A light-emitting device includes a substrate, a light-emitting element disposed on the substrate, and a sealing member for sealing the light-emitting element. The sealing member contains at least a particulate red phosphor. The red phosphor contains at least a Mn.sup.4+-activated fluoride complex phosphor. The sealing member has an upper surface with irregularities on at least part of the upper surface.

A light emitting diode package includes: a housing; a light emitting diode chip arranged in the housing; a wavelength conversion unit arranged on the light emitting diode chip; a first fluorescent substance distributed inside the wavelength conversion unit and emitting light having a peak wavelength in the cyan wavelength band; and a second fluorescent substance distributed inside the wavelength conversion unit and emitting light having a peak wavelength in the red wavelength band, wherein the peak wavelength of light emitted from the light emitting diode chip is located within a range of 415 nm to 430 nm.

A method includes mixing a first fluoride phosphor powder that is doped with tetravalent manganese with a treatment solution for a designated period of time, stopping the mixing to allow the fluoride phosphor powder to settle, removing at least some liquid that has separated from the first fluoride phosphor powder, repeating (a) the mixing, (b) the stopping of the mixing, and (c) removing at least some of the liquid during one or more additional cycles, and obtaining a second fluoride phosphor powder following the repeating of the mixing, the stopping of the mixing, and the removing of at least some of the liquid. The second fluoride phosphor powder includes a reduced amount of the manganese relative to the first fluoride phosphor powder.

Solution for use in filling micrometer-size cavities (10), the solution comprising a first solvent, a first polymer (102) having a first molecular weight, a second polymer (103) having a second molecular weight, luminophores (101) and a surfactant, the second molecular weight being 10 to 50 times greater than the first molecular weight.

The method for manufacturing a light-emitting device includes flip-chip mounting a first light-emitting element and a second light-emitting element on a substrate separately from each other, bonding a first light-transmissive member to the first light-emitting element, the first light-transmissive member having a first lateral surface, and bonding a second light-transmissive member to the second light-emitting element, the second light-transmissive member having a second lateral surface, with the second lateral surface being separated from and facing the first lateral surface, scraping at least one of the first lateral surface and the second lateral surface to expose at least one of a modified first lateral surface and a modified second lateral surface, forming a light-reflective covering member on the substrate to cover the first lateral surface or the modified first lateral surface, and the second lateral surface or the modified second lateral surface, and cutting the substrate and the covering member between the first lateral surface or the modified first lateral surface, and the second lateral surface or the modified second lateral surface.

A light emitting device is provided. The light emitting device includes a light emitting element, which emits blue light, and a light transmissive member having a first principal face bonded to the light emitting element and a second principal face opposite the first principal face. The light transmissive member has a light transmissive base material and wavelength conversion substances, which are contained in the base material and which absorb the light from the light emitting element and emit light. The wavelength conversion substances are localized in the base material towards the first principal face, and include a first phosphor which emits green to yellow light and a second phosphor which emits red light. The first phosphor is more localized towards the first principal face than the second phosphor. The second phosphor is a manganese-activated fluoride phosphor.

A color conversion film is provided. The film includes at least one narrow band emission phosphor dispersed within a binder matrix, wherein the narrow band emission phosphor has a D50 particle size from about 0.1 μm to about 15 μm and is selected from the group consisting of a green-emitting U.sup.6+-containing phosphor, a green-emitting Mn.sup.2+-containing phosphor, a red-emitting phosphor based on complex fluoride materials activated by Mn.sup.4+, and a mixture thereof. A device is also provided.

A method for producing a fluorescent material can be provided. The method includes preparing fluorescent material particles that contain a fluoride having a composition including Mn, at least one selected from the group consisting of alkali metal elements and NH.sub.4.sup.+, and at least one selected from the group consisting of Group 4 elements and Group 14 elements; causing at least one cation selected from rare-earth elements and a phosphate ion to come into contact with each other in a liquid medium containing the fluorescent material particles to obtain rare-earth phosphate-adhered fluorescent material particles including the fluorescent material particles to which the rare-earth phosphate is adhered; and separating the rare-earth phosphate-adhered fluorescent material particles from the liquid medium.

A method of manufacturing a light emitting device includes providing a package; disposing a light emitting element in a recess of the package; injecting a sealing material in the recess, the sealing material including fluorescent material particles and a binder, the fluorescent material particles including particles of fluoride fluorescent material that include a surface region and an inner region, both the surface region and the inner region having a composition including: tetravalent manganese ions, at least one element or compound selected from the group consisting of alkali metal elements and NH.sub.4.sup.+, and at least one element selected from the group consisting of Group 4 and Group 14 elements; sedimenting centrifugally the fluorescent material particles toward a bottom surface in the recess to form a sealing member that comprises a first sealing member portion and a second sealing member portion; and curing the binder to form a cured sealing member.

A white light-emitting device includes a light-emitting element that emits a blue light, and a sealing resin that seals the light-emitting element and that includes a first phosphor and a second phosphor, the first phosphor wavelength-converting a portion of the blue light and emitting a red light, the second phosphor wavelength-converting a portion of the blue light and emitting a green light. The white light-emitting device emits a white light by mixing the blue, red and green lights. The sealing resin further includes a third phosphor that wavelength-converts a portion of the blue light, emits a light in a same color gamut as the first or second phosphor, and has a higher light conversion efficiency than the first or second phosphor. The third phosphor is included in the sealing resin at an additive amount less than an amount that causes a change in a spectrum of the white light.