C10M135/18

Lubricating oils and greases

A lubricating oil composition comprises an amide and at least one additive. A lubricating grease composition comprises a liquid amide, a thickener comprising a metal soap, and at least one additive. The amide in each composition is the reaction product of a secondary, branched amine and a carboxylic acid. The carboxylic acid may be a monocarboxylic acid or a dicarboxylic acid, including dimer acid. The amide is hydrolytically stable, and may be used to increase the hydrolytic stability of the lubricant oil or grease composition. Alternatively, the amide may be used to increase the additive solubility or detergency of the lubricant oil or grease composition.

GREASE COMPOSITION FOR A CONSTANT-VELOCITY JOINT

A grease composition for a constant-velocity joint includes a mineral oil, a thickener, a molybdenum dithiocarbamate, a potassium borate hydrate, and a zinc dialkyldithiophosphate, wherein a content of the molybdenum dithiocarbamate is 1.2% by mass or more and 8% by mass or less, a content of the zinc dialkyldithiophosphate is 0.3% by mass or more and 2.0% by mass or less, and a content of the potassium borate hydrate is 0.28% by mass or more and 1.9% by mass or less, and wherein a mass ratio of the content of the molybdenum dithiocarbamate to the content of the potassium borate hydrate (molybdenum dithiocarbamate/potassium borate hydrate) is 2 or more and 13 or less, and a mass ratio of the content of the zinc dialkyldithiophosphate to the content of the potassium borate hydrate (zinc dialkyldithiophosphate/potassium borate hydrate) is 0.5 or more and 3.6 or less.

GREASE COMPOSITION FOR A CONSTANT-VELOCITY JOINT

A grease composition for a constant-velocity joint includes a mineral oil, a thickener, a molybdenum dithiocarbamate, a potassium borate hydrate, and a zinc dialkyldithiophosphate, wherein a content of the molybdenum dithiocarbamate is 1.2% by mass or more and 8% by mass or less, a content of the zinc dialkyldithiophosphate is 0.3% by mass or more and 2.0% by mass or less, and a content of the potassium borate hydrate is 0.28% by mass or more and 1.9% by mass or less, and wherein a mass ratio of the content of the molybdenum dithiocarbamate to the content of the potassium borate hydrate (molybdenum dithiocarbamate/potassium borate hydrate) is 2 or more and 13 or less, and a mass ratio of the content of the zinc dialkyldithiophosphate to the content of the potassium borate hydrate (zinc dialkyldithiophosphate/potassium borate hydrate) is 0.5 or more and 3.6 or less.

ELECTRIC VEHICLE GREASE
20230332066 · 2023-10-19 ·

A lubricating grease for electric vehicle applications includes thickener 6% by weight (wt. %) to 12 wt. %, lubricating oil 57 wt. % to 92.98 wt. %, and surface-active ester 1 wt. % to 10 wt. %. The lubricating grease also includes additives including friction reducer and modifier 0.1 wt. % to 5 wt. %, anti-wear agent 0.1 wt. % to 5 wt. %, and a balance of extreme pressure agent, oxidation inhibitor, and corrosion inhibitor.

ELECTRIC VEHICLE GREASE
20230332066 · 2023-10-19 ·

A lubricating grease for electric vehicle applications includes thickener 6% by weight (wt. %) to 12 wt. %, lubricating oil 57 wt. % to 92.98 wt. %, and surface-active ester 1 wt. % to 10 wt. %. The lubricating grease also includes additives including friction reducer and modifier 0.1 wt. % to 5 wt. %, anti-wear agent 0.1 wt. % to 5 wt. %, and a balance of extreme pressure agent, oxidation inhibitor, and corrosion inhibitor.

FRICTION MODIFIER SYSTEM

This disclosure describes a lubricant additive. The additive is a friction modifier that includes a molybdenum containing compound and a tertiary amine-containing composition having the following structure:

##STR00001##

wherein each R.sup.1 and R.sup.5 is independently a linear or branched-chain monovalent hydrocarbyl group having one to about twenty carbon atoms, wherein each R.sup.2, R.sup.3, and R.sup.4 is independently a hydrogen, a linear or branched-chain monovalent hydrocarbyl group having one to about twenty carbon atoms, each m is independently from 0 and 4, each p is independently from 0 and 4, for each cyclic moiety m+p is from 2 and 4, and each n is independently from 1 and 6.

FRICTION MODIFIER SYSTEM

This disclosure describes a lubricant additive. The additive is a friction modifier that includes a molybdenum containing compound and a tertiary amine-containing composition having the following structure:

##STR00001##

wherein each R.sup.1 and R.sup.5 is independently a linear or branched-chain monovalent hydrocarbyl group having one to about twenty carbon atoms, wherein each R.sup.2, R.sup.3, and R.sup.4 is independently a hydrogen, a linear or branched-chain monovalent hydrocarbyl group having one to about twenty carbon atoms, each m is independently from 0 and 4, each p is independently from 0 and 4, for each cyclic moiety m+p is from 2 and 4, and each n is independently from 1 and 6.

Lubricating oil additive and lubricating oil composition containing same

The present invention provides a lubricating oil additive, including: a molybdenum compound (A) represented by the following general formula (1); and a sulfur-based composition (B) containing a sulfur-based compound (b-1) represented by the following general formula (2) and at least one kind of sulfur-based compound (b-2) represented by the following general formula (3) or (4), and a lubricating oil composition containing the additive. In the formula (1), R.sup.1 to R.sup.4 each represent alkyl groups having 6 to 18 carbon atoms, the groups being identical to or different from each other, and X.sup.1 to X.sup.4 each independently represent an oxygen atom or a sulfur atom. In the formula (2), R.sup.5 represents an alkyl group having 1 to 22 carbon atoms, R.sup.6 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, R.sup.7 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, and “a” represents a number from 1 to 10. In the formulae (3) and (4), R.sup.8 to R.sup.11 each represent alkylene groups having 1 to 28 carbon atoms, the groups being identical to or different from each other, R.sup.12 and R.sup.13 each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and “b” and “c” each independently represent a number from 1 to 8, provided that at least one of R.sup.12 or R.sup.13 represents an alkyl group having 1 to 3 carbon atoms. ##STR00001##

Lubricating oil additive and lubricating oil composition containing same

The present invention provides a lubricating oil additive, including: a molybdenum compound (A) represented by the following general formula (1); and a sulfur-based composition (B) containing a sulfur-based compound (b-1) represented by the following general formula (2) and at least one kind of sulfur-based compound (b-2) represented by the following general formula (3) or (4), and a lubricating oil composition containing the additive. In the formula (1), R.sup.1 to R.sup.4 each represent alkyl groups having 6 to 18 carbon atoms, the groups being identical to or different from each other, and X.sup.1 to X.sup.4 each independently represent an oxygen atom or a sulfur atom. In the formula (2), R.sup.5 represents an alkyl group having 1 to 22 carbon atoms, R.sup.6 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, R.sup.7 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, and “a” represents a number from 1 to 10. In the formulae (3) and (4), R.sup.8 to R.sup.11 each represent alkylene groups having 1 to 28 carbon atoms, the groups being identical to or different from each other, R.sup.12 and R.sup.13 each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and “b” and “c” each independently represent a number from 1 to 8, provided that at least one of R.sup.12 or R.sup.13 represents an alkyl group having 1 to 3 carbon atoms. ##STR00001##

ENGINE OIL FORMULATIONS FOR LOW TIMING CHAIN STRETCH

A lubricating oil composition and method for controlling timing chain stretch, wherein the composition contains greater than 50 wt. % of base oil, zinc dialkyl dithiophosphate(s) to provide 350-2200 ppm zinc, molybdenum-containing compound(s) to provide >1-3000 ppm molybdenum, and magnesium-containing detergent(s) to provide <2050 ppm magnesium, all based on the total weight of the composition. The composition has a total TBN of less than 7.5 mg KOH/g, measured by ASTM D-2896 and a weight ratio of ppm of zinc from zinc dialkyl dithiophosphate(s) to ppm of molybdenum from molybdenum-containing compound(s) of <10. The method employs the lubricating oil composition to control timing chain stretch to a level of 0.1% or less.