The disclosure relates generally to methods and systems for manufacturing ammonia, ammonium sulfate, nitric acid, ammonium nitrate, or combinations thereof, and particularly to clean and efficient methods and system configurations for manufacturing ammonia, ammonium sulfate, nitric acid, ammonium nitrate, or combinations thereof using coal, petcoke, asphaltenes and/or hydrocarbon waste products.

The present invention provides a method and system for preparing fuel gas by utilizing an organic waste with high water content. The method comprises the following steps: 1) providing an organic waste with high water content; 2) performing hydrothermal reaction by using the organic waste with high water content as a reactant to obtain a hydrothermal reaction product; 3) enabling the hydrothermal reaction product to generate steam, and separating a solid product and an oily liquid product in the hydrothermal reaction product; 4) performing gasification reaction by using the solid product, the oily liquid product and the steam as reactants to obtain a gasification reaction product; and 5) purifying the gasification reaction product to obtain clean fuel gas. The present invention further provides a system for preparing fuel gas. The method can be used for preparing clean fuel gas from the organic waste with water content of 60% or more.

A two-stage gasification reactor may include a reactor lower section and a reactor upper section. The reactor lower section may include (a) a lower reactor body, (b) two primary feed nozzles, configured to introduce at least one of a dry feedstock or a first slurried feedstock and located on opposing terminal ends of the lower reactor body, and (c) at least two secondary feed nozzles, configured to introduce a liquid hydrocarbon feedstock, located on the lower reactor body. The reactor upper section may include (a) an upper reactor body, (b) at least one upper feed nozzle, configured to introduce at least one of a dry feedstock or a first slurried feedstock, located on the upper reactor body, and (c) an outlet.

A gasification system for the partial oxidation of a carbonaceous feedstock to at least provide a synthesis gas, the system comprising a reactor chamber and a quench section below the reactor chamber. An intermediate section connecting the reactor chamber to the quench section comprises at least one layer of refractory bricks arranged on and supported by the reactor chamber floor, the refractory bricks enclosing a reactor outlet opening. A membrane wall extends downwardly from the reactor outlet opening of the reactor chamber floor. A pump system is provided communicating with a source of a liquid coolant for circulating the liquid coolant through the tubes of the membrane wall.

A gasification system for the oxidation of a carbonaceous feedstock to provide a synthesis gas comprising: a reactor chamber for oxidizing the carbonaceous feedstock; a quench section for holding a bath of liquid coolant; an intermediate section having a reactor outlet opening through which the synthesis gas is conducted from the reactor chamber into the bath of the quench section; at least one layer of refractory bricks arranged on the reactor chamber floor, the lower end section of the refractory brick enclosing the reactor outlet opening and defining the inner diameter thereof; the intermediate section including a number of halved tubes for liquid coolant arranged onto at least part of the reactor chamber floor on a side thereof opposite to the lower end section of the refractory bricks; and a pump system for circulating the liquid coolant through the halved tubes on the reactor chamber floor.

A system and method for the pyrolysis of a pyrolysis feedstock utilizes a pyrolysis reactor having a pyrolysis conduit and a solids return conduit segment. Each segment is configured with an outlet and an inlet to receive and discharge solid materials that are circulated through the reactor through the different segments. A solids conveyor is disposed within the pyrolysis conduit segment to facilitate conveying solid materials from the solids inlet upward through the pyrolysis conduit segment toward the solids discharge outlet. A pyrolysis feedstock is introduced into the pyrolysis reactor and at least a portion of the feedstock is converted to pyrolysis gases within the pyrolysis conduit segment, which are discharged through a gas outlet.

A gasification process may include (a) introducing a liquid hydrocarbon feedstock and at least one of a dry feedstock or a first slurried feedstock into a reactor lower section, wherein the at least one dry feedstock or first slurried feedstock is introduced through two primary feed nozzles while the liquid hydrocarbon feedstock is introduced through at least two secondary feed nozzles; (b) partially combusting the feedstocks in the reactor lower section with a gas stream comprising an oxygen-containing gas or steam to evolve heat and form products comprising hot synthesis gas; (c) passing said hot synthesis gas from step (b) upward into a reactor upper section; (d) and introducing a second slurried feedstock into said reactor upper section, whereby heat from said hot synthesis gas supports reaction of the second slurried feedstock by pyrolysis and gasification reactions.

A system and method for the pyrolysis of a pyrolysis feedstock utilizes a pyrolysis reactor having a pyrolysis conduit and a solids return conduit segment. Each segment is configured with an outlet and an inlet to receive and discharge solid materials that are circulated through the reactor through the different segments. A solids conveyor is disposed within the pyrolysis conduit segment to facilitate conveying solid materials from the solids inlet upward through the pyrolysis conduit segment toward the solids discharge outlet. A pyrolysis feedstock is introduced into the pyrolysis reactor and at least a portion of the feedstock is converted to pyrolysis gases within the pyrolysis conduit segment, which are discharged through a gas outlet. An eductor condenser unit with an eductor assembly having a venturi-restricted flow path for receives a pressurized coolant fluid. A second flow path for receiving the discharged pyrolysis gases intersects the venturi-restricted flow path so that the received pyrolysis gases are combined with the coolant fluid and are discharged together to a mixing chamber that is used to condense pyrolysis gases.

A pyrolysis plant 20 comprises a grinding pyrolyzer 22, being a machine or apparatus in which both particle size reduction and pyrolysis occur simultaneously. Plant 20 also comprises a bin (hopper) 30 for holding wet particulate biomass feedstock. Chute 32 leads from the bin 30 to a biomass dryer 34 which reduces moisture content of the feedstock as low as possible, e.g., to below about 10. Dried feedstock is conveyed from dryer 34 via line 36 to a dried biomass feedstock hopper 38. Dried feedstock is fed from hopper 38 into a chute 40 which leads to an inlet trunnion 42 of grinding pyrolyzer 22. A discharge trunnion 44 of grinding pyrolyzer 22 leads to a char holder 60 for collecting char particles and a condensation train 62 for condensing vapor generated by the pyrolysis to produce oil.

A system and method for gasification of a feedstock in a subterranean formation to produce syngas is described. An injection well is completed in the formation to inject an oxidant, provide an ignition source and convey the feedstock that includes water and one or more of a biomass, waste plastic, coal, bitumen and petcoke. Volatized hydrocarbons and gaseous reaction products are simultaneously withdrawn from a producer well from the subterranean formation to the surface. This syngas product is treated at the surface for power generation or conversion to transportation fuels and/or plastics. This method provides a low capital cost gasification unit which is capable of processing a variety of feedstock mixtures.