Provided is a composition for removing a sulfur-containing compound present in liquid or vapor, the sulfur-containing compound being hydrogen sulfide, an SH group-containing compound or a mixture thereof, the composition containing an ,-unsaturated aldehyde represented by the following general formula (1) as an active ingredient;

##STR00001##

wherein R.sup.1 and R.sup.2 each independently represent an alkyl group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or an aryl group having 6 to 12 carbon atoms, or are connected to each other to represent an alkylene group having 2 to 6 carbon atoms; and R.sup.3 represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, or is connected to R.sup.1 to represent an alkylene group having 2 to 6 carbon atoms.

Provided is a composition for removing a sulfur-containing compound present in liquid or vapor, the sulfur-containing compound being hydrogen sulfide, an SH group-containing compound or a mixture thereof, the composition containing an ,-unsaturated aldehyde represented by the following general formula (1) as an active ingredient;

##STR00001##

wherein R.sup.1 and R.sup.2 each independently represent an alkyl group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms or an aryl group having 6 to 12 carbon atoms, or are connected to each other to represent an alkylene group having 2 to 6 carbon atoms; and R.sup.3 represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, or is connected to R.sup.1 to represent an alkylene group having 2 to 6 carbon atoms.

Methods for making sulfide scavenging compositions are provided. The method comprises reducing a settling velocity of the sulfide scavenging composition in a fluid stream by adjusting the specific gravity of the sulfide scavenging composition to within about fifteen percent or less of the specific gravity of the fluid stream. Sulfide scavengers using the above method are also disclosed. Methods for removing sulfides from fluid streams are also provided. The methods include adding the above sulfide scavengers to fluid streams.

Methods for making sulfide scavenging compositions are provided. The method comprises reducing a settling velocity of the sulfide scavenging composition in a fluid stream by adjusting the specific gravity of the sulfide scavenging composition to within about fifteen percent or less of the specific gravity of the fluid stream. Sulfide scavengers using the above method are also disclosed. Methods for removing sulfides from fluid streams are also provided. The methods include adding the above sulfide scavengers to fluid streams.

A process for upgrading a heavy oil, the process comprising the steps of introducing a heavy oil feed to a partial oxidation unit; introducing a water feed to a partial oxidation unit; introducing an oxidant feed to a partial oxidation unit, where the oxidant feed comprises an oxidant; processing the heavy oil feed, the water feed, and the oxidant feed in the partial oxidation unit to produce a liquid oxidation product, where the liquid oxidation product comprises oxygenates; introducing the liquid oxidation product to a supercritical water unit; introducing a water stream to the supercritical water unit; and processing the liquid oxidation product and the water stream in the supercritical water unit to produce an upgraded product stream, the upgraded product stream comprising upgraded hydrocarbons relative to the heavy oil feed.

Provided is a composition for removing iron sulfide, containing, as an active ingredient, an ,-unsaturated aldehyde represented by the following general formula (1):

##STR00001##

wherein R.sup.1 to R.sup.3 each independently represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, or an aryl group having 6 to 12 carbon atoms, provided that R.sup.1 may be connected to R.sup.2 or R.sup.3, to constitute an alkylene group having 2 to 6 carbon atoms; and that R.sup.1 and R.sup.2 are not a hydrogen atom at the same time.

This invention provides a composition comprising I. at least one reaction product between a nitrogen-free monohydric alcohol and an aldehyde or ketone, and II. at least one reaction product between a monosaccharide having 3 to 6 carbon atoms and/or an oligosaccharide being formed by oligomerization of monosaccharides having 3 to 6 carbon atoms and an aldehyde or ketone, and optionally III. at least one reaction product from III.a) formaldehyde, and III.b) an amine, selected from the group consisting of primary alkyl amines having 1 to 4 carbon atoms, and primary hydroxy alkyl amines having 2 to 4 carbon atoms, and optionally IV. at least one solid suppression agent selected from the group consisting of IV(a). alkali or alkaline earth metal hydroxides IV(b). mono-, di- or tri-hydroxy alkyl, aryl or alkylaryl amines, IV(c). mono-, di- or tri-alkyl, aryl or alkylaryl primary, secondary and tertiary amines or IV(d). multifunctional amines and IV(e). mixtures of compounds of groups IV(a) to IV(c). wherein alkyl is C.sub.1 to C.sub.15, aryl is C.sub.6 to C.sub.15 and alkylaryl is C.sub.7 to C.sub.15.

This invention provides a composition comprising I. at least one reaction product between a nitrogen-free monohydric alcohol and an aldehyde or ketone, and II. at least one reaction product between a monosaccharide having 3 to 6 carbon atoms and/or an oligosaccharide being formed by oligomerization of monosaccharides having 3 to 6 carbon atoms and an aldehyde or ketone, and optionally III. at least one reaction product from III.a) formaldehyde, and III.b) an amine, selected from the group consisting of primary alkyl amines having 1 to 4 carbon atoms, and primary hydroxy alkyl amines having 2 to 4 carbon atoms, and optionally IV. at least one solid suppression agent selected from the group consisting of IV(a). alkali or alkaline earth metal hydroxides IV(b). mono-, di- or tri-hydroxy alkyl, aryl or alkylaryl amines, IV(c). mono-, di- or tri-alkyl, aryl or alkylaryl primary, secondary and tertiary amines or IV(d). multifunctional amines and IV(e). mixtures of compounds of groups IV(a) to IV(c). wherein alkyl is C.sub.1 to C.sub.15, aryl is C.sub.6 to C.sub.15 and alkylaryl is C.sub.7 to C.sub.15.

The disclosure pertains to methods and systems for converting inactive chemicals into active chemicals in-situ for treating oil and gas pipelines, other industrial systems, or sanitizing surfaces. A method of treating an oil and gas pipeline is disclosed. The method may include feeding an inactive additive through a first conduit and into a second conduit, wherein the second conduit is in fluid communication with the first conduit and the oil and gas pipeline. The method also includes converting the inactive additive into an active additive within the second conduit and introducing the active additive into the oil and gas pipeline.

The disclosure pertains to methods and systems for converting inactive chemicals into active chemicals in-situ for treating oil and gas pipelines, other industrial systems, or sanitizing surfaces. A method of treating an oil and gas pipeline is disclosed. The method may include feeding an inactive additive through a first conduit and into a second conduit, wherein the second conduit is in fluid communication with the first conduit and the oil and gas pipeline. The method also includes converting the inactive additive into an active additive within the second conduit and introducing the active additive into the oil and gas pipeline.