The present invention relates to compounds of the formula (1) and (2) ##STR00001##
which are suitable for use in electronic devices, in particular organic electroluminescent devices.

This invention provides a luminescent composition comprising a polymer and at least one phosphorescent compound, characterized in that the electronic conjunction chain coefficient Z.sub.e of the main repeating minimum unit of the polymer falls within the following range: 0<Z.sub.e2.00 (1) wherein the electronic conjunction chain coefficient Z.sub.e is defined as a slope obtained by linear approximation of function T.sub.m=T.sub.m (1/n.sub.e) by the least square method wherein n.sub.e represents the number of conjugated electrons contained in repeating minimum units; and T.sub.m represents, for m-mer obtained by bonding repeating minimum units, the lowest triplet excitation energy in each m-mer when the number m is varied from 1 to 3 by one by one. Here in the number of conjugated electrons, only the conjugated electrons present in the main chain of the repeating minimum units are taken into consideration, provided that, when there are a plurality of main repeating minimum units, the minimum Z.sub.e is used.

A method including combining at least one first compound in a neutral form with at least one ionic dopant in a first solvent system to provide a first doped reaction product, isolating the first doped reaction product in solid form, and combining the isolated first doped reaction product with at least one conjugated polymer in neutral form in a second solvent system to form a second doped reaction product including an oxidized form of the conjugated polymer a neutral form of the first compound is described. Advantages include better stability, ease of use, and lower metal content. Applications include organic electronic devices including OLEDs.

The present invention discloses the syntheses of new polymers with defined structures, comprising dithienothiophene (DTT) and thienothiophene (TT) derivatives and boron, light emitting devices of which have wide spectrum of fluorescence at visible region and potential of emitting white light.

There is provided an electroactive material having Formula I ##STR00001##
wherein: Q is the same or different at each occurrence and can be O, S, Se, Te, NR, SO, SO.sub.2, or SiR.sub.3; R is the same or different at each occurrence and can be hydrogen, alkyl, aryl, alkenyl, or alkynyl; and R.sup.1 through R.sup.6 are the same or different and can be hydrogen, alkyl, aryl, halogen, hydroxyl, aryloxy, alkoxy, alkenyl, alkynyl, amino, alkylthio, phosphino, silyl, COR, COOR, PO.sub.3R.sub.2, OPO.sub.3R.sub.2, or CN.

An all-donor black color electrochromic polymer is disclosed as well as a method for preparing the all-donor black color electrochromic polymer. The electrochromic polymer comprises conjugated polymers, and the conjugated polymers are chemically linked, or physically blended, or both.

The invention provides a photopolymerisable or photocrosslinkable reactive mesogen for forming a charge transporting or light emitting polymer network, the mesogen having an asymmetric structure (II): B.sub.1-S.sub.1-A.sub.1-M-(A-S-B).sub.n (II) wherein: A and A.sub.1 are chromophores; S and S.sub.1 are spacers; B and B.sub.1 are endgroups which are susceptible to photopolymerisation or photocrosslinking; M is a non-chromophoric aliphatic, alicyclic or aromatic moiety; and n is an integer from 1 to 3; wherein, when the value of n is greater than 1, each of the groups A, S and B may be the same or different. Preferably, M is of the formula YZ.sub.m, wherein Y is an aliphatic, alicyclic, aromatic or heterocyclic moiety, Z is an aliphatic linking group and m is an integer from 2 to 4, and wherein each of the Z groups may be the same or different. The invention also provides a material for forming a light emitting or charge transporting polymer network comprising the photopolymerisable or photocrosslinkable reactive mesogen, a charge transporting or light emitting polymer network which is obtained by polymerisation or crosslinking of the mesogen, a process for the preparation of the polymer via photopolymerisation or photocrosslinking of suitable end-groups of the mesogen, a device comprising a polymer layer formed from the charge transporting or light emitting polymer network, a process for applying a charge transporting or light emitting polymer network to a surface and a backlight or display comprising a charge transporting or light emitting polymernetwork.

The present specification relates to an organic electronic device including a fullerene derivative.

Nanoparticle compositions comprising nanoparticles formed from -conjugated cross-linked polymers are disclosed, together with their methods of manufacture and their applications. Owing to the nature of the cross-links formed therein, the nanoparticle compositions afford a high degree of manufacturing flexibility and control, as well as being amenable to facile purification for the purpose of imaging and electronics applications.

An electrochromic device includes a first insulating substrate; a first conducting layer disposed over the first insulating substrate; an electrochromic layer disposed over the first conducting layer, an electrolyte layer disposed over the electrochromic layer; a second conducting layer disposed over the electrolyte layer; and a second insulating substrate disposed over the second conducting layer. The electrochromic layer includes an electrochromic polymer having a polymer backbone comprising one or more meta-conjugated linkers (MCLs) and one or more aromatic moieties (Ars). Each of the one or more MCLs is partially conjugated with one of the one or more Ars at a meta position of the one or more MCLs. The thickness of the electrochromic layer is from 10 nm to 5800 nm resulting in transmittance of 70%-99.9% at a wavelength of 550 nm at a neutral state of the electrochromic layer.