A method and composition is described for reducing the levels of hydrogen sulfide in a fluid such as a hydrocarbon stream. The method involves contacting the gas stream with a composition comprising a mixture of amines reacted with formaldehyde. The composition reduces the formation and deposition of solids commonly associated with spent triazine scavengers.

A method and composition is described for reducing the levels of hydrogen sulfide in a fluid such as a hydrocarbon stream. The method involves contacting the gas stream with a composition comprising a mixture of amines reacted with formaldehyde. The composition reduces the formation and deposition of solids commonly associated with spent triazine scavengers.

A ionic liquid composition to remove sulfur from refined crude oil fraction, comprising or consisting of two or more compounds having: —an imidazolium cation substituted by one or more straight or branched C.sub.1-C.sub.6 alkyl group and —an anion selected from the group consisting of R.sub.5COO, CI., Br, [BF.sub.4], [PF.sub.6]—, [SbF.sub.6]—, [R.sub.6SO.sub.4], [OTs], [OMs], wherein R5 is C.sub.1-C.sub.8 alkyl, Cs—Cs cycloalkyl, benzyl, C.sub.2-C.sub.6 alkenyl, and R6 is C.sub.1-C.sub.6 alkyl.

A ionic liquid composition to remove sulfur from refined crude oil fraction, comprising or consisting of two or more compounds having: —an imidazolium cation substituted by one or more straight or branched C.sub.1-C.sub.6 alkyl group and —an anion selected from the group consisting of R.sub.5COO, CI., Br, [BF.sub.4], [PF.sub.6]—, [SbF.sub.6]—, [R.sub.6SO.sub.4], [OTs], [OMs], wherein R5 is C.sub.1-C.sub.8 alkyl, Cs—Cs cycloalkyl, benzyl, C.sub.2-C.sub.6 alkenyl, and R6 is C.sub.1-C.sub.6 alkyl.

The methods described herein produce a naphthenic process oil, as classified by ASTM D-2226, containing 35-65% saturates and 35-65% aromatics as determined by ASTM D-2007. The produced naphthenic process oil also contains polyaromatic hydrocarbons (PAH), more specifically the EU/US EPA 8-regulated PAHs, less than 10 ppm. The naphthenic process oil is produced by first feeding gas oil ranging in viscosities up to 20 cSt at 100° C. through counter-current liquid-liquid extraction towers with a solvent having a selective affinity for aromatics. The extract is then cooled and either continuously processed through a coalescing separator or batch processed in a tank or decanter to produce a second raffinate, which can be further distilled to produce the naphthenic process oil.

An aspect of the present disclosure relates to a process for solvent deasphalting dearomatization, said process including: effecting deasphaltenation of a heavy oil feed by contacting the feed with a paraffinic rich solvent, optionally, in presence of a FCC catalyst to obtain a deasphalted oil rich stream, said paraffinic rich solvent being untreated naphtha; contacting the DAO rich stream with a second solvent to obtain a raffinate stream rich in non-asphaltene and non-aromatic contents and a solvent rich stream; contacting the raffinate stream with water in a first decanter to obtain a first stream rich in aromatic-lean fraction and a second stream rich in the second solvent and water; subjecting the first stream to distillation to recover the paraffinic rich solvent and to obtain deasphalted oil; contacting the solvent rich stream with water in a second decanter to obtain an aromatic rich fraction and a third stream rich in the second solvent and water; and subjecting the second stream and the third stream to distillation to recover the second solvent and water.

An aspect of the present disclosure relates to a process for solvent deasphalting dearomatization, said process including: effecting deasphaltenation of a heavy oil feed by contacting the feed with a paraffinic rich solvent, optionally, in presence of a FCC catalyst to obtain a deasphalted oil rich stream, said paraffinic rich solvent being untreated naphtha; contacting the DAO rich stream with a second solvent to obtain a raffinate stream rich in non-asphaltene and non-aromatic contents and a solvent rich stream; contacting the raffinate stream with water in a first decanter to obtain a first stream rich in aromatic-lean fraction and a second stream rich in the second solvent and water; subjecting the first stream to distillation to recover the paraffinic rich solvent and to obtain deasphalted oil; contacting the solvent rich stream with water in a second decanter to obtain an aromatic rich fraction and a third stream rich in the second solvent and water; and subjecting the second stream and the third stream to distillation to recover the second solvent and water.

An oil desulfurization method may be used to desulfurize various oils, such as used motor oil, crude oil, diesel, high sulfur fuel oil, mid sulfur fuel oil, off-spec fuel oil, and off-spec diesel, to produce a finished product of lower sulfur oil and a high sulfur fuel oil or sulfur containing oil product. Preferably, the method may include the steps of: mixing an oxidizing material with sulfur containing oil to produce a first mixture; subjecting the first mixture to at least one of heat and pressure to oxidize the sulfur in the first mixture; mixing at least one solvent with the first mixture to produce a second mixture; and separating the second mixture to produce a low sulfur oil product and a third mixture, the third mixture having a high sulfur oxidized oil and the at least one solvent.

An oil desulfurization method may be used to desulfurize various oils, such as used motor oil, crude oil, diesel, high sulfur fuel oil, mid sulfur fuel oil, off-spec fuel oil, and off-spec diesel, to produce a finished product of lower sulfur oil and a high sulfur fuel oil or sulfur containing oil product. Preferably, the method may include the steps of: mixing an oxidizing material with sulfur containing oil to produce a first mixture; subjecting the first mixture to at least one of heat and pressure to oxidize the sulfur in the first mixture; mixing at least one solvent with the first mixture to produce a second mixture; and separating the second mixture to produce a low sulfur oil product and a third mixture, the third mixture having a high sulfur oxidized oil and the at least one solvent.

A method for preparing feed material for a catalytic depolymerisation process, the method comprising the steps of: separating feedstock into two or more feedstock streams based on one or more properties of the feedstock, introducing each of the two or more feedstock streams into one or more process vessels, processing the feedstock streams in the presence of a catalyst in the process vessels under conditions of elevated temperature in order to produce two or more intermediate feedstock streams, and blending the two or more intermediate feedstock streams to form the feed material.