Disclosed are highly luminescent nanostructures, particularly highly luminescent quantum dots, comprising a nanocrystal core of InP and shell layers of GaP and AlP. The nanostructures may have an additional shell layer. Also provided are methods of preparing the nanostructures, films comprising the nanostructure and devices comprising the nanostructures.

The present disclosure relates to a device used in conjunction with night vision equipment. The device including an LED light source optically coupled and/or radiationally connected to a phosphor material including a green-emitting phosphor and a red-emitting phosphor of formula I:

A.sub.xMF.sub.y:Mn.sup.4+I wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is an absolute value of a charge of the MF.sub.y ion; and y is 5, 6 or 7. The device limits emission of wavelengths longer than 650 nm to less than 1.75% of total emission. A device including an LED light source optically coupled and/or radiationally connected to a red-emitting phosphor including Na.sub.2SiF.sub.6:Mn.sup.4+ is also provided.

The present disclosure relates to a device used in conjunction with night vision equipment. The device including an LED light source optically coupled and/or radiationally connected to a phosphor material including a green-emitting phosphor and a red-emitting phosphor of formula I:
A.sub.xMF.sub.y:Mn.sup.4+I
wherein A is Li, Na, K, Rb, Cs, or a combination thereof, M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof, x is an absolute value of a charge of the MF.sub.y ion; and y is 5, 6 or 7. The device limits emission of wavelengths longer than 650 nm to less than 1.75% of total emission. A device including an LED light source optically coupled and/or radiationally connected to a red-emitting phosphor including Na.sub.2SiF.sub.6:Mn.sup.4+ is also provided.

Provided is a photochromic substance that has lower toxicity, exhibits good sensitivity in a visible light region, changes color deeply, has slow speed of color fading, has chemical and thermal stability, and has good durability. The photochromic substance has a composition represented by the formula:
Ba.sub.(a-b)Ca.sub.bMg.sub.cSi.sub.dO.sub.e:Fe.sub.fM.sub.gM.sub.h where 1.8a2.2, 0b0.1, 1.4c3.5, 1.8d2.2, e=(a+c+2d), 0.0001f, 0.0001g, 0h, M is at least one of Al and Eu, and M is at least one element selected from the group consisting of Na, K, Nd, Li, S, C, Ti, V, Mn, Cr, Cu, Ni, Co, Ge, Zn, Ga, Zr, Y, Nb, In, Ag, Mo, Sn, Sb, Bi, Ta, W, La, Ce, Pr, Nd, Sm, Gd, Er, Ho, Tb, Tm, Yb, Lu, P, Cd, and Pb.

A phosphor composition includes an activated uranium-based phosphor having formula I or II. The phosphor is doped with Eu.sup.3+

[Ba.sub.1abSr.sub.aCa.sub.b].sub.x[Mg,Zn].sub.y(UO.sub.2).sub.z([P,V]O.sub.4).sub.2(x+y+z)/3(I)

[Ba.sub.1abSr.sub.aCa.sub.b].sub.p(UO.sub.2).sub.q[P,V].sub.rO.sub.(2p+2q+5r)/2(II)

where 0a1, 0b1, 0.75x1.25, 0.75y1.25, 0.75z1.25, 2.5p3.5, 1.75q2.25, and 3.5r4.5 and formula II excludes the combination where a is 0, b is 0, p is 3.5, q is 1.75, and r is 3.5. Phosphor compositions further including formula VI or other luminescent materials, such as quantum dots, devices and displays are also provided.

A uranium-based phosphor selected from (i) phosphors having formula I or II:

##STR00001##

where the phosphor having formula I or II is doped with an activator ion including Pr.sup.3+, Sm.sup.3+, or mixtures thereof, where 0a1, 0b1, 0.75x1.25, 0.75y1.25, 0.75z1.25, 2.5p3.5, 1.75q2.25, and 3.5r4.5; (ii) a phosphor having formula I or II, where the phosphor having formula I or II is doped with an activator ion selected from Eu.sup.3+, Pr.sup.3+, Sm.sup.3+, and mixtures thereof; and a counter ion comprising one or more alkali metal ions; and (iii) phosphors having formula III

##STR00002##

where the phosphors having formula III are doped with an activator ion selected from: Eu.sup.3+, Pr.sup.3+, Sm.sup.3+, and mixtures thereof, where A is Li, Na, K, Rb, Cs, or a combination thereof.