C10G21/16

Chemical process for sulfur reduction of hydrocarbons

Treatment of hydrocarbon streams, and in one non-limiting embodiment refinery distillates, with reducing agents, such as borohydride and salts thereof, alone or together with at least one co-solvent results in reduction of the sulfur compounds such as disulfides, mercaptans, thiophenes, and thioethers that are present to give easily removed sulfides. In one non-limiting embodiment, the treatment converts the original sulfur compounds into hydrogen sulfide or low molecular weight mercaptans that can be extracted from the distillate with caustic solutions, hydrogen sulfide or mercaptan scavengers, solid absorbents such as clay or activated carbon or liquid absorbents such as amine-aldehyde condensates and/or aqueous aldehydes.

Method and system for removing hydrogen sulfide from sour oil and sour water

Embodiments of the present invention are generally related to a system and method to remove hydrogen sulfide from sour water and sour oil. In particular, hydrogen sulfide is removed from sour water and sour oil without the need for special chemicals, such as catalyst chemicals, scavenger chemicals, hydrocarbon sources, or a large scale facility. The system and method in the present invention is particularly useful in exploratory oil and gas fields, where large facilities to remove hydrogen sulfide may be inaccessible. The present invention addresses the need for safe and cost effective transport of the deadly neurotoxin. Particular embodiments involve a system and method that can be executed both on a small and large scale to sweeten sour water and sour oil.

Method and system for removing hydrogen sulfide from sour oil and sour water

Embodiments of the present invention are generally related to a system and method to remove hydrogen sulfide from sour water and sour oil. In particular, hydrogen sulfide is removed from sour water and sour oil without the need for special chemicals, such as catalyst chemicals, scavenger chemicals, hydrocarbon sources, or a large scale facility. The system and method in the present invention is particularly useful in exploratory oil and gas fields, where large facilities to remove hydrogen sulfide may be inaccessible. The present invention addresses the need for safe and cost effective transport of the deadly neurotoxin. Particular embodiments involve a system and method that can be executed both on a small and large scale to sweeten sour water and sour oil.

Composition and a process for reducing aromatics from a hydrocarbon feedstock

The present disclosure relates to a composition for reducing aromatics from a hydrocarbon feedstock. The composition comprises a solvent mixture. The solvent mixture includes a primary solvent, a first co-solvent, a second co-solvent, and a secondary solvent. The present disclosure also relates to a process for reducing aromatics from a hydrocarbon feedstock.

Composition and a process for reducing aromatics from a hydrocarbon feedstock

The present disclosure relates to a composition for reducing aromatics from a hydrocarbon feedstock. The composition comprises a solvent mixture. The solvent mixture includes a primary solvent, a first co-solvent, a second co-solvent, and a secondary solvent. The present disclosure also relates to a process for reducing aromatics from a hydrocarbon feedstock.

Separation of fractions in hydrocarbon samples using an accelerated solvent extractor

A method and a system for separating and recovering an entire liquid hydrocarbon sample using an accelerated solvent extractor is disclosed. In the method, a filter is inserted into a bottom portion of an extraction cell of the accelerated solvent extractor. An adsorbent is activated via heating in a furnace and then cooled. At least a portion of the adsorbent is then inserted into the extraction cell and a liquid hydrocarbon sample is introduced into the extraction cell on top of the adsorbent. The extraction cell comprising the sample is placed in a cell tray of the accelerated solvent extractor and the saturate, aromatics, and resins fractions of the sample are sequentially extracted using first, second and third solvents, respectively. The entire liquid hydrocarbon sample is extracted as a result of the method.

Separation of fractions in hydrocarbon samples using an accelerated solvent extractor

A method and a system for separating and recovering an entire liquid hydrocarbon sample using an accelerated solvent extractor is disclosed. In the method, a filter is inserted into a bottom portion of an extraction cell of the accelerated solvent extractor. An adsorbent is activated via heating in a furnace and then cooled. At least a portion of the adsorbent is then inserted into the extraction cell and a liquid hydrocarbon sample is introduced into the extraction cell on top of the adsorbent. The extraction cell comprising the sample is placed in a cell tray of the accelerated solvent extractor and the saturate, aromatics, and resins fractions of the sample are sequentially extracted using first, second and third solvents, respectively. The entire liquid hydrocarbon sample is extracted as a result of the method.

Method for treating a hydrocarbon feedstock comprising a deasphalting step and an asphalt conditioning step

The invention relates to a process for treating a hydrocarbon-based feedstock, comprising a) a step of extracting the feedstock, b) a step of separating the fraction comprising de-asphalted oil, c) an optional step of injecting a withdrawal flux into the fraction comprising asphalt, d) an optional step of separating the fraction comprising asphalt and solvent or solvent mixture obtained from the extraction step a), e) an optional step of injecting a withdrawal flux into the asphalt fraction alone or as a mixture with a withdrawal flux obtained from step d) and an integrated step of conditioning the asphalt fraction obtained from steps a) and/or c) and/or d) and/or e), in solid form, performed in successive or simultaneous substeps.

Method for treating a hydrocarbon feedstock comprising a deasphalting step and an asphalt conditioning step

The invention relates to a process for treating a hydrocarbon-based feedstock, comprising a) a step of extracting the feedstock, b) a step of separating the fraction comprising de-asphalted oil, c) an optional step of injecting a withdrawal flux into the fraction comprising asphalt, d) an optional step of separating the fraction comprising asphalt and solvent or solvent mixture obtained from the extraction step a), e) an optional step of injecting a withdrawal flux into the asphalt fraction alone or as a mixture with a withdrawal flux obtained from step d) and an integrated step of conditioning the asphalt fraction obtained from steps a) and/or c) and/or d) and/or e), in solid form, performed in successive or simultaneous substeps.

Functionalized aldehydes as H.SUB.2.S and mercaptan scavengers

Certain functionalized aldehydes scavengers may be used to at least partially scavenge sulfur-containing contaminants from fluid systems containing hydrocarbons and/or water. The contaminants scavenged or otherwise removed include, but are not necessarily limited to, H.sub.2S, mercaptans, and/or sulfides. Suitable scavengers include, but are not necessarily limited to, reaction products of glycolaldehyde with aldehydes; reaction products of glycolaldehyde with a nitrogen-containing reactant (e.g. an amine, a triazine, an imine, an aminal, and/or polyamines); non-nitrogen-containing reaction products of a hydrated aldehyde with certain second aldehydes; reaction products of 1,3,5-trioxane with hydroxyl-rich compounds (e.g. glyoxal, polyethylene glycol, polypropylene glycol, pentaerythritol, and/or sugars); and reaction products of certain aldehydes with certain phenols; and combinations of these reaction products.