Systems and methods are provided for integration of electrolysis with biomass gasification to generate synthesis gas that can be used for production of renewable fuels and/or other hydrocarbonaceous compounds. The hydrocarbonaceous compounds can include compounds formed by chemical synthesis, such as alkanes formed by a Fischer-Tropsch process or methanol formed by a methanol synthesis process; or the hydrocarbonaceous compounds can include compounds formed by fermentation, such as alcohols formed by micro-organisms that use the synthesis gas as an input feed.

The invention is directed to a process to prepare an activated carbon product and a gaseous fraction comprising hydrogen, carbon monoxide and a mixture of gaseous organic compounds from a solid torrefied biomass feed comprising the following steps. (i) subjecting the solid biomass feed to a pyrolysis reaction thereby obtaining a gaseous fraction comprising hydrogen, carbon monoxide and a mixture of gaseous organic compounds and a solid fraction comprising of char particles. (ii) separating the solids fraction from the gaseous fraction. and (iii) activating the char particles as obtained in step (ii) to obtain the activated carbon product.

A two-stage syngas production method to produce a final product gas from a carbonaceous material includes producing a first product gas in a first reactor, separating char from the first product gas to produce separated char and char-depleted product gas, and separately reacting the separated char and the char-depleted product gas with an oxygen-containing gas in a second reactor to produce a final product gas. The separated char is introduced into the second reactor above the char-depleted product gas. The solids separation device may include serially connected cyclones, and the separated char may be entrained in a motive fluid in an eductor to produce a char and motive fluid mixture prior to being transferred to the second reactor. A biorefinery method produces a purified product from the final product gas.

Disclosed is a hydrogen generation furnace using decomposition of biomass steam, which employs an infrared source and a furnace body with a water-accommodating structure. A steam separation-drying device is cylindrical and provided at an upper part of an interior of the furnace body and a cavity of the steam separation-drying device forms a secondary gasifier. A lattice plate is provided at a bottom of the interior of the furnace body. A lattice combustion grate is provided above a middle of the lattice plate. A steam distributor is provided outside a lower part of the furnace body. The furnace of the invention performs gasified gas separation as well as secondary oxidation and gasification and mixes steam with gas generated from biomass to perform a decomposition reaction for generating hydrogen.

The invention relates to a method and process arrangement for producing hydrocarbons from plastic containing raw material by means of a gasification process in which the plastic containing raw material is gasified with steam at low gasification temperature of 680-740° C. in a fluidized bed gasifier for forming a product mixture comprising hydrocarbons, and the residence time is below 4 s at the gasification temperature, and the product mixture is cooled rapidly after the gasification to temperature which is below 640° C. for slowing and/or stopping the gasification reaction of the plastic containing raw material in order to increase propylene yield of the gasification process. Further, the invention relates to the use of the method.

A zero emission waste system comprising a waste treatment unit that couples to a facility. The waste treatment unit is onsite with the facility either within the facility or local to the facility for treating waste produced by the facility. Alternatively, the waste treatment unit can be mobile that is designed to couple to the facility for waste disposal. The waste treatment unit comprises a gasification reactor, a syngas treatment unit, and a synthetic fuel generator for treating and converting waste. The synthetic fuel generator comprises an electrolysis unit and a liquid fuel synthesis unit. The waste treatment unit converts the waste to synthetic fuel, gaseous fuel, oxygen, heat, slag, and other components that are useful to the facility or other entities. The waste treatment system uses carbon dioxide generated during a waste conversion process thereby producing substantially zero emissions and eliminating waste that could be harmful to the environment.

A medical zero emission waste system comprising a medical waste treatment unit that couples to a medical facility. The medical waste treatment unit is onsite to the medical facility for processing medical waste generated by the medical facility. The medical waste treatment unit comprises a gasification reactor, a syngas treatment unit, and a synthetic fuel generator for treating and converting medical waste. The synthetic fuel generator comprises an electrolysis unit and a liquid fuel synthesis unit. The medical waste treatment unit converts the medical waste to synthetic fuel, gaseous fuel, oxygen, heat, slag, and other components that are useful to the medical facility or other entities. The medical waste treatment system uses carbon dioxide generated during a medical waste conversion process thereby producing substantially zero emissions and eliminating medical waste that could be harmful to the environment.

The present invention provides a process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; recovering at least part of the raw synthesis gas from the gasification zone and supplying at least part of the recovered raw synthesis gas to a partial oxidation zone; equilibrating the H.sub.2:CO ratio of the raw synthesis gas in the partial oxidation zone to obtain equilibrated synthesis gas; recovering at least part of the equilibrated synthesis gas from the partial oxidation zone and treating the gas to remove impurities and generate a fine synthesis gas; optionally adjusting the H.sub.2:CO ratio of at least part of the fine synthesis gas to obtain adjusted fine synthesis gas; and converting the optionally adjusted fine synthesis gas into the useful product in a further chemical reaction requiring a usage ratio; wherein the fine synthesis gas H2:CO ratio is below the usage ratio and wherein any optional adjustment of at least part of the fine synthesis gas H.sub.2:CO ratio is effective to increase the H.sub.2:CO ratio in the fine synthesis gas to a level at, nearer to or above the usage ratio; wherein the H.sub.2:CO ratio of the raw synthesis gas fluctuates during operation of the process as a result of the fluctuating compositional characteristics of the carbonaceous feedstock by a percentage of ±x; and the H.sub.2:CO ratio of the equilibrated synthesis gas does not fluctuate during operation of the process or fluctuates during operation of the process as a result of the fluctuating compositional characteristics of the carbonaceous feedstock by a percentage±y, y being a lower percentage than x.

A plant, such as a hydrocarbon plant, is provided, which has a syngas stage (A) for syngas generation and a synthesis stage (B) where said syngas is synthesized to produce syngas derived product, such as hydrocarbon product. The syngas stage (A) primarily includes electrically heated reverse water gas shift (e-RWGS) section. Additionally, an electrically-heated steam methane reforming (e-SMR) section (II) can be arranged in parallel to the e-RWGS section (I). The plant makes effective use of various streams; in particular CO2 and H2. A method for producing a product stream, such as a hydrocarbon product stream is also provided.

The disclosure relates to a rotary kiln catalytically enhanced oxy-fuel gasification and oxy-fuel combustion system—power plant including an air separation unit arranged to separate oxygen from air and produce a stream of substantially pure liquid oxygen; rotary kiln gasifiers to convert municipal solid waste, biomass, alternate wastes, coal, or hydrocarbon fuels into a synthesis gas in the presence of oxygen, carbon dioxide, high temperature steam and lime catalysts; an oxy-fuel fired boiler arranged to combust synthesis gas, in the presence of substantially pure oxygen gas, to produce an exhaust gas comprised of water and carbon dioxide; and a carbon dioxide removal unit arranged to recover carbon dioxide gas from the exhaust gas, recycle a portion of the recovered carbon dioxide gas for use in the rotary kiln gasifier, and liquefy the remainder of the recovered carbon dioxide gas for removal from the plant. In this new plant, the carbon dioxide removal unit is thermally integrated with the air separation unit or alternately the liquid oxygen storage and supply system by directing a stream of liquid oxygen to the carbon dioxide removal unit to liquefy the recovered carbon dioxide gas, the liquid oxygen thereby evaporating and forming cold oxygen gas which is heated prior to consumption in the rotary kiln and oxy-fuel fired boiler.