The present invention provides a functional material, its preparation method, a three-dimensional display raster and a display device, which belongs to the display technical field and can solve the pollution problem in current three-dimensional display devices. The functional material includes an inorganic mixed powder with a modified layer, the inorganic mixed powder comprising boron oxide, sodium oxide, lithium oxide, zirconium oxide, aluminum oxide, zinc oxide, titanium oxide, silicon dioxide, calcium oxide, silver complexes, silver phosphate, silver nitrate, tourmaline, silver thiosulfate, carbon nanotubes, aluminum sulfate, manganese, manganese oxide, iron, iron oxide, cobalt, cobalt oxide, nickel, nickel oxide, chromium, chromium oxide, copper, copper oxide, magnesium oxide, boron carbide, silicon carbide, titanium carbide, zirconium carbide, tantalum carbide, molybdenum carbide, boron nitride, chromium nitride, titanium nitride, zirconium nitride, aluminum nitride, chromium boride, Cr.sub.3B.sub.4, titanium boride, zirconium boride, tungsten disilicide, titanium disilicide and the like; the modified layer being generated by a reaction of a dianhydride and a diamine.

A photoluminescent material including by weight a polymer matrix in a percentage comprised between 19.99% and 54.99%, a photoluminescent compound in a percentage comprised between 45% and 80%, porous silica in a percentage comprised between 0.01% and 1% and optionally a dye system and additives with a total percentage for the dye system and additives comprised between 0% and 15%. Also, an article made from or coated with this photoluminescent material.

Lighting systems, methods, and devices for protecting human circadian neuroendocrine function during night use are described. Suitable lighting conditions can be provided for a working environment while protecting the circadian neuroendocrine systems of those occupying the illuminated workplace during the night. Lighting systems, methods, and devices can provide substantive attenuation of the pathologic circadian disruption in night workers. Lighting systems, methods, and devices can attenuate the specific bands of light implicated in circadian disruption. LED lighting systems, methods, and devices can provide increased intensity at a different portion of the spectrum than conventional LEDs, providing a useable white light even when unfavorable portions of the wavelength are attenuated by a notch filter. LED lighting systems, methods, and devices can switch between a daytime configuration and a night time configuration, wherein the daytime configuration provides unfiltered light and the night time configuration provides filtered light.