Patent classifications
C10J3/84
Method of producing liquid fuel from carbonaceous feedstock through gasification and recycling of downstream products
A feedstock delivery system transfers a carbonaceous material, such as municipal solid waste, into a product gas generation system. The feedstock delivery system includes a splitter for splitting bulk carbonaceous material into a plurality of carbonaceous material streams. Each stream is processed using a weighing system for gauging the quantity of carbonaceous material, a densification system for forming plugs of carbonaceous material, a de-densification system for breaking up the plugs of carbonaceous material, and a gas and carbonaceous material mixing system for forming a carbonaceous material and gas mixture. A pressure of the mixing gas is reduced prior to mixing with the carbonaceous material, and the carbonaceous material to gas weight ratio is monitored. A transport assembly conveys the carbonaceous material and gas mixture to a first reactor where at least the carbonaceous material within the mixture is subject to thermochemical reactions to form the product gas.
System and method for biogasification
Embodiments of the invention improve the performance, safety, and efficiency of the gasification process. Embodiments of the invention improve downdraft gasification by improving upon the systems and methods for fuel preparation and by addressing gasifier bridging and channeling. Unique parts of the system include a unique hearth and grate design, a programmable logic controller and interface for managing the gasification process, an improved filtration system, a unique system for eliminating mist, a unique system for cooling gas, a unique combined flare, an integrated auger system, and a new system and method for sampling gas.
System and method for biogasification
Embodiments of the invention improve the performance, safety, and efficiency of the gasification process. Embodiments of the invention improve downdraft gasification by improving upon the systems and methods for fuel preparation and by addressing gasifier bridging and channeling. Unique parts of the system include a unique hearth and grate design, a programmable logic controller and interface for managing the gasification process, an improved filtration system, a unique system for eliminating mist, a unique system for cooling gas, a unique combined flare, an integrated auger system, and a new system and method for sampling gas.
PROCESSES FOR PRODUCING SYNGAS STARTING FROM PRETREATED RECOVERY PLASTIC POLYMERS
A process for producing syngas from pre-treated recovery plastic polymers comprising:
a) gasifying said recovery pre-treated polymers according to the following reaction scheme R1:
[—CH.sub.2—]+H.sub.2O═CO+2H.sub.2; R1:
b) hydrogenating said pre-treated polymers to higher hydrocarbons and methane by using hydrogen produced in R1, according to the following reaction scheme R3:
[—CH.sub.2—].sub.n+H.sub.2═C.sub.nH.sub.(2n+2) R3:
wherein n is an integer of from 1 to 3, said reaction being optionally combined with oligomers and olefin formation reactions;
c) steam reforming of methane according to the following reaction scheme R4:
CH.sub.4+H.sub.2O═CO+3H.sub.2; R4:
and optionally
d) reforming reaction of methane according to the following reaction scheme R5:
CH.sub.4+CO.sub.2=2CO+2H.sub.2; R5:
said process being carried out in a plant (10), (20), (30), (40), (50) comprising a gasification section (11), (21), (31), (41), (51) and a reforming section (12), (22), (32), (42), (52) comprising a tube bundle (13), (23), (33), (43), (53) provided with a catalyst wherein,
i) said gasification (11), (21), (31) and reforming sections (12),(22), (32) are part of a sole reactive unit (10), (20), (30), or said gasification (41), (51) and reforming section (42), (52) are two physically distinct reactive units (40), (50),
ii) the gasification section (11), (21) or the reactive unit (41) provides respectively the energetical support to the reforming section (12), (22) or to the reforming reactive unit (42), thanks to the exothermic combustion reaction scheme R2:
[—CH.sub.2-]+1.5O.sub.2═CO.sub.2+H.sub.2O; R2:
or in alternative: the reforming section (
PROCESSES FOR PRODUCING SYNGAS STARTING FROM PRETREATED RECOVERY PLASTIC POLYMERS
A process for producing syngas from pre-treated recovery plastic polymers comprising:
a) gasifying said recovery pre-treated polymers according to the following reaction scheme R1:
[—CH.sub.2—]+H.sub.2O═CO+2H.sub.2; R1:
b) hydrogenating said pre-treated polymers to higher hydrocarbons and methane by using hydrogen produced in R1, according to the following reaction scheme R3:
[—CH.sub.2—].sub.n+H.sub.2═C.sub.nH.sub.(2n+2) R3:
wherein n is an integer of from 1 to 3, said reaction being optionally combined with oligomers and olefin formation reactions;
c) steam reforming of methane according to the following reaction scheme R4:
CH.sub.4+H.sub.2O═CO+3H.sub.2; R4:
and optionally
d) reforming reaction of methane according to the following reaction scheme R5:
CH.sub.4+CO.sub.2=2CO+2H.sub.2; R5:
said process being carried out in a plant (10), (20), (30), (40), (50) comprising a gasification section (11), (21), (31), (41), (51) and a reforming section (12), (22), (32), (42), (52) comprising a tube bundle (13), (23), (33), (43), (53) provided with a catalyst wherein,
i) said gasification (11), (21), (31) and reforming sections (12),(22), (32) are part of a sole reactive unit (10), (20), (30), or said gasification (41), (51) and reforming section (42), (52) are two physically distinct reactive units (40), (50),
ii) the gasification section (11), (21) or the reactive unit (41) provides respectively the energetical support to the reforming section (12), (22) or to the reforming reactive unit (42), thanks to the exothermic combustion reaction scheme R2:
[—CH.sub.2-]+1.5O.sub.2═CO.sub.2+H.sub.2O; R2:
or in alternative: the reforming section (
Universal feeder with clamshell transfer screw
Exemplary apparatus or method implementations for a universal feeder system configured with a transfer screw feeder within a multi-section clamshell pipe permitting access to the feed screw and pipe interior for inspection, maintenance and/or cleaning during production, without disassembly or screw removal. The clamshell screw feeder pipe provides access to the screw by opening or removing the multi-section top portion of the clamshell pipe. The top pipe section is bolted and or hinges to the bottom portion of the clamshell pipe. The number of segmented multiple clamshell top sections depends on the length of the screw. One or more clamshell top sections may be configured with an inspection port. The universal feeder system configured with a transfer screw feeder within a multi-section clamshell pipe transfers feedstock feed from one or more feed vessels to one or more reactor vessel.
Universal feeder with clamshell transfer screw
Exemplary apparatus or method implementations for a universal feeder system configured with a transfer screw feeder within a multi-section clamshell pipe permitting access to the feed screw and pipe interior for inspection, maintenance and/or cleaning during production, without disassembly or screw removal. The clamshell screw feeder pipe provides access to the screw by opening or removing the multi-section top portion of the clamshell pipe. The top pipe section is bolted and or hinges to the bottom portion of the clamshell pipe. The number of segmented multiple clamshell top sections depends on the length of the screw. One or more clamshell top sections may be configured with an inspection port. The universal feeder system configured with a transfer screw feeder within a multi-section clamshell pipe transfers feedstock feed from one or more feed vessels to one or more reactor vessel.
SYSTEM AND METHOD FOR LIQUID FUEL PRODUCTION FROM CARBONACEOUS MATERIALS USING RECYCLED CONDITIONED SYNGAS
A method of producing liquid fuel and/or chemicals from a carbonaceous material entails combusting a conditioned syngas in pulse combustion heat exchangers of a steam reformer to help convert carbonaceous material into first reactor product gas which includes carbon monoxide, hydrogen, carbon dioxide and other gases. A portion of the first reactor product gas is transferred to a hydrogen reformer into which additional conditioned syngas is added and a reaction carried out to produce an improved syngas. The improved syngas is then subject to one or more gas clean-up steps to form a new conditioned syngas. A portion of the new conditioned syngas is recycled to be used as the conditioned syngas in the pulse combustion heat exchangers and in the hydrocarbon reformer. A system for carrying out the method include, a steam reformer, a hydrocarbon reformer, first and second gas-cleanup systems, a synthesis system and an upgrading system.
SYSTEM AND METHOD FOR LIQUID FUEL PRODUCTION FROM CARBONACEOUS MATERIALS USING RECYCLED CONDITIONED SYNGAS
A method of producing liquid fuel and/or chemicals from a carbonaceous material entails combusting a conditioned syngas in pulse combustion heat exchangers of a steam reformer to help convert carbonaceous material into first reactor product gas which includes carbon monoxide, hydrogen, carbon dioxide and other gases. A portion of the first reactor product gas is transferred to a hydrogen reformer into which additional conditioned syngas is added and a reaction carried out to produce an improved syngas. The improved syngas is then subject to one or more gas clean-up steps to form a new conditioned syngas. A portion of the new conditioned syngas is recycled to be used as the conditioned syngas in the pulse combustion heat exchangers and in the hydrocarbon reformer. A system for carrying out the method include, a steam reformer, a hydrocarbon reformer, first and second gas-cleanup systems, a synthesis system and an upgrading system.
PYROLYSIS GAS PURIFICATION/COOLING DEVICE, PYROLYSIS GAS PURIFICATION/COOLING METHOD, ORGANIC SUBSTANCE PRODUCTION DEVICE, AND METHOD FOR PRODUCING ORGANIC SUBSTANCE
Provided are a method for producing an organic substance and a device for producing an organic substance that are capable of efficiently cooling a synthesis gas and of converting the synthesis gas to an organic substance at a high conversion efficiency using a microbial catalyst. A thermally decomposed gas purification/cooling device including a gasification furnace 10 that gasifies waste to generate a thermally decomposed gas, a cyclone 11 through which the thermally decomposed gas discharged from the gasification furnace 10 is passed to recover a dust component in the thermally decomposed gas, and a heat exchanger 20 through which the thermally decomposed gas that has passed through the cyclone 11 is passed to be cooled.