A supported catalyst has a support and a metal active component disposed on the support. The metal active component is at least one selected from the group consisting of a Group VIB metal element and a Group VIII metal element. The support contains at least one of heat-resistant inorganic oxides and molecular sieves and includes an internal channel penetrating the support. The ratio of the cross-section area of the channel to the cross-section area of the support is 0.05-3:100. The difference R between the water absorption rate and the BET pore volume of the support is not less than 0.2 mL/g. The supported catalyst can be used as a hydrogenation catalyst. When used in the hydrocracking of hydrocarbon oils, it can achieve high catalytic activity and high yield of jet fuels at the same time. The supported catalyst can also be used as a Fischer-Tropsch synthesis catalyst.

In a broad aspect the present disclosure relates to a process plant and a process for upgrading a hydrocarbon mixture, withdrawn as a direct stream from a crude distillation unit and an initial boiling point below 200° C., and a fraction of at least 5% boiling above 500° C., 550° C. or 650° C. comprising the steps of a. directing said hydrocarbon mixture to a vacuum flasher unit, b. withdrawing a heavy hydrocarbon fraction from said vacuum flasher unit, c. withdrawing a light hydrocarbon mixture for hydrocracking from said vacuum flasher unit, d. directing said light hydrocarbon mixture for hydrocracking and a stream rich in hydrogen to con-tact a material catalytically active in hydrocracking, e. withdrawing a hydrocracked stream of hydrocarbon from said hydrocracker. with the associated benefit of limiting the amount of asphaltenes, metals and other heavy components contacting said material catalytically active in hydrocracking.

A catalyst which comprises an amorphous support based on alumina, a C1-C4 dialkyl succinate, citric acid and optionally acetic acid, phosphorus and a hydrodehydrogenating function comprising at least one element from group VIII and at least one element from group VIB; the most intense bands comprised in the Raman spectrum of the catalyst are characteristic of Keggin heteropolyanions (974 and/or 990 cm.sup.−1), C1-C4 dialkyl succinate and citric acid (in particular 785 and 956 cm.sup.−1). Also a process for preparing said catalyst in which a catalytic precursor in the dried, calcined or regenerated state containing the elements of the hydrodehydrogenating function, and optionally phosphorus, is impregnated with an impregnation solution comprising at least one C1-C4 dialkyl succinate, citric acid and optionally at least one compound of phosphorus and optionally acetic acid, and is then dried. Further, the use of said catalyst in any hydrotreatment process.

A catalyst which comprises an amorphous support based on alumina, a C1-C4 dialkyl succinate, citric acid and optionally acetic acid, phosphorus and a hydrodehydrogenating function comprising at least one element from group VIII and at least one element from group VIB; the most intense bands comprised in the Raman spectrum of the catalyst are characteristic of Keggin heteropolyanions (974 and/or 990 cm.sup.−1), C1-C4 dialkyl succinate and citric acid (in particular 785 and 956 cm.sup.−1). Also a process for preparing said catalyst in which a catalytic precursor in the dried, calcined or regenerated state containing the elements of the hydrodehydrogenating function, and optionally phosphorus, is impregnated with an impregnation solution comprising at least one C1-C4 dialkyl succinate, citric acid and optionally at least one compound of phosphorus and optionally acetic acid, and is then dried. Further, the use of said catalyst in any hydrotreatment process.

Disclosed are Group III base stocks comprising at least 30 wt % naphthenes, a viscosity index from 120 to 145; and a unique ratio of molecules with multi-ring naphthenes to single ring naphthenes (2R+N/1RN). A method for preparing the base stocks is also disclosed. Also disclosed is a lubricating oil having the base stock as a major component, and an additive as a minor component.

Disclosed are Group III base stocks comprising at least 30 wt % naphthenes, a viscosity index from 120 to 145; and a unique ratio of molecules with multi-ring naphthenes to single ring naphthenes (2R+N/1RN). A method for preparing the base stocks is also disclosed. Also disclosed is a lubricating oil having the base stock as a major component, and an additive as a minor component.

A method for producing a lubricant base oil includes a first hydrogenation treatment step of bringing a hydrogenation treatment catalyst and a light wax into contact with each other at temperature T.sub.1, and thereby obtaining a first treated oil; a second hydrogenation treatment step of bringing the hydrogenation treatment catalyst and a heavy wax into contact with each other at temperature T.sub.2, and thereby obtaining a second treated oil; and a base oil production step of obtaining a lubricant base oil from a feedstock oil containing at least one selected from the group consisting of the first treated oil and the second treated oil, in which the hydrogenation treatment catalyst is a catalyst obtained by supporting one or more metals selected from the elements of Group 6, Group 8, Group 9, and Group 10 of the Periodic Table of Elements, on an inorganic oxide support.

Methods and systems for producing light olefins are disclosed. A feedstock comprising crude oil is distilled to produce a plurality of streams including a naphtha stream and a vacuum residue stream. The naphtha is fed to a steam cracking unit to produce light olefins, C.sub.4 hydrocarbons, pyrolysis gasoline and pyrolysis oil. The vacuum residue stream is hydrocracked to produce additional naphtha and heavy unconverted oil. The heavy unconverted oil and the pyrolysis oil from steam cracking unit can be deasphalted to produce deasphalted oil and pitch product. The deasphalted oil can be further hydrocracked to produce naphtha. The pitch product can be gasified to produce synthesis gas, which is further used to produce methanol. The methanol can be used to react with isobutylene of the C.sub.4 hydrocarbon stream from steam cracker to produce methyl tert-butyl ether (MTBE).

A process for the production of sustainable aviation fuel (SAF) with low carbon intensity. The jet fuel is produced from the reaction of hydrogen from the electrolysis of water with captured carbon dioxide. The hydrogen and carbon dioxide are reacted to product a stream comprising carbon monoxide. Hydrogen and carbon monoxide are reacted to produce n-alkanes. Alkanes are hydroisomerized to produce sustainable aviation fuel with low carbon intensity.

A process for the production of sustainable aviation fuel (SAF) with low carbon intensity. The jet fuel is produced from the reaction of hydrogen from the electrolysis of water with captured carbon dioxide. The hydrogen and carbon dioxide are reacted to product a stream comprising carbon monoxide. Hydrogen and carbon monoxide are reacted to produce n-alkanes. Alkanes are hydroisomerized to produce sustainable aviation fuel with low carbon intensity.