This disclosure describes an ashless lubricant additive. The additive is a tertiary amine-containing compound having the following structure:

##STR00001##

where each R.sup.1 and R.sup.5 is independently a linear or branched-chain monovalent hydrocarbyl group having two to about twenty carbon atoms, where each R.sup.2, R.sup.3, and R.sup.4 is independently a hydrogen, a linear or branched-chain monovalent hydrocarbyl group having one to about twenty carbon atoms wherein at least one of R.sup.2, R.sup.3, and R.sup.4 is hydrogen, each m is independently from 0 to 2, each p is independently from 0 to 2, for each cylic moiety m+p is from 2 to 4, and each n is independently from 1 to 6.

This disclosure describes an ashless lubricant additive. The additive is a tertiary amine-containing compound having the following structure:

##STR00001##

where each R.sup.1 and R.sup.5 is independently a linear or branched-chain monovalent hydrocarbyl group having two to about twenty carbon atoms, where each R.sup.2, R.sup.3, and R.sup.4 is independently a hydrogen, a linear or branched-chain monovalent hydrocarbyl group having one to about twenty carbon atoms wherein at least one of R.sup.2, R.sup.3, and R.sup.4 is hydrogen, each m is independently from 0 to 2, each p is independently from 0 to 2, for each cylic moiety m+p is from 2 to 4, and each n is independently from 1 to 6.

New ashless TBN molecules are synthesized, and lubricant compositions containing them, boost the total base number. The lubricant compositions further tested for ASTM D6594 copper corrosion test meets ASTM limits.

New ashless TBN molecules are synthesized, and lubricant compositions containing them, boost the total base number. The lubricant compositions further tested for ASTM D6594 copper corrosion test meets ASTM limits.

New ashless TBN molecules are synthesized, and lubricant compositions containing them, boost the total base number. The lubricant compositions further tested for ASTM D6594 copper corrosion test meets ASTM limits.

New ashless TBN molecules are synthesized, and lubricant compositions containing them, boost the total base number. The lubricant compositions further tested for ASTM D6594 copper corrosion test meets ASTM limits.

A lubricant composition for a compression-ignition internal combustion engine includes an amine and a detergent selected from metal sulfonates, phenates, salicylates, carboxylates, thiophosphonates, and combinations thereof. The lubricant composition has a TBN of from about 10 to about 100 mg KOH/g when tested according to ASTM D2896. The amine contributes from about 0.1 to about 28% of the TBN of the lubricant composition. Further, a method of lubricating an internal combustion engine with the lubricant composition includes the steps of injecting a fuel and the lubricant composition into a cylinder to form a mixture, and combusting the mixture via compression-ignition.

A lubricant composition for a compression-ignition internal combustion engine includes an amine and a detergent selected from metal sulfonates, phenates, salicylates, carboxylates, thiophosphonates, and combinations thereof. The lubricant composition has a TBN of from about 10 to about 100 mg KOH/g when tested according to ASTM D2896. The amine contributes from about 0.1 to about 28% of the TBN of the lubricant composition. Further, a method of lubricating an internal combustion engine with the lubricant composition includes the steps of injecting a fuel and the lubricant composition into a cylinder to form a mixture, and combusting the mixture via compression-ignition.

A process to prepare an ethylene-based polymer, said process comprising polymerizing a mixture comprising ethylene, at a pressure greater than, or equal to, 100 MPa, in the presence of at least one free-radical initiator; and in a reactor system comprising at least one reactor and at least one Hyper-compressor, and wherein at least one oil formulation, optionally comprising one or more lubrication agents, is added to the Hyper-compressor; and wherein at least one of the following steps takes place: A) thermally treating the one or more lubrication agents, in an oxygen-free atmosphere, to achieve a peroxide level ≤10 ppm, based on the weight of the lubrication agent(s), and then adding said agent(s) to the oil formulation, prior to adding the oil formulation to the Hyper-compressor; or B) thermally treating the oil formulation, in an oxygen-free atmosphere, to achieve a peroxide level ≤10 ppm, based on the weight of the oil formulation, prior to adding the oil formulation to the Hyper-compressor; C) a combination of A and B.

A process to prepare an ethylene-based polymer, said process comprising polymerizing a mixture comprising ethylene, at a pressure greater than, or equal to, 100 MPa, in the presence of at least one free-radical initiator; and in a reactor system comprising at least one reactor and at least one Hyper-compressor, and wherein at least one oil formulation, optionally comprising one or more lubrication agents, is added to the Hyper-compressor; and wherein at least one of the following steps takes place: A) thermally treating the one or more lubrication agents, in an oxygen-free atmosphere, to achieve a peroxide level ≤10 ppm, based on the weight of the lubrication agent(s), and then adding said agent(s) to the oil formulation, prior to adding the oil formulation to the Hyper-compressor; or B) thermally treating the oil formulation, in an oxygen-free atmosphere, to achieve a peroxide level ≤10 ppm, based on the weight of the oil formulation, prior to adding the oil formulation to the Hyper-compressor; C) a combination of A and B.