Apparatus and methods to eliminate PFAS from wastewater biosolids through fluidized bed gasification. The gasifier decomposes the PFAS in the biosolids at temperatures of 900-1800° F. Syngas exits the gasifier which is coupled to a thermal oxidizer and combusts at temperatures of 1600-2600° F. This decomposes PFAS in the syngas and creates flue gas. Heat is recovered from the flue gas by cooling the flue gas to temperatures of 400-1200° F. in a heat exchanger coupled with the thermal oxidizer. Various methods inject moisture into the gas stream, controlling temperature through evaporative cooling and/or injecting chemicals that react with gas stream components. Cooled flue gas mixes with hydrated lime capturing decomposed PFAS molecules with spent lime filtered from the cooled flue gas using a filter system that may incorporate catalyst impregnated filter elements, eliminating PFAS from wastewater biosolids and controlling emissions in the resulting flue gas.

A reactor enables gasification or melting of waste and additional feed materials. The reactor includes a co-current section with a plenum section and a feed section with a sluice. Feed materials are introduced into the reactor. The reactor further includes a buffer section and a pre-treatment section, which adjoins a bottom of the buffer section to create a cross-sectional enlargement. An intermediate section adjoins the pre-treatment section. An upper oxidation section adjoins a bottom of the intermediate section and includes tuyeres in at least one level. An upper reduction section adjoins a bottom of the upper oxidation section. The reactor further includes a gas outlet section. The reactor further includes a countercurrent section having a conical lower reduction section and a conical lower oxidation section adjoining the conical lower reduction section having at least one tuyere and at least one tapping.

A gas generation plant for generating hydrogen-containing synthesis gas includes a gas generation reactor which is oriented in the vertical direction being greater in length vertically than width. A gas inlet is designed for the passage of superheated water vapor into the gas generation reactor. Through an upper outlet, a gas/water vapor mixture can exit the gas generation reactor and be reused in the second heating element after having been superheated. Synthesis gas can exit through a lower gas outlet. In the vertical direction, the gas inlet is arranged at a smaller distance from the lower end than the lower gas outlet. The upper gas outlet is arranged at a smaller vertical distance from the upper end than the lower gas outlet. The vertical distance between the upper gas outlet and the lower gas outlet is greater than the vertical distance between the lower gas outlet and the gas inlet.

A reactor enables gasification or melting of waste and additional feed materials. The reactor includes a co-current section with a plenum section and a feed section with a sluice. Feed materials are introduced into the reactor. The reactor further includes a buffer section and a pre-treatment section, which adjoins a bottom of the buffer section to create a cross-sectional enlargement. An intermediate section adjoins the pre-treatment section. An upper oxidation section adjoins a bottom of the intermediate section and includes tuyeres in at least one level. An upper reduction section adjoins a bottom of the upper oxidation section. The reactor further includes a gas outlet section. The reactor further includes a countercurrent section having a conical lower reduction section and a conical lower oxidation section adjoining the conical lower reduction section having at least one tuyere and at least one tapping.

Provided are a slag crusher, a gasifier, an integrated gasification combined cycle, and an assembly method of a slag crusher that can ensure the strength of a guide rod. The slag crusher includes: a porous member screen; a spreader that is reciprocated in a predetermined direction along a top surface of the screen and crushes the slag accumulated on the screen; and a guide rod having an axis line along the predetermined direction, is connected to the spreader, and restricts a moving direction of the spreader, the guide rod has a spreader-side member connected to the spreader and a shaft member connected to the spreader-side member, the spreader-side member and the shaft member are connected by butt welding in the axis line direction, and the spreader-side member and the shaft member have the same shape of cross sections orthogonal to the axis line direction at a butt welding position.

Fuel and fuel additives can be produced by processes that provide Fischer-Tropsch liquids having high biogenic carbon concentrations of up to about 100% biogenic carbon. The fuels and fuel additive have essentially the same high biogenic concentration as the Fischer-Tropsch liquids which, in turn, contain the same concentration of biogenic carbon as the feedstock.

Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

An apparatus for fuel gas production and combustion comprises a solid fuel feeding unit for receiving and feeding solid fuel; a gas producing unit being connected to the solid fuel feeding unit for receiving solid fuel from the solid fuel feeding unit; an air feeding unit connected to the gas producing unit for feeding air to the gas producing unit to cause a gasification reaction; an ash trapping unit connected to the gas producing unit for separating fly ash and dust from the fuel gas; a burner unit connected to the ash trapping unit for combusting the fuel gas; and an ash discharging unit connected to the gas producing unit and ash trapping unit and comprising a bottom ash discharging part and a fly ash discharging part, characterized in that the air feeding unit comprises a plurality of air feeding parts wherein at least one air feeding part being connected to the gas producing unit and at least one air feeding part being connected to the ash trapping unit.

Provided are methods or preparing coal ash with acceptable concentrations of sulfur and/or carbon for using making concrete, as well as the coal ash products produced by the described methods.

A method and system for continuous production of contaminant free and size specific biochar using downdraft gasification of variable quality feedstock. The system and process of the present invention includes the transfer of biochar from a gasifier after gasification to a temperature-controlled cooling screw conveyor, into a drum magnet for ferrous metal removal into multiple diverters to separate and remove ungasified materials and non-ferrous metal contaminants, then transferred into a granulator for grinding and screening the biochar to a pre-selected size. By directly attaching a novel and continuous product treatment process to the biochar stream as it exits the gasifier, the particle size, moisture content, carbon content and yield of a contaminant free biochar product can be narrowly controlled and improved to meet strict product quality specifications required by specialty applications.