According to some embodiments, an apparatus and method are provided comprising: an enclosure defining a cavity within the enclosure, the cavity comprising a depth dimension; at least one LED chip; a layer comprising a blend of an encapsulant material and phosphor composition, the layer overlaying the at least one LED chip and disposed within the cavity; the phosphor composition comprising a yellow-green phosphor and a Mn.sup.4+ doped complex fluoride phosphor of formula I, A.sub.x[MF.sub.y]:Mn.sup.4+ (I) where A is Li, Na, K, Rb, Cs, NR.sub.4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; x is the absolute value of the charge of the [Mf.sub.y] ion; and y is 5, 6, or 7; wherein the Mn.sup.4+ doped complex fluoride phosphor of formula I comprises a d50 particle size of from about 1 micrometers to about 10 micrometers, and the LED lighting apparatus, when activated, emits visible light comprising a correlated color temperature (CCT) of from about 2500 K to about 3700 K. Numerous other aspects are provided.

An ink composition is provided. The composition includes a binder material and at least one narrow band emission phosphor being uniformly dispersed throughout the composition, wherein the narrow band emission phosphor has a D50 particle size from about 0.1 μm to about 15 μm and is selected from the group consisting of a green-emitting U.sup.6+-containing phosphor, a green-emitting Mn.sup.2+-containing phosphor, a red-emitting phosphor based on complex fluoride materials activated by Mn.sup.4+, and a mixture thereof. A device is also provided.

A color conversion film is provided. The film includes at least one narrow band emission phosphor dispersed within a binder matrix, wherein the narrow band emission phosphor has a D50 particle size from about 0.1 μm to about 15 μm and is selected from the group consisting of a green-emitting U.sup.6+-containing phosphor, a green-emitting Mn.sup.2+-containing phosphor, a red-emitting phosphor based on complex fluoride materials activated by Mn.sup.4+, and a mixture thereof. A device is also provided.

A stabilized fluoride phosphor for light emitting diode (LED) applications includes a particle comprising manganese-activated potassium fluorosilicate and an inorganic coating on each of the particles. The inorganic coating comprises a silicate. A method of making a stabilized fluoride phosphor comprises forming a reaction mixture that includes particles comprising a manganese-activated potassium fluorosilicate; a reactive silicate precursor; a catalyst; a solvent; and water in an amount no greater than about 10 vol. %. The reaction mixture is agitated to suspend the particles therein. As the reactive silicate precursor undergoes hydrolysis and condensation in the reaction mixture, an inorganic coating comprising a silicate is formed on the particles. Thus, a stabilized fluoride phosphor is formed.

An LED-filament comprising: a partially light transmissive substrate; a plurality of LED chips on a front face of the substrate; a photoluminescence material that is in direct contact with and covers all of the plurality of LED chips; and a light scattering layer that is in direct contact with and covers at least the photoluminescence material, wherein the light scattering layer comprises particles of light scattering material, and wherein the photoluminescence material comprises broadband green to red photoluminescence materials and narrowband red photoluminescence material.

Disclosed are a preparation method for manganese-doped red phosphor, a device and a backlight module including the product. The method includes: 1) mixing A.sub.2BF.sub.6 polycrystalline particles with mill balls; 2) mixing A.sub.2BF.sub.6 powder obtained after ball-milling with a hydrofluoric acid for secondary crystallization; 3) filtering out solid particles in A.sub.2BF.sub.6 and hydrofluoric acid solution after the secondary crystallization; 4) performing ion exchange between A.sub.2BF.sub.6 particles and A.sub.2BF.sub.6; and 5) filtering out solid particles to obtain a filter cake, and performing drying treatment to obtain manganese-doped red phosphor.

A color conversion film is provided. The film includes at least one narrow band emission phosphor dispersed within a binder matrix, wherein the narrow band emission phosphor has a D50 particle size from about 0.1 μm to about 15 μm and is selected from the group consisting of a green-emitting U.sup.6+-containing phosphor, a green-emitting Mn.sup.2+-containing phosphor, a red-emitting phosphor based on complex fluoride materials activated by Mn.sup.4+, and a mixture thereof. A device is also provided.

A process for coating a phosphor of formula I: A.sub.x[MF.sub.y]:Mn.sup.4+ includes combining the phosphor of formula I in particulate form with a first solution including a compound of formula II: A.sub.x[MF.sub.y] to form a suspension and combining a second solution with the suspension, the second solution including a precursor including an element selected from the group consisting of calcium, strontium, magnesium, yittrium, barium, scandium, lanthanum, and combinations thereof. A population of particles having a core including a phosphor of formula I and a manganese-free composite coating disposed on the core, and a lighting apparatus (10) including the population of particles are also presented.

An ink composition is provided. The composition includes a binder material and at least one narrow band emission phosphor being uniformly dispersed throughout the composition, wherein the narrow band emission phosphor has a D50 particle size from about 0.1 μm to about 15 μm and is selected from the group consisting of a green-emitting U.sup.6+-containing phosphor, a green-emitting Mn.sup.2+-containing phosphor, a red-emitting phosphor based on complex fluoride materials activated by Mn.sup.4+, and a mixture thereof. A device is also provided.

A coated phosphors that include a shell comprising a first Mn.sup.4+ doped phosphor of formula I
A.sub.x[MF.sub.y]:Mn.sup.4+  I
directly disposed on a core comprising a second phosphor. The second phosphor is a material other than a compound of formula I or formula II
A.sub.x[MF.sub.y]  II
wherein A is, independently at each occurrence, Li, Na, K, Rb, Cs, or a combination thereof; M is, independently at each occurrence, Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MF.sub.y] ion; and y is 5, 6 or 7.