An apparatus and methods to eliminate PFAS from wastewater biosolids through fluidized bed gasification. The gasifier decomposes the PFAS in the biosolids at temperatures of 900-1800° F. Synthesis gas (syngas) exits the gasifier which is coupled to a thermal oxidizer and is combusted at temperatures of 1600-2600° F. This decomposes PFAS in the syngas and creates flue gas. Heat can be recovered from the flue gas by cooling the flue gas to temperatures of 400-1200° F. in a heat exchanger that is coupled with the thermal oxidizer. Cooled flue gas is mixed with hydrated lime, enhancing PFAS decomposition, with the spent lime filtered from the cooled flue gas using a filter system that may incorporate catalyst impregnated filter elements. The apparatus and methods thereby eliminate PFAS from wastewater biosolids and control emissions in the resulting flue gas.

A waste management system, primarily intended to be for waste floating in water, though it can also be used on land. A shredding device will reduce the size of the particles of waste. Ocean water is removed by a drying device. The dried waste material is cryogenically frozen using liquid nitrogen or other suitable means. The frozen waste material is then pulverized and ground into a powder. The powder may then be sprayed into a gas-filled chamber and heated. Temperature, pressure and humidity are maintained within the chamber for more than one minute. Microwave or other radiation and catalysts may be used to enhance the process of extraction. The processed material is then removed from the chamber. Carbon and water may be recycled. The carbon may be used as fuel by the ship. Water may also be used by the ship or returned to the ocean in a non-toxic condition.

Apparatus and methods to eliminate PFAS from wastewater biosolids through fluidized bed gasification. The gasifier decomposes the PFAS in the biosolids at temperatures of 900-1800° F. Syngas exits the gasifier which is coupled to a thermal oxidizer and combusts at temperatures of 1600-2600° F. This decomposes PFAS in the syngas and creates flue gas. Heat is recovered from the flue gas by cooling the flue gas to temperatures of 400-1200° F. in a heat exchanger coupled with the thermal oxidizer. Various methods inject moisture into the gas stream, controlling temperature through evaporative cooling and/or injecting chemicals that react with gas stream components. Cooled flue gas mixes with hydrated lime capturing decomposed PFAS molecules with spent lime filtered from the cooled flue gas using a filter system that may incorporate catalyst impregnated filter elements, eliminating PFAS from wastewater biosolids and controlling emissions in the resulting flue gas.

Apparatus and associated methods relate to drying a wet coated seed material stream comprising an incoming wet granular biosolids stream mixed with a controlled size dried seed material recycling stream to produce a moist air and pellet stream, separating an uncontrolled size dried pellet stream from the moist air and pellet stream, diverting a recycle portion of the uncontrolled size dried pellet stream to be recycled, diverting the remainder of the uncontrolled size dried pellet stream to an outlet, resizing oversized pellets from the recycle portion of the uncontrolled size dried pellet stream to produce the controlled size dried seed material recycling stream, and mixing the controlled size dried seed material recycling stream with the incoming wet granular biosolids stream to produce the wet coated seed material stream. Oversized pellets may be selected using a screen. The oversized pellets may be resized using a crusher inline with the recycle stream.

The method and plant (1) for conversing solid recovered fuel pellets (117) made from municipal solid waste (103) allow the transformation of the municipal solid waste (103) into hydrogen with a high yield instead of landfilling or incinerating the municipal solid waste (103). The hydrogen rich product gas stream (601) can be used as feedstock for chemical reactions or for storing energy in a releasable manner.

The invention is directed to a process to prepare an activated carbon product and a gaseous fraction comprising hydrogen, carbon monoxide and a mixture of gaseous organic compounds from a solid torrefied biomass feed comprising the following steps. (i) subjecting the solid biomass feed to a pyrolysis reaction thereby obtaining a gaseous fraction comprising hydrogen, carbon monoxide and a mixture of gaseous organic compounds and a solid fraction comprising of char particles. (ii) separating the solids fraction from the gaseous fraction. and (iii) activating the char particles as obtained in step (ii) to obtain the activated carbon product.

The invention is directed to a process to prepare a char product and a syngas mixture comprising hydrogen and carbon monoxide from a solid torrefied biomass feed comprising the following steps: (i) subjecting the solid biomass feed to a pyrolysis reaction thereby obtaining a gaseous fraction comprising hydrogen, carbon monoxide and a mixture of gaseous organic compounds and a solid fraction comprising of char particles; (ii) separating the char particles as the char product from the gaseous fraction; (iii) subjecting the gaseous fraction obtained in step (ii) to a continuously operated partial oxidation to obtain a syngas mixture further comprising water and having an elevated temperature and (iv) contacting the syngas mixture with a carbonaceous compound to chemically quench the syngas mixture. The temperature of the syngas is reduced in step (iv) from between 1000 and 1600° C. to a temperature of between 800 and 1200° C.

A process for the manufacture of one or more useful products comprises: gasifying a carbonaceous feedstock comprising waste materials and/or biomass in a gasification zone to generate a raw synthesis gas; supplying at least a portion of the raw synthesis gas to a clean-up zone to remove contaminants and provide a clean synthesis gas; supplying the clean synthesis gas to a first further reaction train to generate at least one first useful product and a tailgas; and diverting selectively on demand a portion of at least one of the carbonaceous feedstock, the clean synthesis gas, the tailgas and the light gas fraction to heat or power generation within the process, in response to external factors to control the carbon intensity of the overall process and enable GHG emission savings.

A gas generation plant for generating hydrogen-containing synthesis gas includes a gas generation reactor which is oriented in the vertical direction being greater in length vertically than width. A gas inlet is designed for the passage of superheated water vapor into the gas generation reactor. Through an upper outlet, a gas/water vapor mixture can exit the gas generation reactor and be reused in the second heating element after having been superheated. Synthesis gas can exit through a lower gas outlet. In the vertical direction, the gas inlet is arranged at a smaller distance from the lower end than the lower gas outlet. The upper gas outlet is arranged at a smaller vertical distance from the upper end than the lower gas outlet. The vertical distance between the upper gas outlet and the lower gas outlet is greater than the vertical distance between the lower gas outlet and the gas inlet.

Systems and processes provide for a thermal process to transform sludge (and a variety of other natural waste materials) into electricity. Dewatered sludge and other materials containing a high amount of latent energy are dried into a powdered biofuel using a drying gas produced in the system. The drying gas is recirculated and is heated by the biofuel produced in the system, waste heat (from turbines or internal combustion engines), gas (including natural gas or digester gas) and/or oil. The biofuel is combusted in a boiler system that utilizes a burner operable to burn biofuel and produce heat utilized in a series of heat exchangers that heat the recirculating drying air and steam that powers the turbines for electricity production.