Disclosed are methods useful in applications relating to blast furnace processes. The methods of the present invention provide enhanced deposition inhibition of particulate matter in top-pressure recovery turbines. The methods of the present invention comprise adding nitrogen-containing compounds to a top-pressure recovery turbine, inhibiting deposition of solids formed from blast furnace gas on top-pressure recovery turbine components.

Clean, safe and efficient methods, systems, and processes for utilizing thermolysis methods to processes to convert various carpet, rug, polymeric materials and other waste sources, such as solid waste, tires, manure, auto shredder residue, glass and carbon fiber composite materials, municipal solid wastes, medical wastes, waste wood and the like into a Clean Fuel Gas and Char source are disclosed. The invention processes the carpet, rug, polymeric material to effectively shred and/or grind the waste source, such as post-consumer carpet remnants and waste, and then process using thermolysis methods to destroy and/or separate halogen and other dangerous components to provide a Clean Fuel Gas and Char source. Additional waste sources, such as solid waste, tires, manure, auto shredder residue, glass and carbon fiber composite materials, municipal solid wastes, medical wastes, waste wood and the like, are suitable for the processing of the invention disclosed.

A process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.

A process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.

A method for Fischer-Tropsch synthesis, the method including: 1) gasifying a raw material to obtain a crude syngas including H.sub.2, CO and CO.sub.2; 2) electrolyzing a saturated NaCl solution using a chloralkali process to obtain a NaOH solution, Cl.sub.2 and H.sub.2; 3) removing the CO.sub.2 in the crude syngas using the NaOH solution obtained in 2) to obtain a pure syngas; and 4) insufflating the H.sub.2 obtained in 2) to the pure syngas to adjust a mole ratio of CO/H.sub.2 in the pure syngas, and then introducing the pure syngas for Fischer-Tropsch synthesis reaction. A device for Fischer-Tropsch synthesis includes a gasification device, an electrolyzer, a first gas washing device, and a Fischer-Tropsch synthesis reactor.

Systems and processes for treating acid gas from a sour gas stream are provided. A chemical looping combustion (CLC) process is provided that uses CaCO.sub.3 to capture sulfur from the acid gas and produce CaSO.sub.4. An acid gas treatment unit may receive an acid gas from an acid gas removal unit and produce the CaSO.sub.4 and various gas and air streams for use in heat exchangers for steam production. The acid gas treatment unit may include a fuel reactor, an oxidizer reactor, and a calciner reactor. Another acid gas treatment unit may include a fuel reactor that includes the calciner function and an oxidizer reactor. A selective membrane module may be disposed between the sour gas stream and an acid gas removal unit to produce a H.sub.2S and CO.sub.2 permeate that is mixed with the acid gas stream provided to the acid gas treatment unit.

Systems and processes for treating acid gas from a sour gas stream are provided. A chemical looping combustion (CLC) process is provided that uses CaCO.sub.3 to capture sulfur from the acid gas and produce CaSO.sub.4. An acid gas treatment unit may receive an acid gas from an acid gas removal unit and produce the CaSO.sub.4 and various gas and air streams for use in heat exchangers for steam production. The acid gas treatment unit may include a fuel reactor, an oxidizer reactor, and a calciner reactor. Another acid gas treatment unit may include a fuel reactor that includes the calciner function and an oxidizer reactor. A selective membrane module may be disposed between the sour gas stream and an acid gas removal unit to produce a H.sub.2S and CO.sub.2 permeate that is mixed with the acid gas stream provided to the acid gas treatment unit.

The disclosure related to processes for the high-selectivity conversion of olefins to monocyclic aromatic compounds, such as BTX, via the introduction of a weakly coordinating compound to a dehydroaromatization catalyst. Moreover, certain embodiments relate to processes for recycling polyaromatic compounds back to a reactor to improve the yield of said monocyclic aromatic compounds. Moreover, certain embodiments relate to processes for regenerating the dehydroaromatization catalyst.

Disclosed are methods useful in applications relating to blast furnace processes. The methods of the present invention provide enhanced deposition inhibition of particulate matter in top-pressure recovery turbines. The methods of the present invention comprise adding nitrogen-containing compounds to a top-pressure recovery turbine, inhibiting deposition of solids formed from blast furnace gas on top-pressure recovery turbine components.

A method for Fischer-Tropsch synthesis, the method including: 1) gasifying a raw material to obtain a crude syngas including H.sub.2, CO and CO.sub.2; 2) electrolyzing a saturated NaCl solution using a chloralkali process to obtain a NaOH solution, H.sub.2 and H.sub.2; 3) removing the CO.sub.2 in the crude syngas using the NaOH solution obtained in 2) to obtain a pure syngas; and 4) insufflating the H.sub.2 obtained in 2) to the pure syngas to adjust a mole ratio of CO/H.sub.2 in the pure syngas, and then introducing the pure syngas for Fischer-Tropsch synthesis reaction. A device for Fischer-Tropsch synthesis includes a gasification device, an electrolyzer, a first gas washing device, and a Fischer-Tropsch synthesis reactor.