An additive package is disclosed for preparing an automotive crankcase lubricating oil composition for an internal combustion engine. The additive package is made by admixing: (i) 50 mass % or less of an oil of lubricating viscosity; (ii) 50 mass % or less of at least one overbased metal detergent, preferably at least one overbased metal hydroxybenzoate detergent; (iii) 50 mass % or less of an oil-soluble block or graft co-polymer of at to least one polymeric block A which is derived from a hydroxycarboxylic acid and at least one polyalkylene block B which is a residue of a polyalkylene glycol, and (iv) optionally, at least one further additive selected from a dispersant, an antioxidant and/or an antiwear agent.

The additive package includes less than 2.00 mass % preferably less than 1.50 mass %, of a friction modifier which is a monoester of a C.sub.5 to C.sub.30 carboxylic acid and which is free of nitrogen.

Component (ii) is preferably an overbased metal hydroxybenzoate detergent.

Component (iii) acts as a friction modifier and can be used as a replacement for a friction modifier such as glycerol monooleate.

The additive package exhibits improved stability.

Some examples of producing water-based drilling fluids including ecofriendly lubricating additives are described. A raw material oil including fatty acids with a short chain alcohol is esterified in the presence of a catalyst to produce alkyl ester products and triglycerides. The alkyl ester products are washed and heated to remove any residual water or the short chain alcohol. A first quantity of the alkyl ester products is mixed with a second quantity of a water-based wellbore drilling fluid.

Some examples of producing water-based drilling fluids including ecofriendly lubricating additives are described. A raw material oil including fatty acids with a short chain alcohol is esterified in the presence of a catalyst to produce alkyl ester products and triglycerides. The alkyl ester products are washed and heated to remove any residual water or the short chain alcohol. A first quantity of the alkyl ester products is mixed with a second quantity of a water-based wellbore drilling fluid.

The use as an anti-wear additive and/or friction modifier in a non-aqueous lubricant composition and/or in a fuel composition of at least one long chain fatty acid ester of a hydroxy carboxylic acid in which the long chain fatty acid has at least 4 carbon atoms and the ester is an oil-soluble ester of a mono- or poly-hydroxy carboxylic acid having 1 to 4 groups which are independently carboxylic acid groups or lower hydrocarbyl esters thereof and in which, when the hydroxy carboxylic acid is a mono-hydroxy carboxylic acid, the ester has a long chain fatty acid ester moiety of the hydroxy group of the hydroxy carboxylic acid and, when the hydroxy carboxylic acid is a poly-hydroxy carboxylic acid, the ester has independently long chain fatty acid ester moieties of one or two of the hydroxy groups of the poly-hydroxy carboxylic acid. Also, a non-aqueous lubricant composition and a fuel composition for an internal combustion engine which comprises at least one of said long chain fatty acid esters.

The use as an anti-wear additive and/or friction modifier in a non-aqueous lubricant composition and/or in a fuel composition of at least one long chain fatty acid ester of a hydroxy carboxylic acid in which the long chain fatty acid has at least 4 carbon atoms and the ester is an oil-soluble ester of a mono- or poly-hydroxy carboxylic acid having 1 to 4 groups which are independently carboxylic acid groups or lower hydrocarbyl esters thereof and in which, when the hydroxy carboxylic acid is a mono-hydroxy carboxylic acid, the ester has a long chain fatty acid ester moiety of the hydroxy group of the hydroxy carboxylic acid and, when the hydroxy carboxylic acid is a poly-hydroxy carboxylic acid, the ester has independently long chain fatty acid ester moieties of one or two of the hydroxy groups of the poly-hydroxy carboxylic acid. Also, a non-aqueous lubricant composition and a fuel composition for an internal combustion engine which comprises at least one of said long chain fatty acid esters.

The present invention is toward a base oil or lubricant additives, methods of using the same, lubricant compositions including the same, and methods of forming the lubricant compositions. A base oil or lubricant additive has Structure I or Structure II as described herein.

The present invention is toward a base oil or lubricant additives, methods of using the same, lubricant compositions including the same, and methods of forming the lubricant compositions. A base oil or lubricant additive has Structure I or Structure II as described herein.

A mixture of alkylesters of fatty acids is provided, wherein the fatty acids have the following composition: at least 56% of saturated C12 chains, at least 23% of saturated C14 chains, at most 8% of saturated C16 chains, at most 5% of saturated C6-10 chains, at most 5% of monounsaturated C18 chains, at most 2% of saturated C18 chains, at most 0.8% of diunsaturated C18 chains, and at most 0.2% of saturated C20 chains. The percentages are an average percentage expressed in number of moles per total number of moles of alkylesters, and the use of these mixtures is as a viscosity agent.

A mixture of alkylesters of fatty acids is provided, wherein the fatty acids have the following composition: at least 56% of saturated C12 chains, at least 23% of saturated C14 chains, at most 8% of saturated C16 chains, at most 5% of saturated C6-10 chains, at most 5% of monounsaturated C18 chains, at most 2% of saturated C18 chains, at most 0.8% of diunsaturated C18 chains, and at most 0.2% of saturated C20 chains. The percentages are an average percentage expressed in number of moles per total number of moles of alkylesters, and the use of these mixtures is as a viscosity agent.

The invention provides a lubricating composition containing an aromatic compound and an oil of lubricating viscosity. The invention further relates to the use of the lubricating composition in an internal combustion engine. The invention further relates to the use of the aromatic compound as an antiwear agent.