A system includes a solution generation tool for generating a liquid foam treatment, where the liquid foam treatment has a solution medium and nanobubbles, where the nanobubbles migrate along a concentration gradient, and an acoustic signal generator transmits an acoustic signal. The system also includes a downhole tool signally coupled to the acoustic signal generator fluidly coupled to the solution generation tool, and the downhole tool transmits an acoustic wave into an NWR and introduces the liquid foam treatment into the wellbore proximate to the NWR.

A chemical gel system having a polymer and a graphene oxide Janus nanosheets crosslinker for treating thief zones in carbonate formations. The polymer and graphene oxide Janus nanosheets crosslinker may form a crosslinked polymer gel to reduce or prevent water production via thief zones during hydrocarbon production. The graphene oxide Janus nanosheets crosslinker includes a first side having negatively charged functional groups and a second side having amines. The negatively charged functional groups may include carboxyl groups, negatively charged oxygen groups, and hydroxyl groups. Methods of reducing water production in a thief zone using the graphene oxide Janus nanosheets crosslinker and methods of manufacturing the graphene oxide Janus nanosheets crosslinker are also provided.