Patent classifications
C10J2300/0943
Process and Device for Producing Hydrogen, Carbon Monoxide and a Carbon-Containing Product
The invention relates to a process for producing hydrogen, carbon monoxide and a carbon-containing product in at least one reaction apparatus, wherein the at least one reaction apparatus comprises a bed of carbon-containing material and is characterized in that the bed of carbon-containing material in the at least one reaction apparatus is alternately heated to a temperature of >800° C. and, no later than upon reaching a temperature of 1800° C., cooled to a maximum of 800° C., wherein hydrogen and carbon monoxide are produced during the heating phase and carbon and hydrogen are produced during the cooling phase.
REDUCING CARBON EMISSIONS ASSOCIATED WITH WASTE GAS
Methods of the present disclosure may comprise: introducing a first effluent and a second effluent in a gasifier of a partial oxidation unit to produce a waste gas, wherein the first effluent comprises one or more hydrocarbon containing feeds and the second effluent comprises air, enriched air with oxygen or oxygen; selectively removing hydrogen sulfide (H.sub.2S) from the waste gas; combining the waste gas and steam in a water-gas shift unit to produce a shift gas comprising hydrogen and carbon dioxide; separating the carbon dioxide from the shift gas in a carbon capture unit to produce a carbon dioxide-enriched effluent and an effluent comprising a hydrogen- and nitrogen-enriched mixture; and recovering the carbon dioxide from the carbon dioxide-enriched effluent.
Method and apparatus for integrating pressurized hydrocracking of heavy oil and coke gasification
The present disclosure provides a method and an apparatus for integrating pressurized hydrocracking of heavy oil and coke gasification. A coupled reactor having a cracking section and a gasification section is used in the method: a heavy oil feedstock and a hydrogenation catalyst are fed into a cracking section, to generate light oil-gas and coke; the coke is carried by the coke powder into the gasification section, to generate syngas; a regenerated coke powder is returned to the cracking section; the syngas enters the cracking section and merges with light oil-gas, and enters a gas-solid separator, to separate out first-stage solid particles and second-stage particles in sequence, and a purified oil-gas product is collected; oil-gas fractionation of the purified oil-gas product is performed, and a light oil product and a syngas product are collected. Yield and quality of the light oil can be improved by the method.
Gasification of plastics and solid fossil fuels to produce organic compounds
Pre-ground plastics of small particle size not more than 2 mm are co-fed into a solid fossil fuel fed entrained flow partial oxidation gasifier. High solids concentrations in the feedstock stream can be obtained without significant impact on the feedstock stream stability and pumpability. A consistent quality of syngas can be continuously produced, including generation of carbon dioxide and a carbon monoxide/hydrogen ratio while stably operating the gasifier and avoiding the high tar generation of fluidized bed or fixed bed waste gasifiers and without impacting the operations of the gasifier. The subsequent syngas produced from this material can be used to produce a wide range of chemicals.
TWO-STAGE GASIFIER AND GASIFICATION PROCESS WITH FEEDSTOCK FLEXIBILITY
A gasification process may include (a) introducing a liquid hydrocarbon feedstock and at least one of a dry feedstock or a first slurried feedstock into a reactor lower section, wherein the at least one dry feedstock or first slurried feedstock is introduced through two primary feed nozzles while the liquid hydrocarbon feedstock is introduced through at least two secondary feed nozzles; (b) partially combusting the feedstocks in the reactor lower section with a gas stream comprising an oxygen-containing gas or steam to evolve heat and form products comprising hot synthesis gas; (c) passing said hot synthesis gas from step (b) upward into a reactor upper section; (d) and introducing a second slurried feedstock into said reactor upper section, whereby heat from said hot synthesis gas supports reaction of the second slurried feedstock by pyrolysis and gasification reactions.
Integrated method and apparatus for catalytic cracking of heavy oil and production of syngas
The present disclosure provides an integrated method and apparatus for catalytic cracking of heavy oil and production of syngas. A cracking-gasification coupled reactor having a cracking section and a gasification section is used as a reactor in the method. A heavy oil feedstock is fed into a cracking section to contact with a bed material in a fluidized state that contains a cracking catalyst, a catalytic cracking reaction is conducted under atmospheric pressure to obtain light oil-gas and coke. The coke is carried downward by the bed material into a gasification section to conduct a gasification reaction to generate syngas; the syngas goes upward into the cracking section to merge with the light oil-gas, and is guided out from the coupled reactor and enter a gas-solid separation system. Oil-gas fractionation is performed to a purified oil-gas product output from the gas-solid separation system to collect light oil and syngas products.
Method and device for heavy oil lightening and synthesis gas production
A method for heavy oil lightening and synthesis gas production and a device thereof are provided, where the method uses a cracking/gasification coupled reactor, which internally has a cracking section and a gasification section that communicate with each other, and includes the following steps: feeding a heavy oil material into the cracking section to implement a cracking reaction, to produce a light oil gas and a coke; the coke being carried by the coke powders and descending into the gasification section to implement a gasification reaction, to produce a synthesis gas; at least performing a first stage gas-solid separation, collecting coke powder particles and dividing them into two parts; performing an oil and gas fractionation on a purified oil and gas product output by the gas-solid separation system, and collecting a light oil product and a synthesis gas product.
Integrated method and integrated device for heavy oil contact lightening and coke gasification
An integrated method and an integrated device for heavy oil contact lightening and coke gasification are provided. The integrated method uses a coupled reactor including a cracking section and a gasification section, and the integrated method includes: feeding a heavy oil material into the cracking section to implement a cracking reaction, to obtain a light oil gas and a carbon-deposited contact agent; passing the carbon-deposited contact agent into the gasification section, so as to implement a gasification reaction, to obtain a regenerated contact agent and a syngas; and discharging the light oil gas and the ascended and incorporated syngas from the cracking section, to perform a gas-solid separation, so that the carbon-deposited contact agent carried is separated and returned to the cracking section, and a purified oil gas is obtained at the same time.
Demetallization by delayed coking and gas phase oxidative desulfurization of demetallized residual oil
The invention is an integrated process for treating residual oil of a hydrocarbon feedstock. The oil is first subjected to delayed coking and then oxidative desulfurization. Additional, optional steps including hydrodesulfurization, and hydrocracking, may also be incorporated in to the integrated process.
Method for reducing the tar content in pyrolysis gas
Disclosed is a method for reducing the tar content in pyrolysis gas generated in a pyrolysis reactor (1). The method comprises the steps of: guiding the pyrolysis gas through a filter (2) to remove at least 90% of all the particles in the pyrolysis gas having a particle size down to 7μ and preferably down to 4μ from the pyrolysis gas, partially oxidizing the pyrolysis gas in a partial oxidation reactor (3) to remove tar from the pyrolysis gas, and guiding the pyrolysis gas through a coke bed (4) to further remove tar from the pyrolysis gas. Furthermore, a two-stage gasifier (6) is disclosed.