C09K15/22

Compositions and methods comprising nitrification inhibitors containing a mixture of protic and aprotic solvent systems

The present invention relates to increasing longevity of the nitrogen content of soil through improved liquid delivery formulations of nitrification inhibitors. The liquid formulation can also be comprised of nitrification inhibitors and optionally urease inhibitors that are blended solutions of each. The nitrification inhibitors are present in a mixture that comprises both a protic and an aprotic solvent system. The novel formulations are designed to be applied to fertilizers, especially urea and manure based fertilizers. The delivery formulations provide an environmentally sound and inherently safe solvating system that improves the storage stability of the urease inhibitors by utilizing liquid organic non-water containing solvents, maintains the nitrification inhibitors in solution to storage temperatures of at least 10? C., and provides improved application to fertilizer of nitrification inhibitors. These delivery formulations enable safe storage, transport and subsequent application or blending with urea-based or manure-based fertilizers that can be applied to soil in either a liquid or granular form to provide improved nitrogen retention in the soil for uptake for plant life.

Using novel amines to stabilize quaternary trialkylalkanolamines
10264785 · 2019-04-23 · ·

New stabilizers for solutions of choline hydroxide and related quaternary trialkylalkanolamines are disclosed. The stabilizers are alkyl hydroxylamines, hydrazines, hydrazides, or derivates thereof, including compounds containing more than one such functionality. The new stabilizers are effective at concentrations less than about 1000 ppm, and choline hydroxide solutions stabilized with the compounds described herein typically have Gardner Color change less than about 2.0 after six months at reasonable temperatures.

Using novel amines to stabilize quaternary trialkylalkanolamines
10264785 · 2019-04-23 · ·

New stabilizers for solutions of choline hydroxide and related quaternary trialkylalkanolamines are disclosed. The stabilizers are alkyl hydroxylamines, hydrazines, hydrazides, or derivates thereof, including compounds containing more than one such functionality. The new stabilizers are effective at concentrations less than about 1000 ppm, and choline hydroxide solutions stabilized with the compounds described herein typically have Gardner Color change less than about 2.0 after six months at reasonable temperatures.

COMPOSITIONS WITH IMPROVED UREASE-INHIBITING EFFECT COMPRISING (THIO)PHOSPHORIC ACID TRIAMIDE AND FURTHER COMPOUNDS

An composition comprising: (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I)


R.sup.1R.sup.2NP(X)(NH.sub.2).sub.2, wherein X is oxygen or sulfur; R.sup.1 is a C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, C.sub.6 to C.sub.20 aryl, or dialkylaminocarbonyl group; R.sup.2 is H, or R.sup.1 and R.sup.2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and (C) at least one amine selected from the group consisting of (C1) a polymeric polyamine, and (C2) an amine containing not more than one amino group and at least three alkoxy- or hydroxy-substituted C.sub.2 to C.sub.12 alkyl groups R.sup.21, wherein at least one of the groups R.sup.21 is different to the other groups R.sup.21, and (C3) an amine containing not more than one amino group and at least two alkoxy- or hydroxy-substituted C.sub.2 to C.sub.12 alkyl groups R.sup.22, wherein at least one of the groups R.sup.22 bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom and wherein at least one of the groups R.sup.22 is different to the other group(s) R.sup.22, and (C4) an amine containing at least one saturated or unsaturated C.sub.8 to C.sub.40 alkyl group R.sup.23, and (C5) a saturated or unsaturated heterocyclic amine which contains at least one oxygen atom as ring atom and which does not contain a further alkoxy group.

COMPOSITIONS WITH IMPROVED UREASE-INHIBITING EFFECT COMPRISING (THIO)PHOSPHORIC ACID TRIAMIDE AND FURTHER COMPOUNDS

An composition comprising: (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I)


R.sup.1R.sup.2NP(X)(NH.sub.2).sub.2, wherein X is oxygen or sulfur; R.sup.1 is a C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, C.sub.6 to C.sub.20 aryl, or dialkylaminocarbonyl group; R.sup.2 is H, or R.sup.1 and R.sup.2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and (C) at least one amine selected from the group consisting of (C1) a polymeric polyamine, and (C2) an amine containing not more than one amino group and at least three alkoxy- or hydroxy-substituted C.sub.2 to C.sub.12 alkyl groups R.sup.21, wherein at least one of the groups R.sup.21 is different to the other groups R.sup.21, and (C3) an amine containing not more than one amino group and at least two alkoxy- or hydroxy-substituted C.sub.2 to C.sub.12 alkyl groups R.sup.22, wherein at least one of the groups R.sup.22 bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom and wherein at least one of the groups R.sup.22 is different to the other group(s) R.sup.22, and (C4) an amine containing at least one saturated or unsaturated C.sub.8 to C.sub.40 alkyl group R.sup.23, and (C5) a saturated or unsaturated heterocyclic amine which contains at least one oxygen atom as ring atom and which does not contain a further alkoxy group.

Primary amine-containing polymers useful as scale inhibitors

Processes for inhibiting scale produced during wet process phosphoric acid production by adding a scale-inhibiting amount of a reagent having a primary amine-containing polymer to at least one stage of a wet process phosphoric acid production process are provided herein, wherein said primary amine-containing polymer includes one or more organic moieties that reduce the polymer's solubility in an aqueous environment as compared to its native form, thereby reducing or preventing scale in the wet process phosphoric acid production process.

Primary amine-containing polymers useful as scale inhibitors

Processes for inhibiting scale produced during wet process phosphoric acid production by adding a scale-inhibiting amount of a reagent having a primary amine-containing polymer to at least one stage of a wet process phosphoric acid production process are provided herein, wherein said primary amine-containing polymer includes one or more organic moieties that reduce the polymer's solubility in an aqueous environment as compared to its native form, thereby reducing or preventing scale in the wet process phosphoric acid production process.

THERMAL INTERFACE MATERIAL WITH ION SCAVENGER
20190048245 · 2019-02-14 ·

A thermal interface material includes at least one polymer, at least one thermally conductive filler; and at least one ion scavenger. In some embodiments, the ion scavenger is a complexing agent selected from the group consisting of: nitrogen containing complexing agents, phosphorus containing complexing agents, and hydroxyl carboxylic acid based complexing agents.

THERMAL INTERFACE MATERIAL WITH ION SCAVENGER
20190048245 · 2019-02-14 ·

A thermal interface material includes at least one polymer, at least one thermally conductive filler; and at least one ion scavenger. In some embodiments, the ion scavenger is a complexing agent selected from the group consisting of: nitrogen containing complexing agents, phosphorus containing complexing agents, and hydroxyl carboxylic acid based complexing agents.

SYNTHESIS OF TETRADECANOIC MODIFIED GRAPHENE AS A CORROSION INHIBITOR

Described is a method of synthesizing a corrosion inhibitor. An amine modified graphene oxide is synthesized from graphene oxide nanosheets using a bifunctional amine having a terminal amide group. Amide groups of the bifunctional amine are reacted with carboxyl groups of the graphene oxide. Aliphatic and amine modified graphene oxide is synthesized from the amine modified graphene oxide using an aliphatic acid. The aliphatic and amine modified graphene oxide includes aliphatic groups derived from a long chain aliphatic acid and amine groups derived from the bifunctional amine. Amine modified graphene oxide is synthesized by dispersing graphene oxide nanosheets in methanol, adding diethylenetriamine, and adding an amount of N,N-Dicyclohexylcarbodiimide (DCC) catalyst. Tetradecanoic and amine modified graphene nanosheets are synthesized by adding amine modified graphene to tetradecanoic acid to form a solution, then adding an amount of cobalt-salen catalyst to the solution.