Patent classifications
C10G2300/304
Polymeric pour point depressants for waxy crude oils
This invention relates a wax inhibitor for hydrocarbon oils comprising an esterified copolymer having repeating structural units derived from an esterified ethylenically unsaturated dicarboxylic acid and α-olefins having at least 18 carbon atoms, whereof at least 3 mol-% of the α-olefins have 30 or more carbon atoms, and wherein the ethylenically unsaturated dicarboxylic acid has been esterified with a mixture of alcohols comprising i) 70 to 97 mol-% of a saturated fatty alcohol having 18 to 24 carbon atoms and ii) 3 to 30 mol-% of an unsaturated alcohol having 16 to 24 carbon atoms.
PRODUCTION OF PARAFFINIC PRODUCTS
A method for combined production of renewable paraffinic products is disclosed, wherein the method includes providing a renewable paraffinic feed, and fractionating the renewable paraffinic feed into two fractions. Within the two fractions, a lighter fraction fulfils a specification for an aviation fuel component, and a heavier fraction fulfils a specification for an electrotechnical fluid component.
Circular economy for plastic waste to polyethylene via refinery FCC and alkylation units
Provided in one embodiment is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil and optionally wax comprising a naphtha/diesel and heavy fraction, and char. The pyrolysis oil and wax is passed to a refinery FCC unit from which a liquid petroleum gas C.sub.3-C.sub.5 olefin/paraffin mixture fraction is recovered. The liquid petroleum gas C.sub.3-C.sub.5 olefin/paraffin mixture fraction is passed to a refinery alkylation unit, with a propane and butane fraction recovered from the alkylation unit. The propane and butane fraction is then passed to a steam cracker for ethylene production. In another embodiment, a naphtha fraction (C.sub.5-C.sub.8) is recovered from the alkylation unit and passed to the steam cracker. In another embodiment, a propane/propylene fraction (C.sub.3-C.sub.3.sup.=) is recovered from the FCC and passed to the steam cracker.
Circular economy for plastic waste to polypropylene and lubricating oil via refinery FCC and isomerization dewaxing units
A continuous process for converting waste plastic into recycle for polypropylene polymerization is provided. The process integrates refinery operations to provide an effective and efficient recycle process. The process comprises selecting waste plastics containing polyethylene and polypropylene and then passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a refinery FCC unit, from which is recovered a liquid petroleum gas C.sub.3 olefin/paraffin mixture. The C.sub.3 paraffins and C.sub.3 olefins are separated into different fractions with a propane/propylene splitter. The C.sub.3 olefin fraction is passed to a propylene polymerization reactor. The C.sub.3 paraffin fraction is optionally passed to a dehydrogenation unit to produce additional propylene and then the resulting C.sub.3 olefin is passed to a propylene polymerization reactor. The heavy fraction of pyrolyzed oil is passed to an isomerization dewaxing unit to produce a lubricating base oil.
LOW SULFUR FUEL OIL BUNKER COMPOSITION AND PROCESS FOR PRODUCING THE SAME
The present disclosure relates to marine fuel compositions having low sulfur content and processes for making such compositions.
RENEWABLE HYDROCARBON COMPOSITION HAVING GOOD CETANE NUMBER AND GOOD COLD PROPERTIES
A renewable hydrocarbon composition as disclosed includes monobranched isoparaffins, dibranched isoparaffins, tribranched isoparaffins multibranched isoparaffins, and n-paraffins, having carbon numbers from C8 to C30. Said renewable hydrocarbon composition has high cetane number and excellent cold properties. The renewable hydrocarbon composition can be used as diesel fuel or as a diesel fuel component.
Process for deparaffinning a middle distillate feedstock using a catalyst based on IZM-2 zeolite and an MFI-type zeolite
The present invention relates to a process for deparaffinning a middle distillate feedstock, to convert, in good yield, feedstocks having high pour points into at least one cut having an improved pour point. Said process is performed with at least one catalyst comprising at least one hydro-dehydrogenating phase containing at least one metal from group VIB and at least one metal from group VIII of the Periodic Table of the Elements, and a support comprising at least one IZM-2 zeolite, a zeolite of WI framework type code and at least one binder.
Circular economy for plastic waste to polypropylene via refinery FCC unit
Provided is a continuous process for converting waste plastic into recycle for polypropylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. Pyrolysis oil and wax, comprising naphtha/diesel and heavy fractions, is passed to a refinery FCC unit. A liquid petroleum gas C.sub.3 olefin/paraffin mixture is recovered from the FCC unit. The C.sub.3 paraffins and C.sub.3 olefins are separated into different fractions with the C.sub.3 olefin fraction passed to a propylene polymerization reactor, and the C.sub.3 paraffin fraction passed optionally to a dehydrogenation unit to produce additional propylene.
Polymeric Pour Point Depressants For Waxy Crude Oils
This invention relates a wax inhibitor for hydrocarbon oils comprising an esterified copolymer having repeating structural units derived from an esterified ethylenically unsaturated dicarboxylic acid and α-olefins having at least 18 carbon atoms, whereof at least 3 mol-% of the α-olefins have 30 or more carbon atoms, and wherein the ethylenically unsaturated dicarboxylic acid has been esterified with a mixture of alcohols comprising i) 70 to 97 mol-% of a saturated fatty alcohol having 18 to 24 carbon atoms and ii) 3 to 30 mol-% of an unsaturated alcohol having 16 to 24 carbon atoms.
Ultra low sulfur marine fuel compositions
Hydroprocessed residual fuel and/or fuel blending components are provided that have a sulfur and nitrogen level comparable to liquefied natural gas (LNG). Because of the low starting level of sulfur and/or nitrogen, the severity of the hydroprocessing that is needed for the crude oil or bottoms fraction in order to remove sulfur to a level that is comparable to LNG is reduced or minimized. This can allow the resulting marine residual fuels to have low carbon intensity, low SOx and NOx emission and high energy density. Since the hydroprocessed fractions correspond to a fuel oil product, the resulting marine fuel can be used in existing fleets, and can be distributed in existing bunkering systems.