Systems and processes for hydrotreating, splitting, and extracting a gasoil feed to produce a saturate-rich feedstock for olefin pyrolysis are provided. A gasoil feed is provided to a hydrotreating section to produce an ultralow sulfur distillate (ULSD) stream. The ULSD stream is provided to a splitter section to produce a light distillate stream and a heavy bottom stream. The light distillate stream is provided to an extraction section to produce an aromatic-rich extract phase and a saturate-rich raffinate phase. The raffinate phase is mixed with the heavy bottom stream to produce an olefin pyrolysis feedstock having a reduced BMCI as compared to the gasoil feed stream and the ULSD stream.

Systems and processes for hydrotreating, splitting, and extracting a gasoil feed to produce a saturate-rich feedstock for olefin pyrolysis are provided. A gasoil feed is provided to a hydrotreating section to produce an ultralow sulfur distillate (ULSD) stream. The ULSD stream is provided to a splitter section to produce a light distillate stream and a heavy bottom stream. The light distillate stream is provided to an extraction section to produce an aromatic-rich extract phase and a saturate-rich raffinate phase. The raffinate phase is mixed with the heavy bottom stream to produce an olefin pyrolysis feedstock having a reduced BMCI as compared to the gasoil feed stream and the ULSD stream.

Oxidized disulfide oil (ODSO) compounds, derived from by-product disulfide oil (DSO) compounds produced as by-products from the generalized mercaptan oxidation (MEROX) in the practice of the process, are effective as aromatic extraction solvents. This use of ODSO compounds as an extraction solvent converts an otherwise DSO waste oil product into a valuable commodity that has utility in improving the extraction of aromatics from hydrocarbons derived from fossil fuels.

Oxidized disulfide oil (ODSO) compounds, derived from by-product disulfide oil (DSO) compounds produced as by-products from the generalized mercaptan oxidation (MEROX) in the practice of the process, are effective as aromatic extraction solvents. This use of ODSO compounds as an extraction solvent converts an otherwise DSO waste oil product into a valuable commodity that has utility in improving the extraction of aromatics from hydrocarbons derived from fossil fuels.

The invention provides a method for pretreating a hydrocarbon steam cracker feed, comprising contacting the feed with a solvent to produce a pretreated feed having a reduced content of fouling components that cause fouling in the preheat, convection and radiant sections of the steam cracker and a rich solvent having an increased content of fouling components. The invention further provides a method for steam cracking hydrocarbons comprising: a) feeding a hydrocarbon steam cracker feed to the process; b) pretreating the feed by contacting the feed with a solvent to produce a pretreated feed having a reduced content of fouling components that cause fouling in the steam cracker and a rich solvent having an increased content of fouling components; c) heating the pretreated feed; and d) passing the pretreated feed through a steam cracker under cracking conditions to produce cracked products.

A process for upgrading a pyrolysis oil comprising treating the pyrolysis oil with an upgrading solution to provide a mixture comprising an extract phase and a raffinate phase, wherein the upgrading solution comprises a polar organic solvent, and wherein the pyrolysis oil is a derived from the pyrolysis of plastic or rubber, or a combination thereof, and an upgraded pyrolysis oil prepared by said process.

A process for upgrading a pyrolysis oil comprising treating the pyrolysis oil with an upgrading solution to provide a mixture comprising an extract phase and a raffinate phase, wherein the upgrading solution comprises a polar organic solvent, and wherein the pyrolysis oil is a derived from the pyrolysis of plastic or rubber, or a combination thereof, and an upgraded pyrolysis oil prepared by said process.

A process for upgrading a pyrolysis oil comprising treating the pyrolysis oil with an upgrading solution to provide a mixture comprising an extract phase and a raffinate phase, wherein the upgrading solution comprises a polar organic solvent, and wherein the pyrolysis oil is a derived from the pyrolysis of plastic or rubber, or a combination thereof, and an upgraded pyrolysis oil prepared by said process.

A process for upgrading a pyrolysis oil comprising treating the pyrolysis oil with an upgrading solution to provide a mixture comprising an extract phase and a raffinate phase, wherein the upgrading solution comprises a polar organic solvent, and wherein the pyrolysis oil is a derived from the pyrolysis of plastic or rubber, or a combination thereof, and an upgraded pyrolysis oil prepared by said process.

A method of upgrading a petroleum feedstock, the method comprising the steps of introducing a disulfide oil, a water feed, and a petroleum feedstock to a supercritical water upgrading unit, and operating the supercritical water upgrading unit to produce a product gas stream, a product oil stream, and a used water stream.