A method of making chlorofluorohydrocarbons including, contacting, a fluorinated hydrocarbon reagent in the vapor phase, with hydrogen chloride (HCl). The reaction is conducted in the presence of an effective amount of a catalyst, at an elevated temperature sufficient to effect hydrochlorination to form a reaction mixture including a chlorofluorohydrocarbon.

The propagation of a disproportionation reaction of a refrigerant is suppressed. Disclosed is a method that uses a composition as a refrigerant in a compressor, in which the composition includes one or more compounds selected from the group of ethylene-based fluoroolefins, 2,3,3,3-tetrafluoropropene, and 1,3,3,3-tetrafluoropropene, and the flow rate of the refrigerant flowing through a region around an ignition energy generation portion in the compressor under a predetermined high-pressure condition is greater than or equal to 1 m/s.

Methods and systems for liquefying natural gas using environmentally-friendly low combustibility refrigerants are provided. Methods of liquefaction include cooling a fluid in an LNG facility via indirect heat exchange with an environmentally-friendly low combustibility refrigerants that are propane, ethane and methane mixed with small amounts of fluorinated olefin, but still within close proximity to the boiling points of the pure refrigerants such that the mixed refrigerants can still be used in an optimized cascade process.

A working medium for a heat cycle includes HFO-1123, HFC-32, and HFO-1234ze. These three components HFO-1123, HFC-32, and HFO-1234ze are present as principal components in a mixture state.

The propagation of a disproportionation reaction of a refrigerant is suppressed. Disclosed is a method that uses a composition as a refrigerant in a refrigerant circuit, in which the composition includes one or more compounds selected from the group consisting of ethylene-based fluoroolefins, 2,3,3,3-tetrafluoropropene, and 1,3,3,3-tetrafluoropropene, and the refrigerant circuit includes a compressor, a four-way switching valve, and a first refrigerant pipe connecting the compressor and the four-way switching valve, the first refrigerant pipe having a pipe diameter less than or equal to ⅜ inch or a length greater than or equal to 5 cm.

A pressure increase in a compressor is suppressed. Disclosed is a method that uses a composition as a refrigerant in a refrigerant circuit, in which the composition includes one or more compounds selected from the group consisting of ethylene-based fluoroolefins, 2,3,3,3-tetrafluoropropene, and 1,3,3,3-tetrafluoropropene, and in the refrigerant circuit, the total internal volume of a refrigerant pipe and a component that are connected to a compressor is greater than or equal to 0.7 times the internal volume of the compressor.

The present invention relates, in part, to heat transfer compositions, and associated systems and methods, which include a first composition selected from the group consisting of HFO-1233zd, HFC-245fa, and combinations of these; and, optionally, a second composition selected from the group consisting of HFO-1234ze, HFC-134a, and combinations of these.

An object of the present invention is to provide, as a working fluid to be used for a heat cycle system, a working fluid for heat cycle that has cycle performance replaceable with that of R410A, and at the same time, has a small burden on an apparatus, low flammability, suppressed self-decomposition, and less effect on global warming, and therefore, is usable stably even if leaked, a composition for heat cycle system containing the same, and a heat cycle system using the composition. The working fluid for heat cycle contains trifluoroethylene, difluoromethane, and at least one selected from 1,1-difluoroethane, fluoroethane, propane, propylene, carbon dioxide, 2,3,3,3-tetrafluoropropene, and (E)-1,3,3,3-tetrafluoropropene at mass ratios satisfying predetermined expressions and at a ratio of the total content to be 90 to 100 mass % relative to the total amount of the working fluid and has a temperature glide of 10° C. or less.

An object is to provide a hydrofluoroolefin-based or hydrochlorofluoroolefin-based azeotropic or azeotropic-like composition. The azeotropic or azeotropic-like composition contains trans-1-chloro-3,3,3-trifluoropropene and 1-chloro-1,3,3,3-tetrafluoropropene. In the azeotropic or azeotropic-like composition, 1-chloro-1,3,3,3-tetrafluoropropene exists in an effective amount to form an azeotropic or azeotropic-like mixture with trans-1-chloro-3,3,3-trifluoropropene.

A composition comprising a heat transfer portion and a lubricating portion, wherein the lubricating portion comprises one or more compounds according to formula (I) of the present disclosure, wherein W is H; Y is independently selected from the group consisting of F, Cl, Br and I; Z is independently selected from the group consisting of H, OH, (CW.sub.2).sub.PCW.sub.3, CY.sub.3, OCW.sub.3, O(CW.sub.2).sub.pCW.sub.3, OCW((CY.sub.2).sub.mCY.sub.3)CWCW.sub.2, polyalkylene glycol and polyolester; n is an integer from 2 to 250; m is an integer from 0 to 3; and p is an integer from 0 to 9.