The present invention provides a process for the manufacture of a synthetic fuel comprising gasifying a carbonaceous feedstock comprising waste materials and/or biomass to generate a raw synthesis gas; supplying the raw synthesis gas to a primary clean-up zone to wash particulates and ammonia or HCl out of the raw synthesis gas; contacting the synthesis gas in a secondary clean-up zone with a physical solvent for sulphurous materials; contacting the desulphurised raw synthesis gas in a tertiary clean-up zone with a physical solvent for CO.sub.2 effective to absorb CO.sub.2; removing at least part of the absorbed CO.sub.2 in a solvent regeneration stage to recover CO.sub.2 in a form sufficiently pure for sequestration or other use; and supplying the clean synthesis gas to a further reaction train to generate a synthetic fuel.

Methods and systems for processing construction and demolition (C&D) materials to produce a product gas stream and/or electricity are disclosed herein. In some embodiments, the method comprises pre-processing C&D materials to produce a C&D feed, and processing the C&D feed to produce syngas. The C&D feed can comprise untreated wood, treated wood, paper and cardboard, yard waste, plastic, rubber, and/or foam. Processing the C&D feed can comprise gasifying the C&D feed, steam, and oxygen in a gasifier at a temperature of no more than 950° C. and/or a pressure of no more than 200 psi to produce syngas.

Provided are methods or preparing coal ash with acceptable concentrations of sulfur and/or carbon for using making concrete, as well as the coal ash products produced by the described methods.

The disclosure relates to a rotary kiln catalytically enhanced oxy-fuel gasification and oxy-fuel combustion system—power plant including an air separation unit arranged to separate oxygen from air and produce a stream of substantially pure liquid oxygen; rotary kiln gasifiers to convert municipal solid waste, biomass, alternate wastes, coal, or hydrocarbon fuels into a synthesis gas in the presence of oxygen, carbon dioxide, high temperature steam and lime catalysts; an oxy-fuel fired boiler arranged to combust synthesis gas, in the presence of substantially pure oxygen gas, to produce an exhaust gas comprised of water and carbon dioxide; and a carbon dioxide removal unit arranged to recover carbon dioxide gas from the exhaust gas, recycle a portion of the recovered carbon dioxide gas for use in the rotary kiln gasifier, and liquefy the remainder of the recovered carbon dioxide gas for removal from the plant. In this new plant, the carbon dioxide removal unit is thermally integrated with the air separation unit or alternately the liquid oxygen storage and supply system by directing a stream of liquid oxygen to the carbon dioxide removal unit to liquefy the recovered carbon dioxide gas, the liquid oxygen thereby evaporating and forming cold oxygen gas which is heated prior to consumption in the rotary kiln and oxy-fuel fired boiler.

Disclosed is an adsorbent containing a metal oxide for adsorption of hydrogen sulfide in biogas, and a biogas purification system using the same.

A catalyst for COS hydrolysis includes titanium dioxide and a barium compound supported on the titanium dioxide. The catalyst, when expressing Ba and S in the catalyst in terms of BaO and SO.sub.3, respectively, has a molar ratio of SO.sub.3 to BaO of at least 1. The catalyst converts COS and H.sub.2O in a raw material gas to CO.sub.2 and H.sub.2S.

A gas purification device removes a part of ammonia contained in a first gas; recovers a first off-gas containing the removed ammonia, removes hydrogen sulfide and ammonia from a second gas produced by removing the part of ammonia, recovers a second off-gas containing the removed hydrogen sulfide and ammonia, and combusts the first off-gas and the second off-gas. The gas purification device includes: a first combustion chamber in which combustion is performed in a reducing atmosphere; a second combustion chamber in which combustion is performed in a reducing atmosphere downstream of the first combustion chamber; and a third combustion chamber in which combustion is performed in an oxidizing atmosphere downstream of the second combustion chamber. The first off-gas flows into the first combustion chamber and the second off-gas flows into the third combustion chamber.

A process for sweetening a syngas stream, the process comprising the steps of: providing a syngas stream to a nonselective amine absorption unit, the sour syngas stream comprising syngas, carbon dioxide, and hydrogen sulfide; separating the syngas stream in the nonselective amine absorption unit to obtain an overhead syngas stream and an acid gas stream; introducing the acid gas stream to a membrane separation unit, the acid gas stream comprising hydrogen sulfide and carbon dioxide; separating the acid gas stream in the membrane separation unit to produce a retentate stream and a permeate stream, wherein the retentate stream comprises hydrogen sulfide, wherein the permeate stream comprises carbon dioxide; introducing the retentate stream to a sulfur recovery unit; processing the retentate stream in the sulfur recovery unit to produce a sulfur stream and a tail gas stream, wherein the sulfur stream comprises liquid sulfur.

The invention relates to an aftertreatment arrangement (1.0) for the aftertreatment of at least gases downstream of a fluidized bed gasification process, in particular downstream of an HTW gasifier (1) of a pressure-loaded fluidized bed gasification process, having a particle separation unit (2; 11) which can be arranged downstream of the fluidized bed gasification process and upstream of a gas cooler (3) that can be used for the further aftertreatment of the gases, wherein the aftertreatment arrangement comprises an intermediate cooling unit (12) which can be arranged downstream of the fluidized bed gasification process and upstream of the particle separation unit (11), having a return (B1) for gasification steam (B) that can be coupled to the fluidized bed gasification process. Furthermore, the invention relates to a method for the aftertreatment of at least gases downstream of a fluidized bed gasification process as well as the use of an intermediate cooling unit.

The present invention provides a process and apparatus for converting feedstock comprising biomass and/or carbon-containing solid waste material to synthesis gas. The process comprises supplying the feedstock to a gasifier comprising a fluidized bed zone and a post-gasification zone and contacting the feedstock with a gasification agent at a plurality of different operating temperatures based on the ash softening temperature of the feedstock and finally recovering the synthesis gas. The apparatus is configured to perform the process and comprises a plurality of nozzles arranged at an acute angle relative to a horizontal plane of the gasifier.