An ASG system for polygeneration with CC includes a devolatilizer that pyrolyzes solid fuel to produce char and gases. A burner adds exothermic heat by high-pressure sub-stoichiometric combustion, a mixing pot causes turbulent flow of the gases to heat received solid fuel, and a riser micronizes resulting friable char. A devolatilizer cyclone separates the micronized char by weight providing micronized char, steam and gases to a gasifier feed and oversized char to the mixing pot. An indirect fluid bed gasifier combustion loop includes a gasifier coupled to the gasifier feed, a steam input to provide oxygen for gasification and to facilitate sand-char separation, and an output for providing syngas. A burner provides POC to a mixing pot which provides hot sand with POC to a POC cyclone via a riser, where the POC cyclone separates sand and POC by weight and provides POC and sand for steam-carbon reaction.

The present disclosure relates to a modified gasification system (100) for producing syngas from waste materials having moisture content. The gasification system (100) has crossflow arrangement for circulation of gases across the solids present and has well-defined drying (120), pyrolysis (130) and gasification zones (140). A burner (150) of the gasification system (100) situated downstream of the pyrolysis zone (130) is configured to receive the pyrolysis product and a secondary oxidizer to produce a burner output gas and to supply the burner output gas to the pyrolysis zone (130) and gasification zone (140). The gasification zone (140) is additionally configured to receive a primary oxidizer gas and a tertiary oxidizer gas to aid gasification. The present disclosure overcomes limitation of the prior-arts and provides means of isolating the drying, pyrolysis, and gasification zones and eliminates tar formation during gasification. The gasification system (100) disclosed herein is a fully scalable equipment.

An apparatus and methods to eliminate PFAS from wastewater biosolids through fluidized bed gasification. The gasifier decomposes the PFAS in the biosolids at temperatures of 900-1800° F. Synthesis gas (syngas) exits the gasifier which is coupled to a thermal oxidizer and is combusted at temperatures of 1600-2600° F. This decomposes PFAS in the syngas and creates flue gas. Heat can be recovered from the flue gas by cooling the flue gas to temperatures of 400-1200° F. in a heat exchanger that is coupled with the thermal oxidizer. Cooled flue gas is mixed with hydrated lime, enhancing PFAS decomposition, with the spent lime filtered from the cooled flue gas using a filter system that may incorporate catalyst impregnated filter elements. The apparatus and methods thereby eliminate PFAS from wastewater biosolids and control emissions in the resulting flue gas.

A first voltage source produces a first voltage such as an AC voltage. Further, a first electrode of a hydrogen generation system conveys the first voltage. The first voltage conveyed over the first electrode generates low-temperature plasma extending between the first electrode and the mass of material. Presence of the low-temperature plasma releases gas from the mass of material.

Electric-powered, closed-loop, continuous-feed, endothermic energy-conversion systems and methods are disclosed. In one embodiment, the presently disclosed energy-conversion system includes a shaftless auger. In another embodiment, the presently disclosed energy-conversion system includes a drag conveyor. In yet another embodiment, the presently disclosed energy-conversion system includes a distillation and/or fractionating stage. The endothermic energy-conversion systems and methods feature mechanisms for natural resource recovery, refining, and recycling, such as secondary recovery of metals, minerals, nutrients, and/or carbon char.

A process and system for liquefying and plasticizing a waste plastic in a pyrolysis film reactor are provided. More particularly, a liquefied waste plastic, which may include halogen-depleted molten waste plastics, may be pyrolyzed in a pyrolysis film reactor to form a pyrolysis oil and a pyrolysis gas. The pyrolysis film reactors may include a falling film reactor and/or an upflow film reactor.

A hydrogen composition having a recycle content value is obtained by processing a recycle content feedstock to make a recycle content hydrogen or by deducting from a recycle inventory a recycle content value applied to a hydrogen composition. At least a portion of the recycle content value in the feedstock or in an allotment obtained by a hydrogen manufacturer has its origin in recycled waste plastics.

The present invention relates to a method for gasification of carbon-containing materials including biohazard wastes, and more specifically, to a method for gasification of carbon-containing materials which allows an increase in carbon efficiency and a reduction in carbon dioxide emission, comprising the steps of: biohazard wastes grinding and sterilization, mix with carbon-containing materials for the gasification; and catalytic production of diesel fuel. A system having a movable platform including: material preparation block, gasification and catalytic of diesel fuel production reactors which are structurally and functionally integrated. In the practice of the process, a mixture of carbon-containing materials, a compressed air feed and process steam is fed to the gasifier to produce a synthesis gas. The synthesis gas is fed to the Fischer-Tropsch reactor where it is catalytically reacted to produce heavy hydrocarbons. The outlet from the Fischer-Tropsch reactor is separated into water, a low heating value tail gas, and the desired hydrocarbon liquid product. The water is pressurized and heated to generate process steam. The system further includes a plurality of heat exchangers that enable heat to be recovered from the outlet of the gasifier. The recovered heat is used to make the process steam as well as to preheat the hydrocarbon mix before it is fed to the gasifier and preheat the synthesis gas before it is fed to the Fischer-Tropsch reactor. The method of the present invention greatly increases carbon efficiency and reduces the generation of carbon dioxide.

Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

A method for preparing high-temperature, active particle-containing steam. The method includes: 1) preparing steam; selecting one or several non-oxidizing gases as a working gas; ionizing the working gas into a plasma working medium by using a plasma generator; and 2) injecting the plasma working medium into a high-temperature steam generator to form high-temperature ionized environment while introducing the steam into the high-temperature steam generator for allowing the steam to contact with the plasma working medium so that the steam is heated and activated to form active particle-containing steam. A device for preparing the high-temperature, active particle-containing steam is also provided.