An electrochromic device is provided. The electrochromic device includes a first electrode, a second electrode opposed to the first electrode at an interval, and an electrochromic layer between the first electrode and the second electrode. The electrochromic layer contains an electrochromic material and a first ion-conducting material partially comprising a non-ion-conducting portion that does not conduct ions. The non-ion-conducting portion comprises a molecular unit structure having an atomic arrangement in which 8 or more atoms having a valence of 2 or more are bonded with each other. The atoms comprise heteroatoms in a number of 15% or less based on a total number of the atoms.

The invention provides for polyfluoreno[4,5-cde]oxepine conjugates and their use in methods of analyte detection.

Copolymers including dioxythiophene repeating units and no acceptor units allow the formation of electrochromic polymers (ECPs) with vivid neutral state colors and very colorless oxidized states that can be switched rapidly. The dioxythiophene repeating units can included in sequences where all of one type of dioxythiophene is included exclusively as isolated dyads or triads within the copolymer, or the copolymer can be an alternating copolymer with propylenedioxythiophene units. Other non-acceptor units can be included in the copolymers. The copolymers are rendered organic solvent soluble by alkyl substituents on repeating units. The inclusion of sterically encumbered acyclic dioxythiophene (AcDOT) units promotes red color while unsubstituted ethylenedioxythiophene (EDOT) units promote blue colors, and their respective content can be manipulated to achieve a desired neutral state color. Soluble copolymers comprising at least 50% EDOT repeating units can be used in supercapacitor applications.

Yellow electrochromic polymers (ECPs) are prepared that display a yellow neutral state and a highly transmissive oxidized state. The ECPs are copolymers where a dyad of dioxyhetereocyclic repeating unis alternate with a monad of an aromatic repeating unit. An alternate yellow ECP has an oxidation potential of 450 mV or less and is an alternating copolymer of an acyclic dioxythiophene (AcDOT) or a propylene dioxythiophene (ProDOT) with an aromatic repeating unit that has an electron donating substituent. The yellow ECPs can be processed from solution for electrochromic devices.

Compositions comprising a polymeric dye and a cyclodextrin are provided. Methods associated with preparation and use of such compounds, for example in methods for detection of any analyte molecule, are also provided.

Disclosed is a rare-earth complex polymer including trivalent rare-earth ions and a phosphine oxide bidentate ligand represented by the formula (1). One phosphine oxide bidentate ligand is coordinated to the two rare-earth ions, and crosslinks the same.

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The present disclosure discloses a fluorescent starch nanocrystal and a preparation method and application thereof. Mainly based on the character that starch nanocrystal has an active hydroxyl group on the surface, the present disclosure introduces fluorescein isothiocyanate into the surface of the starch nanocrystal in the form of stable covalent bonds through a two-step chemical modification method: silane coupling and electrophilic addition of fluorescein, so as to prepare the starch nanocrystal with fluorescent properties. The preparation process of the present disclosure is simple and easy to operate, uses cheap and readily available raw materials, involves low cost, and allows the non-fluorescent starch nanocrystal to produce significant fluorescent properties without affecting the properties of the starch nanocrystal itself, thereby expanding the application of starch. Moreover, the fluorescent starch nanocrystal thus obtained has significant fluorescent properties, good biocompatibility and biodegradability, has application prospects in the fields of biosensor preparation, bioimaging marking and fluorescent analysis and detection, and can be further prepared into a novel nano-fluorescent probe with organic nano-particles as the matrix.

A composition including a fluorescent polymer tag and an aqueous-based drilling fluid is provided. Also provided is a method of determining drill depth of recovered drill cuttings. The method includes introducing a fluorescent polymer tag into a drilling fluid, the fluorescent polymer tag includes the composition having the fluorescent compound linked to the polymer. The method then includes circulating the drilling fluid through a well during a drilling operation that creates formation cuttings such that the fluorescent polymer interacts with the formation cuttings, creating tagged cuttings. The returned cuttings are collected from the circulating drilling fluid at a surface of the well. The method then includes detecting the presence of the fluorescent polymer tag on the returned cuttings to identify the tagged cuttings, and correlating the tagged cuttings with the drill depth in the well at a time during the drilling operation.

A method for making photochromic molecule-cyclodextrin inclusion compounds, including: preparing a solution of photochromic molecules and preparing a solution of cyclodextrins. The molecule of cyclodextrin is frusto-conical shaped and hollow. The photochromic solution and the cyclodextrin solution are mixed, the photochromic molecules being entrapped in the cavities of the cyclodextrins, thereby forming the photochromic molecule-cyclodextrin inclusion compounds.

A photochromic ophthalmic lens includes a body and photochromic molecule-cyclodextrin inclusion compounds dispersed in the body. The photochromic molecule-cyclodextrin inclusion compounds include cyclodextrins and photochromic molecules entrapped in a cavity of the cyclodextrins. Notwithstanding the hydrophobic nature of the photochromic molecules, the cyclodextrins, which contains cavities entrapping the photochromic molecules, are hydrophilic.