Processes for controlling afterburn in a reheater and loss of entrained solid particles in reheater flue gas are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium comprising combustible solid particles. The spent heat transfer medium is introduced into a fluidizing dense bed. The combustible solid particles of the spent heat transfer medium are combusted forming combustion product flue gas in a dilute phase above the fluidizing dense bed. The combustion product flue gas comprises flue gas and solid particles entrained therein. The solid particles are separated from the combustion product flue gas to form separated solid particles. At least a portion of the separated solid particles are returned to the fludizing dense bed.

Processes for controlling afterburn in a reheater and loss of entrained solid particles in reheater flue gas are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium comprising combustible solid particles. The spent heat transfer medium is introduced into a fluidizing dense bed. The combustible solid particles of the spent heat transfer medium are combusted forming combustion product flue gas in a dilute phase above the fluidizing dense bed. The combustion product flue gas comprises flue gas and solid particles entrained therein. The solid particles are separated from the combustion product flue gas to form separated solid particles. At least a portion of the separated solid particles are returned to the fluidizing dense bed.

Processes for controlling afterburn in a reheater and loss of entrained solid particles in reheater flue gas are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium comprising combustible solid particles. The spent heat transfer medium is introduced into a fluidizing dense bed. The combustible solid particles of the spent heat transfer medium are combusted forming combustion product flue gas in a dilute phase above the fluidizing dense bed. The combustion product flue gas comprises flue gas and solid particles entrained therein. The solid particles are separated from the combustion product flue gas to form separated solid particles. At least a portion of the separated solid particles are returned to the fluidizing dense bed.

The invention provides a pyrolysis reaction system, the system comprising: a pyrolysis chamber comprising a feed inlet, a gas inlet and a product outlet, wherein the pyrolysis chamber is configured i) to receive a pyrolysable organic feed and an inert gas via the feed inlet and gas inlet respectively, ii) to pyrolyse the organic feed at a pyrolysis temperature to produce a carbonaceous pyrolysis product and a pyrolysis gas, wherein the pyrolysis gas will combine with the inert gas to form a gas mixture having a pyrolysis chamber pressure in the pyrolysis chamber, and iii) to discharge the carbonaceous pyrolysis product via the product outlet; a gas reactor configured to react the pyrolysis gas by combustion and/or carbon deposition at a gas reaction temperature and a gas reactor pressure; and a first partition defining a boundary between the pyrolysis chamber and the gas reactor, the first partition comprising a plurality of first apertures to provide fluid communication between the pyrolysis chamber and the gas reactor, wherein the pyrolysis reaction system is operable with the gas reactor pressure less than the pyrolysis chamber pressure such that the gas mixture flows from the pyrolysis chamber to the gas reactor through the first apertures, thereby providing at least a portion of the pyrolysis gas for reaction in the gas reactor.

The invention provides a pyrolysis reaction system, the system comprising: a pyrolysis chamber comprising a feed inlet, a gas inlet and a product outlet, wherein the pyrolysis chamber is configured i) to receive a pyrolysable organic feed and an inert gas via the feed inlet and gas inlet respectively, ii) to pyrolyse the organic feed at a pyrolysis temperature to produce a carbonaceous pyrolysis product and a pyrolysis gas, wherein the pyrolysis gas will combine with the inert gas to form a gas mixture having a pyrolysis chamber pressure in the pyrolysis chamber, and iii) to discharge the carbonaceous pyrolysis product via the product outlet; a gas reactor configured to react the pyrolysis gas by combustion and/or carbon deposition at a gas reaction temperature and a gas reactor pressure; and a first partition defining a boundary between the pyrolysis chamber and the gas reactor, the first partition comprising a plurality of first apertures to provide fluid communication between the pyrolysis chamber and the gas reactor, wherein the pyrolysis reaction system is operable with the gas reactor pressure less than the pyrolysis chamber pressure such that the gas mixture flows from the pyrolysis chamber to the gas reactor through the first apertures, thereby providing at least a portion of the pyrolysis gas for reaction in the gas reactor.

Reactor for recovery or recycling of hydrocarbon products from hydrocarbon-containing material by decomposing and gasifying the material in a reactor housing, comprising a gas/particle separator device arranged to separate solid particles accompanying the gas and to return these particles directly to the reactor housing in the opposite direction to axially flowing gasified hydrocarbon products, and/or comprising a rotor shaft with axially running channels which are in flow communication with a coolant, and/or comprising a radial play formed between the periphery of a rotor and the inside of the reactor housing and amounting to at least 3 cm and at most 6 cm.

Reactor for recovery or recycling of hydrocarbon products from hydrocarbon-containing material by decomposing and gasifying the material in a reactor housing, comprising a gas/particle separator device arranged to separate solid particles accompanying the gas and to return these particles directly to the reactor housing in the opposite direction to axially flowing gasified hydrocarbon products, and/or comprising a rotor shaft with axially running channels which are in flow communication with a coolant, and/or comprising a radial play formed between the periphery of a rotor and the inside of the reactor housing and amounting to at least 3 cm and at most 6 cm.

A fluidized bed coking reactor apparatus comprises a reaction vessel; a temperature sensor inside the reaction vessel for measuring a reactor temperature, a solids feed mechanism for feeding solid particles into the reactor vessel at a mass flow rate, a feed material feed mechanism for feeding feed material into the reactor at an operating feed rate; and a supervisory controller programmed to determine an upper feed material feed rate of the reactor when operating at the reactor temperature and receiving solid particles at the mass flow rate. The upper feed material feed rate is defined as a feed rate of feed material deposited onto a selected fraction of a fluidized bed of solid particles that causes defluidization in the reactor when the reactor is operating under conditions having a selected degree of backmixing in the fluidized bed, wherein the degree of backmixing is modeled as a selected number of reactors arranged in series and each operating under continuous well-mixed conditions, with the selected number of reactors being an integer between one and infinity.

A fluidized bed coking reactor apparatus comprises a reaction vessel; a temperature sensor inside the reaction vessel for measuring a reactor temperature, a solids feed mechanism for feeding solid particles into the reactor vessel at a mass flow rate, a feed material feed mechanism for feeding feed material into the reactor at an operating feed rate; and a supervisory controller programmed to determine an upper feed material feed rate of the reactor when operating at the reactor temperature and receiving solid particles at the mass flow rate. The upper feed material feed rate is defined as a feed rate of feed material deposited onto a selected fraction of a fluidized bed of solid particles that causes defluidization in the reactor when the reactor is operating under conditions having a selected degree of backmixing in the fluidized bed, wherein the degree of backmixing is modeled as a selected number of reactors arranged in series and each operating under continuous well-mixed conditions, with the selected number of reactors being an integer between one and infinity.

The invention provides a pyrolysis reaction system, the system comprising: a pyrolysis chamber comprising a feed inlet, a gas inlet and a product outlet, wherein the pyrolysis chamber is configured i) to receive a pyrolysable organic feed and an inert gas via the feed inlet and gas inlet respectively, ii) to pyrolyse the organic feed at a pyrolysis temperature to produce a carbonaceous pyrolysis product and a pyrolysis gas, wherein the pyrolysis gas will combine with the inert gas to form a gas mixture having a pyrolysis chamber pressure in the pyrolysis chamber, and iii) to discharge the carbonaceous pyrolysis product via the product outlet; a gas reactor configured to react the pyrolysis gas by combustion and/or carbon deposition at a gas reaction temperature and a gas reactor pressure; and a first partition defining a boundary between the pyrolysis chamber and the gas reactor, the first partition comprising a plurality of first apertures to provide fluid communication between the pyrolysis chamber and the gas reactor, wherein the pyrolysis reaction system is operable with the gas reactor pressure less than the pyrolysis chamber pressure such that the gas mixture flows from the pyrolysis chamber to the gas reactor through the first apertures, thereby providing at least a portion of the pyrolysis gas for reaction in the gas reactor.