Patent classifications
C10G45/16
Method for converting heavy hydrocarbon feedstocks with recycling of a deasphalted oil
The invention relates to a process for converting a heavy hydrocarbon feedstock containing a fraction of at least 50% with a boiling point of at least 300° C., and containing sulfur, Conradson carbon, metals, and nitrogen, comprising at least two successive hydroconversion steps, which may be separated by an intermediate separation step, and at least one step of deasphalting a heavy fraction of the effluent resulting from the hydroconversion, with recycling at least one portion of the deasphalted oil (DAO) during the hydroconversion, downstream of the first hydroconversion step. The DAO is either recycled at the outlet thereof from the deasphalter, or after having undergone a fractionation step that produces a heavy fraction of the DAO that then constitutes the portion of the DAO that is recycled. This process makes it possible to simultaneously improve the degree of conversion and the stability of the liquid effluents.
ZrCe-SBA-15-NiMo HYDRODESULFURIZATION CATALYST
A robust catalyst useful for hydrodesulfurization (HDS) of sulfur-containing hydrocarbons such as sulfur-containing diesel fuel. The catalyst contains a modified mesoporous silica, such as SBA-15, Zr atoms, Ni, Mo, Ce atoms. A method for removing sulfur from a hydrocarbon, such as diesel fuel or a refinery feedstock using the catalyst. A one-pot method for making the catalyst.
PROCESS FOR CONVERTING A FEEDSTOCK CONTAINING PYROLYSIS OIL
The invention relates to a process for converting a feedstock comprising pyrolysis oil and a heavy hydrocarbon-based feedstock, with: a) a step of hydroconversion in a reactor; b) a step of separating the liquid effluent obtained from step a) into a naphtha fraction, a gas oil fraction, a vacuum gas oil fraction and an unconverted residue fraction; c) a step of hydrocracking of the vacuum gas oil fraction; d) a step of fractionating the hydrocracked liquid effluent obtained from step c) into a naphtha fraction, a gas oil fraction and a vacuum gas oil fraction; e) a step of steam cracking of a portion of the naphtha fraction obtained from step d); f) a step of fractionating at least a portion of the steam-cracked effluent obtained from step e); g) a step in which the pyrolysis oil fraction obtained from step f) is sent into step a).
PROCESS FOR CONVERTING A FEEDSTOCK CONTAINING PYROLYSIS OIL
The invention relates to a process for converting a feedstock comprising pyrolysis oil and a heavy hydrocarbon-based feedstock, with: a) a step of hydroconversion in a reactor; b) a step of separating the liquid effluent obtained from step a) into a naphtha fraction, a gas oil fraction, a vacuum gas oil fraction and an unconverted residue fraction; c) a step of hydrocracking of the vacuum gas oil fraction; d) a step of fractionating the hydrocracked liquid effluent obtained from step c) into a naphtha fraction, a gas oil fraction and a vacuum gas oil fraction; e) a step of steam cracking of a portion of the naphtha fraction obtained from step d); f) a step of fractionating at least a portion of the steam-cracked effluent obtained from step e); g) a step in which the pyrolysis oil fraction obtained from step f) is sent into step a).
METHOD FOR CONVERTING HEAVY HYDROCARBON FEEDSTOCKS WITH RECYCLING OF A DEASPHALTED OIL
The invention relates to a process for converting a heavy hydrocarbon feedstock containing a fraction of at least 50% with a boiling point of at least 300 C., and containing sulfur, Conradson carbon, metals, and nitrogen, comprising at least two successive hydroconversion steps, which may be separated by an intermediate separation step, and at least one step of deasphalting a heavy fraction of the effluent resulting from the hydroconversion, with recycling at least one portion of the deasphalted oil (DAO) during the hydroconversion, downstream of the first hydroconversion step. The DAO is either recycled at the outlet thereof from the deasphalter, or after having undergone a fractionation step that produces a heavy fraction of the DAO that then constitutes the portion of the DAO that is recycled. This process makes it possible to simultaneously improve the degree of conversion and the stability of the liquid effluents.
METHOD FOR CONVERTING HEAVY HYDROCARBON FEEDSTOCKS WITH RECYCLING OF A DEASPHALTED OIL
The invention relates to a process for converting a heavy hydrocarbon feedstock containing a fraction of at least 50% with a boiling point of at least 300 C., and containing sulfur, Conradson carbon, metals, and nitrogen, comprising at least two successive hydroconversion steps, which may be separated by an intermediate separation step, and at least one step of deasphalting a heavy fraction of the effluent resulting from the hydroconversion, with recycling at least one portion of the deasphalted oil (DAO) during the hydroconversion, downstream of the first hydroconversion step. The DAO is either recycled at the outlet thereof from the deasphalter, or after having undergone a fractionation step that produces a heavy fraction of the DAO that then constitutes the portion of the DAO that is recycled. This process makes it possible to simultaneously improve the degree of conversion and the stability of the liquid effluents.
CATALYST STRUCTURE AND METHOD OF UPGRADING HYDROCARBONS IN THE PRESENCE OF THE CATALYST STRUCTURE
A catalyst structure includes a porous support structure, where the support structure includes an aluminosilicate material. Any two or more metals are loaded in the porous support structure, the two or more metals selected from the group consisting of Ga, Ag, Mo, Zn, Co and Ce, where each metal loaded in the porous support structure is present in an amount from about 0.1 wt % to about 20 wt %. In example embodiments, the catalyst structure includes three or more of the metals loaded in the porous support structure. The catalyst structure is used in a hydrocarbon upgrading process that is conducted in the presence of methane, nitrogen or hydrogen.
Flexible hydroprocessing of slurry hydrocracking products
Processes for hydrotreating an effluent from a slurry hydrocracking process are described. Different streams are formed from the SHC effluent, and different hydroprocessing conditions are applied to the streams, e.g., more severe conditions are applied to streams which need additional hydroprocessing, while less severe conditions are applied to streams which do not need as much hydroprocessing. Common equipment is shared between different hydroprocessing steps.
Flexible hydroprocessing of slurry hydrocracking products
Processes for hydrotreating an effluent from a slurry hydrocracking process are described. Different streams are formed from the SHC effluent, and different hydroprocessing conditions are applied to the streams, e.g., more severe conditions are applied to streams which need additional hydroprocessing, while less severe conditions are applied to streams which do not need as much hydroprocessing. Common equipment is shared between different hydroprocessing steps.
PROCESSING OF HEAVY HYDROCARBON FEEDS
Systems and methods are provided for hydroconversion of a heavy oil feed under slurry hydroprocessing conditions and/or solvent assisted hydroprocessing conditions. The systems and methods for slurry hydroconversion can include the use of a configuration that can allow for improved separation of catalyst particles from the slurry hydroprocessing effluent. In addition to allowing for improved catalyst recycle, an amount of fines in the slurry hydroconversion effluent can be reduced or minimized. This can facilitate further processing or handling of any pitch generated during the slurry hydroconversion. The systems and methods for solvent assisted hydroprocessing can include processing of a heavy oil feed in conjunction with a high solvency dispersive power crude.