Various liquid and semisolid lubricant compositions are provided, in particular lubricant compositions containing oil from the seeds of the Brassicaceae Orychophragmus violaceus, preferably those that have been esterified with one or more fatty acids such as palmitoleic acid, oleic acid, linoleic acid, lauric acid, palmitic acid, stearic acid, or a combination thereof. In various aspects, lubricant compositions are provided that include a petroleum or a synthetic base oil and about 40% or less by weight of a liquid lubricant composition containing oil from the seeds of the Brassicaceae Orychophragmus violaceus, preferably those that have been esterified with one or more fatty acids. In various aspects, semisolid lubricant composition are provided containing an emulsion of (i) a thickener and (ii) an oil from the seeds of the Brassicaceae Orychophragmus violaceus, preferably those that have been esterified with one or more fatty acids.

The present invention describes a process for obtaining a biolubricant from vegetable oil, which comprises the steps of (a) esterification reaction of the product of vegetable oil hydrolysis using a branched aliphatic alcohol; (b) epoxidation reaction of the esters obtained in step (a); and (c) nucleophilic substitution reaction of the epoxidated esters obtained in step (b) using a branched aliphatic alcohol. The present invention also describes a biolubricant obtained from the process. More specifically, a biolubricant is described that is produced from a ricinoleic fatty acid, whose formula is illustrated in FIG. 1 of the present invention, and where R.sub.1 is a hydroxyl or it is from the formula R.sub.3COO.sup.−, with R.sub.3 being an alkyl radical C.sub.1-C.sub.3, preferably a methyl radical; and R.sub.2 consists of a straight chain of hydrocarbons C.sub.4-C.sub.8 and a branched chain of hydrocarbons C.sub.1-C.sub.3.

The present invention describes a process for obtaining a biolubricant from vegetable oil, which comprises the steps of (a) esterification reaction of the product of vegetable oil hydrolysis using a branched aliphatic alcohol; (b) epoxidation reaction of the esters obtained in step (a); and (c) nucleophilic substitution reaction of the epoxidated esters obtained in step (b) using a branched aliphatic alcohol. The present invention also describes a biolubricant obtained from the process. More specifically, a biolubricant is described that is produced from a ricinoleic fatty acid, whose formula is illustrated in FIG. 1 of the present invention, and where R.sub.1 is a hydroxyl or it is from the formula R.sub.3COO.sup.−, with R.sub.3 being an alkyl radical C.sub.1-C.sub.3, preferably a methyl radical; and R.sub.2 consists of a straight chain of hydrocarbons C.sub.4-C.sub.8 and a branched chain of hydrocarbons C.sub.1-C.sub.3.

Various liquid and semisolid lubricant compositions are provided, in particular lubricant compositions are provided which have been chemically modified to increase a concentration of triacylglyceride estolide content. The estolides can be produced via esterification with one or more fatty acids such as palmitoleic acid, oleic acid, linoleic acid, lauric acid, palmitic acid, stearic acid, or a combination thereof. Both liquid and semisolid lubricant compositions are provided.

The invention relates to ester compounds of the general formula (I)

##STR00001##

to a process for preparation thereof and to the use thereof. These ester compounds may contain a mixture of at least two compounds of the general formula (I).

Various liquid and semisolid lubricant compositions are provided, in particular lubricant compositions containing oil from the seeds of the Brassicaceae Orychophragmus violaceus, preferably those that have been esterified with one or more fatty acids such as palmitoleic acid, oleic acid, linoleic acid, lauric acid, palmitic acid, stearic acid, or a combination thereof. In various aspects, lubricant compositions are provided that include a petroleum or a synthetic base oil and about 40% or less by weight of a liquid lubricant composition containing oil from the seeds of the Brassicaceae Orychophragmus violaceus, preferably those that have been esterified with one or more fatty acids. In various aspects, semisolid lubricant composition are provided containing an emulsion of (i) a thickener and (ii) an oil from the seeds of the Brassicaceae Orychophragmus violaceus, preferably those that have been esterified with one or more fatty acids.

Various liquid and semisolid lubricant compositions are provided, in particular lubricant compositions containing oil from the seeds of the Brassicaceae Orychophragmus violaceus, preferably those that have been esterified with one or more fatty acids such as palmitoleic acid, oleic acid, linoleic acid, lauric acid, palmitic acid, stearic acid, or a combination thereof. In various aspects, lubricant compositions are provided that include a petroleum or a synthetic base oil and about 40% or less by weight of a liquid lubricant composition containing oil from the seeds of the Brassicaceae Orychophragmus violaceus, preferably those that have been esterified with one or more fatty acids. In various aspects, semisolid lubricant composition are provided containing an emulsion of (i) a thickener and (ii) an oil from the seeds of the Brassicaceae Orychophragmus violaceus, preferably those that have been esterified with one or more fatty acids.

The purpose of the present invention is to provide a lubricant composition which can be applied as a gear oil for a high-output and high-speed gear mechanism, and whereby fuel saving as well as further wear resistance in a bearing of a pinion gear can be realized while maintaining excellent durability, seizure resistance, and stability are maintained. A lubricant composition containing a Fischer-Tropsch-derived base oil, a poly alpha-olefin, and an ester compound, and further containing an unsaturated fatty acid and/or a partial ester compound of an unsaturated fatty acid and a polyol, wherein the partial ester compound of an unsaturated fatty acid includes a monoester compound of an unsaturated fatty acid and a polyol in a ratio of 50% by mass with respect to the total amount of the partial ester compound, and the SAE viscosity grade of the lubricant composition is 75W-85 or lower.

The purpose of the present invention is to provide a lubricant composition which can be applied as a gear oil for a high-output and high-speed gear mechanism, and whereby fuel saving as well as further wear resistance in a bearing of a pinion gear can be realized while maintaining excellent durability, seizure resistance, and stability are maintained. A lubricant composition containing a Fischer-Tropsch-derived base oil, a poly alpha-olefin, and an ester compound, and further containing an unsaturated fatty acid and/or a partial ester compound of an unsaturated fatty acid and a polyol, wherein the partial ester compound of an unsaturated fatty acid includes a monoester compound of an unsaturated fatty acid and a polyol in a ratio of 50% by mass with respect to the total amount of the partial ester compound, and the SAE viscosity grade of the lubricant composition is 75W-85 or lower.

The invention relates to novel ester compounds of the general formula (I) ##STR00001##
to a process for preparation thereof and to the use thereof. These ester compounds may contain a mixture of at least two compounds of the general formula (I).