Sustainable lubricant compositions made from recycled thermoplastic polyesters and other reclaimed or biorenewable reactants and a method of formulating them are disclosed. The lubricant compositions comprise a polyester base oil, which incorporates recurring units from a digested thermoplastic polyester, a low-molecular-weight polyol, and C.sub.8-C.sub.24 fatty acid. The base oil has a number-average molecular weight within the range of 300 to 5000 g/mol, a hydroxyl value less than 50 mg KOH/g, and a viscosity at 40 C. less than 5000 cSt. Some of the lubricant compositions comprise the polyester base oil and one or more additives including anti-wear agents, corrosion inhibitors, antioxidants, thickeners, detergents, and the like. The lubricants have properties that rival those of commercial products made from nonrenewable hydrocarbon blends or polyol esters and are useful for many practical applications such as internal combustion engine oils, gear lubrication oils, hydraulic oils, compressor oils, metal working fluids, and lubricating greases.

Sustainable lubricant compositions made from recycled thermoplastic polyesters and other reclaimed or biorenewable reactants and a method of formulating them are disclosed. The lubricant compositions comprise a polyester base oil, which incorporates recurring units from a digested thermoplastic polyester, a low-molecular-weight polyol, and C.sub.8-C.sub.24 fatty acid. The base oil has a number-average molecular weight within the range of 300 to 5000 g/mol, a hydroxyl value less than 50 mg KOH/g, and a viscosity at 40 C. less than 5000 cSt. Some of the lubricant compositions comprise the polyester base oil and one or more additives including anti-wear agents, corrosion inhibitors, antioxidants, thickeners, detergents, and the like. The lubricants have properties that rival those of commercial products made from nonrenewable hydrocarbon blends or polyol esters and are useful for many practical applications such as internal combustion engine oils, gear lubrication oils, hydraulic oils, compressor oils, metal working fluids, and lubricating greases.

A lubricant base oil composed of an ester. The ester includes a component (A) derived from trimethylolpropane in a molar percentage A.sub.mol% of 25 to 42 mol %; components (B) derived from monovalent straight-chain saturated fatty acids each having a carbon number of 8 to 12 in a molar percentage B.sub.mol% of 33 to 55 mol %: and a component (C) derived from adipic acid in a molar ratio C.sub.mol% of 12 to 34 mol %. The components (B) include lauric acid in a molar percentage of 5 to 50 mol %, and (B.sub.COOH+C.sub.COOH)/A.sub.OH is 0.90 to 1.02. A.sub.OH represents a hydroxyl equivalent of the component (A), B.sub.COOH represents a carboxyl group equivalent of the components (B); and C.sub.COOH represents a carboxyl group equivalent of the component (C).

A lubricant base oil composed of an ester. The ester includes a component (A) derived from trimethylolpropane in a molar percentage A.sub.mol% of 25 to 42 mol %; components (B) derived from monovalent straight-chain saturated fatty acids each having a carbon number of 8 to 12 in a molar percentage B.sub.mol% of 33 to 55 mol %: and a component (C) derived from adipic acid in a molar ratio C.sub.mol% of 12 to 34 mol %. The components (B) include lauric acid in a molar percentage of 5 to 50 mol %, and (B.sub.COOH+C.sub.COOH)/A.sub.OH is 0.90 to 1.02. A.sub.OH represents a hydroxyl equivalent of the component (A), B.sub.COOH represents a carboxyl group equivalent of the components (B); and C.sub.COOH represents a carboxyl group equivalent of the component (C).

This application relates to branched diester compositions that can be used as a base stock for lubricant applications, or as a base stock blend component for use in a finished lubricant or for particular applications, and methods for making the same.

This application relates to branched diester compositions that can be used as a base stock for lubricant applications, or as a base stock blend component for use in a finished lubricant or for particular applications, and methods for making the same.

Levulinic-capped estolides having improved physical properties that make them more desirable and suitable as bio-based industrial or commercial products are disclosed. The physical properties of the disclosed estolide compositions have surprisingly low pour points that are substantially lower than previously known estolide compounds and superior to petroleum-based compounds designed for similar applications.

Provided herein are compositions comprising at least one estolide compound of formula: ##STR00001##
in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R.sub.1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R.sub.2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R.sub.3 and R.sub.4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided are uses of the compositions described herein.

Provided herein are compositions comprising at least one estolide compound of formula: ##STR00001##
in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R.sub.1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R.sub.2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R.sub.3 and R.sub.4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided are uses of the compositions described herein.

The invention refers to use of lubricant compositions comprising a specific diester and additives to reduce the fuel consumption of an engine.