C10G2300/1062

BLOCKED OPERATION FOR GROUP II AND GROUP III LUBRICANT PRODUCTION
20190040326 · 2019-02-07 ·

Systems and methods are provided for block processing of a feedstock to produce multiple viscosity grades of lubricant base stocks with substantially different viscosity index values. The systems and methods can involve the use of a sweet stage hydrocracking catalyst that can maintain good aromatic saturation activity under conditions that produce substantially different levels of viscosity index uplift. Optionally, the reactor including the sweet stage hydrocracking catalyst can include additional aromatic saturation catalyst. The systems and methods can further involve using a combination of aromatic saturation catalyst and dewaxing catalyst in a second sweet stage reactor, so that additional aromatic saturation activity is available for saturation of aromatics for products that undergo lower amounts of conversion in the sweet hydrocracking stage. The systems and methods can also allow for increased control over the relative temperatures of reactors within a reaction system.

METHOD FOR PROCESSING HEAVY HYDROCARBON FEEDSTOCK

The method for processing heavy hydrocarbon feedstock, predominantly heavy crude oil, comprises pre-treatment of an initial feedstock and an auxiliary gaseous mixture at a pre-set pressure, introducing the pre-treated auxiliary gaseous mixture into the pre-treated feedstock and mixing thereof, cavitation treatment of the resulting mixture, separating liquid and gaseous products followed by isolating the final petroleum product. The novelty is in that gaseous hydrocarbons having the activation energy comparable with the molecule dissociation energy of the main components of the heavy hydrocarbon feedstock, are used as auxiliary gaseous mixture; and the pre-treatment of the initial heavy hydrocarbon feedstock and the auxiliary gaseous mixture, both of which are in the liquid state, is performed at a pressure which exceeds the saturated vapour pressure of the auxiliary gaseous mixture. The technical result is the improved physical and chemical characteristics of the final petroleum product by virtue of changing the composition and structure thereof, more particularly, by reducing its density, viscosity, and initial boiling point, by increasing the light fraction yield during refining, and by increasing the efficiency and the effectiveness factor of processing heavy hydrocarbon feedstock.

TRIM DEWAXING OF DISTILLATE FUEL

Methods and catalysts are provided for performing dewaxing of diesel boiling range fractions, such as trim dewaxing, that allow for production of diesel boiling range fuels with improved cold flow properties at desirable yields. In some aspects, the methods can include use of dewaxing catalysts based on an MEL framework structure (ZSM-11) to provide improved dewaxing activity. This can provide sufficient dewaxing activity to achieve a desired level of improvement in cold flow properties at the lower hydrotreating temperatures that are generally desired near the start of operation of a hydrotreating reactor. In other aspects, the methods can include use of MEL dewaxing catalysts with reduced ratios of molecular sieve to binder so that trim dewaxing can be provided while maintaining a desirable yield under end-of-run hydrotreating conditions.

A COMPOSITION AND A PROCESS FOR REDUCING AROMATICS FROM A HYDROCARBON FEEDSTOCK

The present disclosure relates to a composition for reducing aromatics from a hydrocarbon feedstock. The composition comprises a solvent mixture. The solvent mixture includes a primary solvent, a first co-solvent, a second co-solvent, and a secondary solvent. The present disclosure also relates to a process for reducing aromatics from a hydrocarbon feedstock.

Liquid-Phase Hydroisomerization System And Process Therefor And Use Thereof

Provided are a liquid-phase hydroisomerization system and a process therefor and use thereof. The system comprises a gas-liquid mixer (3), a hydroisomerization reactor (4) and a fractionating column (6). An oil product and hydrogen are mixed as a liquid hydrogen-oil mixture, and are introduced into the hydroisomerization reactor for a hydroisomerization reaction, and after being fractionated, a target product is led out. A supplemental hydrogen-dissolving inner member is provided at least between a group of two adjacent catalyst bed layers in order to supplement hydrogen to the reactants. The process cancels a circulating hydrogen compressor, has a simple process flow, and can be applied to the production of a lubricant base oil by the hydroisomerization of a lubricant raw material or the production of a low freezing point diesel by the hydroisomerization of and the reduction in the freezing point of a diesel raw material.

Production of base oils from petrolatum

Methods are provided for producing lubricant base oils from petrolatum. After solvent dewaxing of a brightstock raffinate to form a brightstock base oil, petrolatum is generated as a side product. The petrolatum can be hydroprocessed to form base oils in high yield. The base oils formed from hydroprocessing of petrolatum have an unexpected pour point relationship. For a typical lubricant oil feedstock, the pour point of the base oils generated from the feedstock increases with the viscosity of the base oil. By contrast, lubricant base oils formed from hydroprocessing of petrolatum have a relatively flat pour point relationship, and some of the higher viscosity base oils unexpectedly have lower pour points than lower viscosity base oils generated from the same petrolatum feed. The base oils from petrolatum are also unusual in yielding both high viscosity and high viscosity index and can be generated while maintaining a high yield.

BLOCK PROCESSING CONFIGURATIONS FOR BASE STOCK PRODUCTION FROM DEASPHALTED OIL

Systems and methods are provided for block operation during lubricant and/or fuels production from deasphalted oil. During block operation, a deasphalted oil and/or the hydroprocessed effluent from an initial processing stage can be split into a plurality of fractions. The fractions can correspond, for example, to feed fractions suitable for forming a light neutral fraction, a heavy neutral fraction, and a bright stock fraction, or the plurality of fractions can correspond to any other convenient split into separate fractions. The plurality of separate fractions can then be processed separately in the process train (or in the sweet portion of the process train) for forming fuels and/or lubricant base stocks. The separate processing can allow for selection of conditions for forming lubricant fractions, such as bright stock fractions, that have a cloud point that is lower than the pour point.

BLOCK PROCESSING FOR BASE STOCK PRODUCTION FROM DEASPHALTED OIL

Systems and methods are provided for block operation during lubricant and/or fuels production from deasphalted oil. During block operation, a deasphalted oil and/or the hydroprocessed effluent from an initial processing stage can be split into a plurality of fractions. The fractions can correspond, for example, to feed fractions suitable for forming a light neutral fraction, a heavy neutral fraction, and a bright stock fraction, or the plurality of fractions can correspond to any other convenient split into separate fractions. The plurality of separate fractions can then be processed separately in the process train (or in the sweet portion of the process train) for forming fuels and/or lubricant base stocks.

BLOCK PROCESSING WITH BULK CATALYSTS FOR BASE STOCK PRODUCTION FROM DEASPHALTED OIL

Systems and methods are provided for block operation during lubricant and/or fuels production from deasphalted oil. During block operation, a deasphalted oil and/or the hydroprocessed effluent from an initial processing stage can be split into a plurality of fractions. The fractions can correspond, for example, to feed fractions suitable for forming a light neutral fraction, a heavy neutral fraction, and a bright stock fraction, or the plurality of fractions can correspond to any other convenient split into separate fractions. The plurality of separate fractions can then be processed separately in the process train (or in the sweet portion of the process train) for forming fuels and/or lubricant base stocks. The initial stage can optionally include a bulk hydrotreating catalyst to assist with increasing the space velocity in the initial stage.

BASE STOCKS AND LUBRICANT COMPOSITIONS CONTAINING SAME

Systems and methods are provided for block operation during lubricant and/or fuels production from deasphalted oil. During block operation, a deasphalted oil and/or the hydroprocessed effluent from an initial processing stage can be split into a plurality of fractions. The fractions can correspond, for example, to feed fractions suitable for forming a light neutral fraction, a heavy neutral fraction, and a bright stock fraction, or the plurality of fractions can correspond to any other convenient split into separate fractions. The plurality of separate fractions can then be processed separately in the process train (or in the sweet portion of the process train) for forming fuels and/or lubricant base stocks. This can allow for formation of unexpected base stock compositions.