Patent classifications
C10L2200/0453
Systems and methods for renewable fuel
The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.
MIXTURES OF TRIGLYCERIDES AND OF ALKYLESTERS FROM VEGETABLE OIL AND APPLICATIONS
A mixture of alkylesters of fatty acids is provided, wherein the fatty acids have the following composition: at least 56% of saturated C12 chains, at least 23% of saturated C14 chains, at most 8% of saturated C16 chains, at most 5% of saturated C6-10 chains, at most 5% of monounsaturated C18 chains, at most 2% of saturated C18 chains, at most 0.8% of diunsaturated C18 chains, and at most 0.2% of saturated C20 chains. The percentages are an average percentage expressed in number of moles per total number of moles of alkylesters, and the use of these mixtures is as a viscosity agent.
XANTHENES AS FUEL MARKERS
A method for marking a petroleum hydrocarbon or a liquid biologically derived fuel; said method comprising adding to said petroleum hydrocarbon or liquid biologically derived fuel at least one compound that is a R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 , R.sup.8, R.sup.9 and R.sup.10-substituted xanthene, wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9 and R.sup.10 independently are hydrogen, hydrocarbyl, hydrocarbyloxy, aryl or aryloxy; wherein each compound of formula (I) is present at a level from 0.01 ppm to 20 ppm.
FIRE STARTER
A fire starter includes a casing made from a first material a first material having a first time associated therewith that defines a length of time that the casing burns after being ignited. A second material disposed in the casing has a second time associated therewith that defines a length of time that the second material burns after being ignited. An igniter, disposed in the casing and adjacent to the second material, generates a first thermal event to ignite the second material wherein the second material combusts to define a second thermal event that ignites the first material. An actuator is coupled to the igniter and is positioned outside of the casing for activating the igniter to generate the first thermal event.
ADDITIVES FOR ENHANCEMENT OF OIL FLOW
Use of pyrolysis oil (commonly referred to as bio-oil, bio-crude or tire oil) in combination with naphtha or liquified petroleum gas (LPG) can be utilized to reduce viscosity, increase API gravity and/or liquify paraffin and/or asphaltene in heavy crude oil at a reduced, overall percentage of naphtha.
Terpene, citrus isolates and/or non-ionic surfactants can be added to pyrolysis oil to form an additive. The additive can be combined with naphtha or LPG and added to heavy crude oil to reduce viscosity, increase API gravity, and/or liquify paraffin and/or asphaltene at a reduced, overall percentage of naphtha.
Method to improve the efficiency of pipeline transportation of heavy oils
Disulfide oil (DSO) compounds recovered as a by-product of the mercaptan oxidation of a hydrocarbon refinery feedstock and their oxidized derivatives, oxidized disulfide oils (ODSO) are effective as a diluent to lower the viscosity and thereby improve the pipeline transportation properties of heavy oils, and particularly of wellhead crude oil. The use of the DSO and/or ODSO compounds as diluents converts an otherwise extremely low value or waste oil product into a valuable commodity that has utility in improving the transportation properties of heavy oils, particularly in oil field pipeline applications.
COPOLYMERS COMPRISING A-OLEFINS AND OLEFIN DICARBOXYLIC ACID ESTERS, PRODUCTION THEREOF, AND USE THEREOF AS POUR POINT DEPRESSANTS FOR CRUDE OILS, MINERAL OILS, OR MINERAL OIL PRODUCTS
Copolymers comprising C.sub.14 to C.sub.50 olefins and at least two different olefindicarboxylic esters and optionally maleic acid or maleic acid derivatives. The olefindicarboxylic esters are firstly esters with linear C.sub.18- to C.sub.50-alkyl groups and secondly esters with short-chain linear, branched or cyclic alkyl groups, or esters with aromatic groups. The invention further relates to a process for preparing copolymers of this kind and to the use thereof as pour point depressant for crude oil, mineral oil and/or mineral oil products, preferably as pour point depressant for crude oil.
Method for the production of fuel oil
A method making fuel oil from refining residuals. Refining residuals are mixed with a diluent and an additive. Preferred diluents include diesel and reformed naphtha and combinations thereof. The additive is believed to be a cross-linked cyclic anhydride copolymer having an intrinsic viscosity (limiting viscosity, ) of between about 0.10 and 3.0 deciliters per gram and an average molecular weight between about 3,000 and 3,000,000. The additive includes excess aromatic hydrocarbons and a surfactant. In the preferred embodiment, the diluent and the residuals are mixed together in a ratio of about 3:1, by weight. The additive is introduced to this mixture in the amount of about 0.10 to 0.25 percent by weight. The components are thoroughly combined to yield a fuel oil having a viscosity that is about 25 to as much as about 70 percent lower than the viscosity of the same residual/diluent mixture lacking the additive.
METHOD TO IMPROVE THE EFFICIENCY OF PIPELINE TRANSPORTATION OF HEAVY OILS
Disulfide oil (DSO) compounds recovered as a by-product of the mercaptan oxidation of a hydrocarbon refinery feedstock and their oxidized derivatives, oxidized disulfide oils (ODSO) are effective as a diluent to lower the viscosity and thereby improve the pipeline transportation properties of heavy oils, and particularly of wellhead crude oil. The use of the DSO and/or ODSO compounds as diluents converts an otherwise extremely low value or waste oil product into a valuable commodity that has utility in improving the transportation properties of heavy oils, particularly in oil field pipeline applications.
Copolymers comprising a-olefins and olefin dicarboxylic acid esters, production thereof, and use thereof as pour point depressants for crude oils, mineral oils, or mineral oil products
Copolymers comprising C.sub.14 to C.sub.50 olefins and at least two different olefindicarboxylic esters and optionally maleic acid or maleic acid derivatives. The olefindicarboxylic esters are firstly esters with linear C.sub.18- to C.sub.50-alkyl groups and secondly esters with short-chain linear, branched or cyclic alkyl groups, or esters with aromatic groups. The invention further relates to a process for preparing copolymers of this kind and to the use thereof as pour point depressant for crude oil, mineral oil and/or mineral oil products, preferably as pour point depressant for crude oil.