Patent classifications
C10G35/095
Integration process for pyrolysis oil upgrading with maximized BTX yield
A method for producing aromatic compounds from pyrolysis oil comprises: upgrading the pyrolysis oil to pyrolysis gasoline in a multi-stage reactor comprising a slurry-phase reactor and a fixed-bed reactor, wherein the slurry-phase reactor comprises a mixed metal oxide catalyst, and the fixed-bed reactor comprises a mesoporous zeolite-supported metal catalyst; aromatizing the pyrolysis gasoline in an aromatization unit; hydrodealkylating and transalkylating a product from the aromatization unit in a hydrodealkylation-transalkylation unit, thereby producing an aromatic stream; and processing the aromatic stream in an aromatics recovery complex to produce the aromatic compounds comprising benzene, toluene, and xylenes (BTX).
Molecular sieves and a process for making molecular sieves
Processes are provided for preparing molecular sieves. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of nonionic surfactants, anionic surfactants, sugars and combinations thereof.
Molecular sieves and a process for making molecular sieves
Processes are provided for preparing molecular sieves. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of nonionic surfactants, anionic surfactants, sugars and combinations thereof.
Molecular sieves and a process for making molecular sieves
Processes are provided for preparing molecular sieves of framework structure MEI, TON, MRE, MWW, MFS, MOR, FAU, EMT, or MSE. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of cationic surfactants having a quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars and combinations thereof.
Molecular sieves and a process for making molecular sieves
Processes are provided for preparing molecular sieves of framework structure MEI, TON, MRE, MWW, MFS, MOR, FAU, EMT, or MSE. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of cationic surfactants having a quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars and combinations thereof.
Catalyst for Producing C8 Aromatic Hydrocarbon Having Reduced Ethylbenzene Content and Preparation Method Therefor
Disclosed are a catalyst and a preparation method therefor, the catalyst being able to maintain a high production yield of C8 aromatic hydrocarbons in the process of converting a feedstock containing alkyl aromatics to C8 aromatic hydrocarbons such as mixed xylene through disproportionation/transalkylation/dealkylation while reducing a content of ethylbenzene in the products.
Catalyst for Producing C8 Aromatic Hydrocarbon Having Reduced Ethylbenzene Content and Preparation Method Therefor
Disclosed are a catalyst and a preparation method therefor, the catalyst being able to maintain a high production yield of C8 aromatic hydrocarbons in the process of converting a feedstock containing alkyl aromatics to C8 aromatic hydrocarbons such as mixed xylene through disproportionation/transalkylation/dealkylation while reducing a content of ethylbenzene in the products.
Aromatization catalyst and methods of making and using same
A process of making an aromatization catalyst comprising: (a) mixing a zeolite, a binder, and water to form a mixture; (b) extruding the mixture to form a green extrudate; (c) drying the green extrudate to form a dried green extrudate; (d) calcining the dried green extrudate to form a support, wherein calcining the dried green extrudate is the only calcination step in the process; (e) washing the support to form a washed support; (f) drying the washed support to form a dried washed support; (g) impregnating the dried washed support with a Group 8-10 transition metal compound and at least one halide-containing compound to form a metalized-halided material; and (h) vacuum drying the metalized-halided material to form a dried metalized-halided material which is the aromatization catalyst.
PROCESSING OF PARAFFINIC NAPHTHA WITH MODIFIED USY ZEOLITE DEHYDROGENATION CATALYST
Methods for processing paraffinic naphtha include contacting a paraffinic naphtha feedstock with a catalyst system in a dehydrogenation reactor. The catalyst system includes a framework-substituted ultra-stable Y (USY)-type zeolite to produce a dehydrogenated product stream. The catalyst system includes a framework-substituted ultra-stable Y (USY)-type zeolite. The framework-substituted USY-type zeolite has a modified USY framework. The modified USY framework includes a USY aluminosilicate framework modified by substituting a portion of framework aluminum atoms of the USY aluminosilicate framework with substitution atoms independently selected from the group consisting of titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof. A dehydrogenation catalyst for dehydrogenating a paraffinic naphtha includes the framework-substituted ultra-stable Y (USY)-type zeolite.
PROCESSING OF PARAFFINIC NAPHTHA WITH MODIFIED USY ZEOLITE DEHYDROGENATION CATALYST
Methods for processing paraffinic naphtha include contacting a paraffinic naphtha feedstock with a catalyst system in a dehydrogenation reactor. The catalyst system includes a framework-substituted ultra-stable Y (USY)-type zeolite to produce a dehydrogenated product stream. The catalyst system includes a framework-substituted ultra-stable Y (USY)-type zeolite. The framework-substituted USY-type zeolite has a modified USY framework. The modified USY framework includes a USY aluminosilicate framework modified by substituting a portion of framework aluminum atoms of the USY aluminosilicate framework with substitution atoms independently selected from the group consisting of titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof. A dehydrogenation catalyst for dehydrogenating a paraffinic naphtha includes the framework-substituted ultra-stable Y (USY)-type zeolite.