Patent classifications
C10J2300/1621
Arrangement and method for preparing a gas
The invention relates to an arrangement for preparing a gas in a closable reactor by supplying the reactor with carbon-based biomass or chopped wood material, such as chips, in substantially oxygen-free conditions, by allowing the biomass or wood material to gasify at a high temperature, and by recovering the gas generated in a gasification reaction. In that the arrangement the reactor has its interior defined by a feed pipe whose inlet end is closable with a shut-off valve, especially with a ball valve, and whose outlet end adjoins a heatable gasification dome, biomass or chopped wood material is delivered from the feed pipe's inlet end into the reactor's interior, the reactor's interior is supplied with free water/water vapor in its supercritical state, which is optionally prepared catalytically by splitting water/water vapor, the biomass or wood material is conveyed into a gasification space of the reactor's interior, which is in connection with the heated gasification dome and which is adapted to have existing conditions selected in a manner such that the water present in said gasification space is present in its supercritical state, and the gas generated in the gasification reaction is recovered.
Multi-Purpose Application of the Second Stage of a 2-Stage Bio-Reforming Reactor System for Reforming Bio-Syngas, Natural Gas and Process Recycle Streams
Multiple stages of reactors form a bio-reforming reactor that generates chemical grade bio-syngas for any of 1) a methanol synthesis reactor, 2) a Methanol-to-Gasoline reactor train, 3) a high temperature Fischer-Tropsch reactor train, and 4) any combination of these three that use the chemical grade bio-syngas derived from biomass fed into the bio-reforming reactor. A tubular chemical reactor of a second stage has inputs configured to receive chemical feedstock from at least two sources, i) the raw syngas from the reactor output of the first stage via a cyclone, and ii) purge gas containing renewable carbon-based gases that are recycled back via a recycle loop as a chemical feedstock from any of 1) the downstream methanol-synthesis-reactor train, 2) the downstream methanol-to-gasoline reactor train, or 3) purge gas from both trains. The plant produces fuel products with solely 100% biogenic carbon content as well as fuel products with 50-100% biogenic carbon content.
Burner with only oxidation reaction space for reactor with only reduction reaction space
The present disclosure provides a burner for a reduction reactor, the reduction reactor has a reaction space formed therein, wherein each burner has a fuel feeding hole and multiple oxygen feeding holes formed therein, wherein each burner has an elongate combustion space formed at one end of a head portion thereof, the combustion space fluid-communicating with the reaction space of the reactor, wherein the elongate combustion space has a length such that oxygen supplied from the oxygen feeding holes thereto is completely consumed via oxidation or combustion with fuels supplied from the fuel feeding hole thereto only in the elongate combustion space upon igniting the burner.
METHODS AND APPARATUS FOR RECYCLING TAIL GAS IN SYNGAS FERMENTATION TO ETHANOL
The invention present provides a method (and suitable apparatus) to convert biomass to ethanol, comprising gasifying the biomass to produce raw syngas; feeding the raw syngas to an acid-gas removal unit to remove at least some CO.sub.2 and produce a conditioned syngas stream; feeding the conditioned syngas stream to a fermentor to biologically convert the syngas to ethanol; capturing a tail gas from an exit of the fermentor, wherein the tail gas comprises at least CO.sub.2 and unconverted CO or H.sub.2; and recycling a first portion of the tail gas to the fermentor and/or a second portion of the tail gas to the acid-gas removal unit. This invention allows for increased syngas conversion to ethanol, improved process efficiency, and better overall biorefinery economics for conversion of biomass to ethanol.
NET-ZERO HYDROGEN PLANTS AND METHODS OF OPERATION
The present invention relates to net-zero hydrogen plants and methods of operating said plants having a lower cost and much larger scale compared to electrolysis driven plants utilized to produce green hydrogen.
SYSTEM AND METHOD FOR POWER PRODUCTION USING PARTIAL OXIDATION
The present disclosure relates to a power production system that is adapted to achieve high efficiency power production using partial oxidation of a solid or liquid fuel to form a partially oxidized stream that comprises a fuel gas. This fuel gas stream can be one or more of quenched, filtered, and cooled before being directed to a combustor of a power production system as the combustion fuel. The partially oxidized stream is combined with a compressed recycle CO.sub.2 stream and oxygen. The combustion stream is expanded across a turbine to produce power and passed through a recuperator heat exchanger. The expanded and cooled exhaust stream can be further processed to provide the recycle CO.sub.2 stream, which is compressed and passed through one or more recuperator heat exchangers in a manner useful to provide increased efficiency to the combined systems.
Various methods and apparatuses for multi-stage synthesis gas generation
A multiple stage synthesis gas generation system is disclosed including a high radiant heat flux reactor, a gasifier reactor control system, and a Steam Methane Reformer (SMR) reactor. The SMR reactor is in parallel and cooperates with the high radiant heat flux reactor to produce a high quality syngas mixture for MeOH synthesis. The resultant products from the two reactors may be used for the MeOH synthesis. The SMR provides hydrogen rich syngas to be mixed with the potentially carbon monoxide rich syngas from the high radiant heat flux reactor. The combination of syngas component streams from the two reactors can provide the required hydrogen to carbon monoxide ratio for methanol synthesis. The SMR reactor control system and a gasifier reactor control system interact to produce a high quality syngas mixture for the MeOH synthesis.
VARIOUS METHODS AND APPARATUSES FOR MULTI-STAGE SYNTHESIS GAS GENERATION
A multiple stage synthesis gas generation system is disclosed including a high radiant heat flux reactor, a gasifier reactor control system, and a Steam Methane Reformer (SMR) reactor. The SMR reactor is in parallel and cooperates with the high radiant heat flux reactor to produce a high quality syngas mixture for MeOH synthesis. The resultant products from the two reactors may be used for the MeOH synthesis. The SMR provides hydrogen rich syngas to be mixed with the potentially carbon monoxide rich syngas from the high radiant heat flux reactor. The combination of syngas component streams from the two reactors can provide the required hydrogen to carbon monoxide ratio for methanol synthesis. The SMR reactor control system and a gasifier reactor control system interact to produce a high quality syngas mixture for the MeOH synthesis.
Methods and apparatus for recycling tail gas in syngas fermentation to ethanol
The invention present provides a method (and suitable apparatus) to convert biomass to ethanol, comprising gasifying the biomass to produce raw syngas; feeding the raw syngas to an acid-gas removal unit to remove at least some CO.sub.2 and produce a conditioned syngas stream; feeding the conditioned syngas stream to a fermentor to biologically convert the syngas to ethanol; capturing a tail gas from an exit of the fermentor, wherein the tail gas comprises at least CO.sub.2 and unconverted CO or H.sub.2; and recycling a first portion of the tail gas to the fermentor and/or a second portion of the tail gas to the acid-gas removal unit. This invention allows for increased syngas conversion to ethanol, improved process efficiency, and better overall biorefinery economics for conversion of biomass to ethanol.
System and methods of processing waste to generate energy and green hydrogen
Systems and methods for producing green hydrogen from a source material (e.g., biowaste) are contemplated. The source material is at least partially dehydrated to produce a dried intermediate and recovered water. The dried intermediate is pyrolyzed to produce syngas and a char. The recovered water is electrolyzed to produce oxygen and green hydrogen.