Patent classifications
C10G3/47
CONVERSION OF ALCOHOLS AND ALDEHYDES TO ENERGY-DENSE HYDROCARBON FUEL MIXTURES
The present disclosure relates to a process for preparing long-chain alkanes and alkenes from alcohols, aldehydes, or both. The process proceeds via acceptorless dehydrogenation and decarbonylative coupling using a supported catalyst.
Conversion of alcohols to hydrocarbons using a dual catalyst system comprising basic oxide on mixed oxide or mesoporous carrier and etched metal loaded zeolite catalyst
A method for converting an alcohol to hydrocarbons comprises two serially placed catalysts. The fraction of aromatics is reduced to desired levels. The method comprises: a) contacting the alcohol with a first catalyst on a carrier, said carrier is selected from a mixed oxide and a mesoporous carrier, said first catalyst comprises at least one basic oxide and optionally at least one selected from the group consisting of metals and metal oxides, then b) contacting the resulting mixture from step a) with a second catalyst wherein said second catalyst is an etched metal loaded zeolite catalyst wherein the etched metal loaded zeolite catalyst is manufactured with a method comprising etching with subsequent loading of metal onto the catalyst, wherein the metal is in the form of nanoparticles, and wherein at least two different metals are loaded onto the etched zeolite catalyst. The hydrocarbons are recovered and used for instance for fuel including gasoline, kerosene, diesel, and jet propellant, and jet fuel. Naturally, other uses of hydrocarbons should not be excluded.
Purification of recycled and renewable organic material
A method is disclosed of purifying a recycled or renewable organic material, wherein the recycled or renewable organic material includes more than 1 ppm silicon as silicon compounds. Exemplary steps include (a) providing the recycled or renewable organic material; (b) heat treating the recycled or renewable organic material to form a heat treated recycled or renewable organic material, wherein the at least part of silicon compounds present in the recycled or renewable organic material are converted to volatile silicon compounds, and (c) evaporating volatile silicon compounds from the heat treated recycled or renewable organic material to obtain recycled or renewable organic material fraction containing less silicon than the recycled or renewable organic material provided in step (a).
HIGH YIELD JET FUEL AND CHEMICALS FROM OZONOLYSIS OF TRIGLYCERIDES
A method for producing jet range hydrocarbons may include reacting at least a portion a fatty acid stream comprising C18:1 free fatty acid with ozone in an ozonolysis unit to form at least a C18:1 ozonide intermediate; introducing the C18:1 ozonide intermediate into a reactor, wherein at least a portion of the C18:1 ozonide intermediate is reacted with a reductive agent to produce oxidized products comprising azelaic acid and nonanoic acid; and introducing the oxidized products into a hydrotreating unit, wherein at least a portion of the oxidized products is hydrotreated to produce a paraffin product comprising nonane.
Diesel fuel composition
A diesel fuel composition containing a renewable diesel component and oxymethylene ethers having molecular structure CH3O—(CH2O)n-CH3 with n=3-5 (OME3-5). A method for producing a diesel fuel composition and use thereof. Use of OME3-5 to decrease particle emission of renewable diesel fuels is further disclosed.
Process for the production of olefinic compounds and a hydrocarbon fuel or a fraction thereof
The present invention relates to a process for the production of olefinic compounds that can be used for the production of detergents, additives, lubricants and/or plastic materials, or components which can be used in the field of oil explorations and productions, and a hydrocarbon fuel or a fraction thereof, which comprises subjecting a mixture of glycerides having at least one unsaturated hydrocarbon chain, to metathesis reaction and, after separating the olefinic mixture obtained, effecting a hydrodeoxygenation and subsequently hydroisomerization process, so as to obtain the hydrocarbon fuel or a fraction thereof.
Process for producing low sulphur oxygen containing renewable oil
The invention relates to a process for producing an upgraded renewable oil from renewable carbonaceous material(-s) comprising providing a low sulphur oxygen containing renewable crude oil having a sulphur content of less than 0.5 wt % and an oxygen content from about 2.0 wt to about 20 wt %, pressurising the low sulphur oxygen containing renewable crude oil to an operational pressure in the range 20 to 200 bar, adding and mixing hydrogen to the pressurized low sulphur oxygen containing crude oil, heating the oil to an operational temperature in the range 180-410° C. in one or more steps, contacting said oil with at least one heterogeneous catalyst contained in a first reaction zone, contacting the effluent from said first reaction zone with at least one heterogeneous catalyst contained in a second reaction zone, where in at least one of the heterogeneous catalysts in the first reaction zone and/or the second reaction zone is on a non-sulphided form.
METHOD FOR PRODUCING RENEWABLE BASE OIL AND RENEWABLE FUEL COMPONENTS
The present disclosure relates to methods for producing renewable base oil and other valuable renewable fuel components from a feedstock of biological origin comprising free fatty acids and glycerides. The feedstock is first separated to two or more effluent streams containing a fatty acid fraction and glyceride fraction. The glycerides are hydrolyzed to free fatty acids and glycerol, and the fatty acids thus obtained are recycled to the separating. The fatty acids are then converted to the base oil by ketonisation, hydrodeoxygenation and hydroisomerisation. The glycerol is converted to propanols by selective hydrogenolysis.
SELECTIVE HYDROXYL GROUP REMOVAL FROM ALKYLPHENOLS
A process for selective removal of hydroxyl groups from phenolic compounds is disclosed. The process uses a combination of catalytic hydrodeoxygenation and catalytic direct deoxygenation to convert alkylphenols into alkylbenzenes.
Process and apparatus for recycling hydrogen to hydroprocess biorenewable feed
The process and apparatus enables purification of a recycle hydrogen gas stream from hydroprocessing biorenewable feedstocks. The recycle gas stream is fed to a methanator reactor to hydrogenate carbon monoxide in the gas stream to water and methane. Other acid gases can be removed by scrubbing preferably upstream of the methanator. Removal of carbon monoxide omits the need for a hydrogen purge stream to avoid carbon monoxide accumulation and enables use of the hydrogen for a downstream hydroisomerization reaction.