Patent classifications
C10G2300/1007
Free fatty acid separation and recovery using resin
The disclosure provides various methods for separating and recovering free fatty acids crude oil containing free fatty acids using certain ion-exchange resins to reduce the amount of free fatty acids in the crude oil to 3% or less such that the resultant oil is useable in downstream chemical processes. After separation and removal of the free fatty acids form the crude oil, the ion-exchange resin is reusable in further free fatty acid separation reactions.
Solvent composition prepared from waste oil and method of preparing the same
Provided is a technology to convert an oil having a high content of Cl into a solvent. Impurities such as Cl, S, N, and metals are removed from an oil having a boiling point of 340° C. or lower in a waste oil having a high content of Cl, and hydrogenation is carried out to recover an oil, and the oil may be applied as a solvent. Separation by boiling points to meet the properties of the solvent product is performed, a solid acid material and an oil having a high Cl content are mixed, impurities are removed by a heat treatment at a high temperature, and hydrogenation is carried out with a metal oxide catalyst, thereby manufacturing a solvent product.
Process and plant for producing hydrocarbons with reduced CO.SUB.2.-footprint and improved hydrogen integration
Process and plant for producing hydrocarbon products from a feedstock originating from a renewable source, where a hydrogen-rich stream and on off-gas stream comprising hydrocarbons is formed. A portion of the hydrogen-rich stream is used as a recycle gas stream in a hydroprocessing stage for the production of said hydrocarbon products, and another portion may be used for hydrogen production, while the off-gas stream is treated to remove its H.sub.2S content and used as a recycle gas stream in the hydrogen producing unit, from which the hydrogen produced i.e. make-up hydrogen, is used in the hydroprocessing stage. The invention enables minimizing natural gas consumption in the hydrogen producing unit as well as steam reformer size.
Production of linear alpha olefins
The present invention provides a novel route for synthesis and production of linear alpha olefins (LAO) and central olefins from the feedstock comprising fatty acids, triglycerides and esters of fatty acids, and mixture thereof through controlled hydrogenolysis, hydrogenation and dehydration reactions simultaneously in a hydro processing reactor containing a catalyst system having dual site—a metallic site for hydrogenation/reduction reaction under hydrogen environment, and an acidic site for conversion of alcohol to olefin via E1 or E2 reaction mechanism.
PROCESS AND PLANT FOR PRODUCING HYDROCARBONS WITH REDUCED CO2-FOOTPRINT AND IMPROVED HYDROGEN INTEGRATION
Process and plant for producing hydrocarbon products from a feedstock originating from a renewable source, where a hydrogen-rich stream and on off-gas stream comprising hydrocarbons is formed. A portion of the hydrogen-rich stream is used as a recycle gas stream in a hydroprocessing stage for the production of said hydrocarbon products, and another portion may be used for hydrogen production, while the off-gas stream is treated to remove its H.sub.2S content and used as a recycle gas stream in the hydrogen producing unit, from which the hydrogen produced i.e. make-up hydrogen, is used in the hydroprocessing stage. The invention enables minimizing natural gas consumption in the hydrogen producing unit as well as steam reformer size.
Lubricant base stock production from recycled oil
Systems and methods are provided for co-processing of used lubricant oils with a coker feedstock in a fluidized coking process to form lubricant base stocks. The fluidized coking process can remove contaminants and/or additives from used lubricant oils with modest conversion of the lubricant boiling range portion.
Preparation of an aviation fuel composition
A method is disclosed for preparing an aviation fuel composition by subjecting a feedstock of biological and/or recycled origin to cracking in a cracking unit and to fractionation in a fractionation unit to obtain a kerosene fraction. The obtained kerosene fraction is subjected to hydrotreatment in a hydrotreatment unit to form a first jet fuel component. The formed first jet fuel component is mixed with a further jet fuel component to form a fuel composition having a wear scar diameter of 0.78 mm or less, as measured with BOCLE lubricity test method according to ASTM D5001. The feedstock contains one or more of tall oil pitch (TOP), a mixture of sludge palm oil, palm fatty acid distillate and animal fat (FATS), and used lubricant oil (ULO).
RECYCLE CONTENT ETHYLENE AND PROPYLENE
The present application discloses a recycle content (C.sub.2-3)alkene product (r-(C.sub.2-3)alkene) having a certain compositional profile a obtained from cracking recycle content pyrolysis oil composition and processes for obtaining the recycle content (C.sub.2-3)alkene product having a certain compositional profile.
METHOD AND SYSTEM FOR RE-REFINING AND UPGRADING USED OIL
A method for re-refining used oils comprises contacting feedstock comprising purified used oil with extraction solvent to perform continuous liquid-liquid solvent extraction, to produce an extract stream comprising the extraction solvent and an extract dissolved in the extraction solvent. The feedstock and the extraction solvent are agitated by a variable speed agitator during the solvent extraction at a selected agitation speed. The extract is separated from the extraction solvent and subjected to a continuous flow liquid phase hydrogenation treatment to produce an oil product. A system for performing the method includes a purification unit for purifying the used oil; an extraction column for extracting the extract from the feedstock; and a continuous flow liquid phase hydrogenation unit. The extraction column comprises an agitator configured to agitate the feedstock and the extraction solvent flowing through the extraction column at a variable agitation speed.
Production of Linear Alpha Olefins
The present invention provides a novel route for synthesis and production of linear alpha olefins (LAO) and central olefins from the feedstock comprising fatty acids, triglycerides and esters of fatty acids, and mixture thereof through controlled hydrogenolysis, hydrogenation and dehydration reactions simultaneously in a hydro processing reactor containing a catalyst system having dual site—a metallic site for hydrogenation/reduction reaction under hydrogen environment, and an acidic site for conversion of alcohol to olefin via E1 or E2 reaction mechanism.