Patent classifications
C10G3/48
SYSTEMS AND PROCESSES FOR LIPID FEEDSTOCK TREATMENT WITH MOVING BED REACTOR
A lipid feedstock including fatty acid(s) is treated in a process flow through a moving bed reactor with catalyst to produce a treated stream. The catalyst may include metal oxide catalyst on a particulate oxide support. The catalyst may be transferred, using a catalyst withdrawal line, from the bottom of the moving bed reactor to a fluidized bed regenerator, and regenerated. The catalyst may be transferred from the fluidized bed regenerator to a cyclone that separates the catalyst from flue gas. The catalyst may be transferred from the cyclone to the top of the moving bed reactor using a catalyst feed line. A first separation gas may be flowed into the catalyst feedline, and a second separation gas may be flowed into the bottom of the moving bed reactor or into the catalyst withdrawal line, to generate pressure differentials driving the process flow through the moving bed reactor.
Process for integrated production of renewable fuels and chemicals
The present disclosure provides a versatile process for producing valuable renewable hydrocarbons from triglyceride containing feedstock. The triglyceride containing feedstock is first split to provide a mixture containing fatty acids, glycerol and water, from which a phase separation provides an oily phase, and an aqueous phase. The oily phase containing fatty acids is subjected to fractionation, whereby specific fractions may be refined to products with controlled hydroprocessing. Products may contain paraffinic renewable aviation fuel components, paraffinic renewable base oil, renewable paraffinic diesel fuel components, renewable paraffinic technical fluid, or any combination thereof.
Method for Catalytic Deoxygenation of Natural Oils and Greases
A method for deoxygenating renewable oils comprised of natural oils or greases or derivatives thereof containing triglycerides or free fatty acids includes the steps of: providing a catalyst comprising a support predominantly comprised of alumina with metal compounds provided on the support based on Mo and at least one selected from the group consisting of Ni and Co, and at least one selected from the group consisting of Cu and Cr, and contacting the renewable oils with the catalyst under conditions sufficient to deoxygenate the renewable oils.
PROCESS OF CONVERTING NATURAL PLANT OILS TO BIOFUELS
The conversion of renewable feedstock, particularly camelina oil, into jet fuel and other high-value chemicals. The conversion comprises the processes of alkene metathesis, dehydrogenation, hydrogenation, and vacuum distillation.
Production of aromatics from di- and polyoxygenates
Methods, catalysts, and reactor systems for producing in high yield aromatic chemicals and liquid fuels from a mixture of oxygenates comprising di- and polyoxygenates are disclosed. Also disclosed are methods, catalysts, and reactor systems for producing aromatic chemicals and liquid fuels from oxygenated hydrocarbons such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like; and methods, catalysts, and reactor systems for producing the mixture of oxygenates from oxygenated hydrocarbons such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like. The disclosed catalysts for preparing the mixture of oxygenates comprise a Ni.sub.nSn.sub.m alloy and a crystalline alumina support.
Process for producing hydrocarbons
The present invention relates to process for producing hydrocarbons, wherein starting material comprising tall oil material and polar co-feed, which polar co-feed comprises fatty acids, is diluted with a non-polar diluent to obtain feedstock, and said feedstock is catalytically hydroprocessed to obtain hydrocarbons, suitable as fuels, fuel blending components and fuel additives.
Process for producing hydrocarbons
The present invention relates to a process for converting feedstock comprising materials of biological origin into hydrocarbons, said process comprising the steps where a) feedstock comprising at least one material of biological origin is subjected to purification treatment to obtain purified feedstock, and b) the purified feedstock is subjected to hydroprocessing in the presence of at least one hydrodeoxygenation catalyst, at least one hydrodewaxing catalyst and at least one hydrodearomatization catalyst to obtain a hydroprocessing product.
CONVERSION OF SOLID BIOMASS INTO A LIQUID HYDROCARBON MATERIALS
The present invention provides a process for producing liquid hydrocarbon products from a solid biomass feedstock, said process comprising the steps of: a) providing in a first hydropyrolysis reactor vessel a first hydropyrolysis catalyst composition, said composition comprising one or more active metals selected from cobalt, molybdenum, nickel, tungsten, ruthenium, platinum, palladium, iridium and iron on an oxide support, wherein the one or more active metals are present in an oxidic state; b) contacting the solid biomass feedstock with said first hydropyrolysis catalyst composition and molecular hydrogen in said first hydropyrolysis reactor vessel at a temperature in the range of from 350 to 600 C. and a pressure in the range of from 0.50 to 7.50 MPa, to produce a product stream comprising partially deoxygenated hydropyrolysis product, H.sub.2O, H.sub.2, CO.sub.2, CO, C.sub.1-C.sub.3 gases, char and catalyst fines; c) removing said char and catalyst fines from said product stream; d) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalyst and of the H.sub.2O, CO.sub.2, CO, H.sub.2, and C.sub.1-C.sub.3 gas generated in step a), to produce a vapour phase product 25 comprising substantially fully deoxygenated hydrocarbon product, H.sub.2O, CO, CO.sub.2, and C.sub.1-C.sub.3 gases.
Optimized method for recycling bio-oils into hydrocarbon fuels
A process for the production of hydrocarbon products from a feed comprising at least one non-pre-treated bio-oil, comprising a first step for hydroreforming in the presence of hydrogen and a hydroreforming catalyst, used alone or as a mixture, to obtain at least one liquid effluent comprising at least one aqueous phase and at least one organic phase, a second step in which at least a portion of the organic phase of the effluent obtained from the first hydroreforming step is recycled to the first hydroreforming step with a recycle ratio equal to the ratio of the mass flow rate of said organic phase to the mass flow rate of the non-pre-treated bio-oil in the range 0.05 to 2 and in which the hydrocarbon effluent obtained from the hydrotreatment and/or hydrocracking step is not recycled to said first hydroreforming step.
CONVERSION OF SOLID BIOMASS INTO A LIQUID HYDROCARBON MATERIAL
The present invention provides a process for producing liquid hydrocarbon products from a solid biomass feedstock, said process comprising the steps of:
a) providing in a first hydropyrolysis reactor vessel a first hydropyrolysis catalyst composition;
b) contacting the solid biomass feedstock with said first hydropyrolysis catalyst composition and molecular hydrogen in said first hydropyrolysis reactor vessel to produce a product stream comprising partially deoxygenated hydropyrolysis product, H2O, H2, CO2, CO, C1-C3 gases, char and catalyst fines;
c) removing said char and catalyst fines from said product stream;
d) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalyst and of the H.sub.2O, CO.sub.2, CO, H.sub.2, and C.sub.1-C.sub.3 gas generated in step a), to produce a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H.sub.2O, CO, CO.sub.2, and C.sub.1-C.sub.3 gases.