Provided herein are polyolefin dispersants, as well as methods for producing polyolefin dispersants. The polyolefin dispersants can be defined by the formula below

##STR00001##

where R.sup.x is cationic initiator residue; R.sup.a is a polyolefin group; R.sup.1 and R.sup.2 are each, independently in each (CR.sup.1R.sup.2) unit, H, alkyl, alkoxy, or alkylaryl; R.sup.3 and R.sup.4 are each, independently, H, alkyl, or alkoxy; m is an integer from 1 to 20; n is an integer from 1 to 6; r is an integer from 1 to 4; Y is a polyvalent amine linker comprising one or more tertiary amines, wherein the polyvalent amine linker does not include a primary amine or a secondary amine; and A is absent, or comprises a dispersive moiety.

Provided herein are polyolefin dispersants, as well as methods for producing polyolefin dispersants. The polyolefin dispersants can be defined by the formula below

##STR00001##

where R.sup.x is cationic initiator residue; R.sup.a is a polyolefin group; R.sup.1 and R.sup.2 are each, independently in each (CR.sup.1R.sup.2) unit, H, alkyl, alkoxy, or alkylaryl; R.sup.3 and R.sup.4 are each, independently, H, alkyl, or alkoxy; m is an integer from 1 to 20; n is an integer from 1 to 6; r is an integer from 1 to 4; Y is a polyvalent amine linker comprising one or more tertiary amines, wherein the polyvalent amine linker does not include a primary amine or a secondary amine; and A is absent, or comprises a dispersive moiety.

An oleaginous nanoparticle dispersion of nanoparticles having a core of an organic base material immobilized within a surfactant layer, the use thereof as a low ash, or ash-free source of TBN in lubricating oil compositions, and lubricating oil compositions formulated with such oleaginous nanoparticle dispersions.

An oleaginous nanoparticle dispersion of nanoparticles having a core of an organic base material immobilized within a surfactant layer, the use thereof as a low ash, or ash-free source of TBN in lubricating oil compositions, and lubricating oil compositions formulated with such oleaginous nanoparticle dispersions.

An antioxidant polymer (e.g., oligomer) composition comprising repeat units of diphenylamine monomers of formula I

##STR00001##

wherein R is H, C.sub.1-C.sub.18 alkyl, C.sub.2-C.sub.18 alkenyl, C.sub.2-C.sub.18 alkynyl, C(O)C.sub.1-C.sub.18 alkyl, C(O)aryl and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently H or a linear or branched C.sub.1-C.sub.18 alkyl, C.sub.1-C.sub.18 alkoxy, C.sub.1-C.sub.18 alkylamino, C.sub.1-C.sub.18 dialkylamino, C.sub.1-C.sub.18 alkylthio, C.sub.2-C.sub.18 alkenyl, C.sub.2-C.sub.18 alkynyl or C.sub.7-C.sub.21 aralkyl and wherein the number average molecular weight (Mn) of the polymer is from about 350 g/mol to about 5000 g/mol are highly effective antioxidants in lubricant compositions. The polymer compositions may be prepared by a process comprising subjecting diarylamine monomers to dehydrocondensation conditions.

An antioxidant polymer (e.g., oligomer) composition comprising repeat units of diphenylamine monomers of formula I

##STR00001##

wherein R is H, C.sub.1-C.sub.18 alkyl, C.sub.2-C.sub.18 alkenyl, C.sub.2-C.sub.18 alkynyl, C(O)C.sub.1-C.sub.18 alkyl, C(O)aryl and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently H or a linear or branched C.sub.1-C.sub.18 alkyl, C.sub.1-C.sub.18 alkoxy, C.sub.1-C.sub.18 alkylamino, C.sub.1-C.sub.18 dialkylamino, C.sub.1-C.sub.18 alkylthio, C.sub.2-C.sub.18 alkenyl, C.sub.2-C.sub.18 alkynyl or C.sub.7-C.sub.21 aralkyl and wherein the number average molecular weight (Mn) of the polymer is from about 350 g/mol to about 5000 g/mol are highly effective antioxidants in lubricant compositions. The polymer compositions may be prepared by a process comprising subjecting diarylamine monomers to dehydrocondensation conditions.

Disclosed in certain embodiments is a lubricating oil composition comprising an antioxidant polymer (e.g., oligomer) composition comprising repeat units of diphenylamine monomers of formula I

##STR00001## wherein R is H, C.sub.1-C.sub.18 alkyl, C.sub.2-C.sub.18 alkenyl, C.sub.2-C.sub.18 alkynyl, C(O)C.sub.1-C.sub.18 alkyl, C(O)aryl and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently H or a linear or branched C.sub.1-C.sub.18 alkyl, C.sub.1-C.sub.18 alkoxy, C.sub.1-C.sub.18 alkylamino, C.sub.1-C.sub.18 dialkylamino, C.sub.1-C.sub.18 alkylthio, C.sub.2-C.sub.18 alkenyl, C.sub.2-C.sub.18 alkynyl or C.sub.7-C.sub.21 aralkyl and wherein the number average molecular weight (Mn) of the polymer composition is from about 350 g/mol to about 5000 g/mol.

Disclosed in certain embodiments is a lubricating oil composition comprising an antioxidant polymer (e.g., oligomer) composition comprising repeat units of diphenylamine monomers of formula I

##STR00001## wherein R is H, C.sub.1-C.sub.18 alkyl, C.sub.2-C.sub.18 alkenyl, C.sub.2-C.sub.18 alkynyl, C(O)C.sub.1-C.sub.18 alkyl, C(O)aryl and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently H or a linear or branched C.sub.1-C.sub.18 alkyl, C.sub.1-C.sub.18 alkoxy, C.sub.1-C.sub.18 alkylamino, C.sub.1-C.sub.18 dialkylamino, C.sub.1-C.sub.18 alkylthio, C.sub.2-C.sub.18 alkenyl, C.sub.2-C.sub.18 alkynyl or C.sub.7-C.sub.21 aralkyl and wherein the number average molecular weight (Mn) of the polymer composition is from about 350 g/mol to about 5000 g/mol.

This patent relates to a lubricating oil with added decorated graphene nanoparticles, which is called nanolubricant. This nanolubricant has automotive and industrial applications and offers as major benefits, simultaneous improvements in the thermal, rheological and tribological properties of the lubricant used as base fluid. Additionally, this nanolubricant offers a rheopectic behavior from a specific concentration, the same behavior that gives it the ability to increase its viscosity over time provided it is subjected to a constant cutting rate. Finally, the decorated graphene may include metallic, ceramic or polymeric nanoparticles, in a concentration range of 0.5% weight/weight to 2% w/w without changing the newtonian fluid behavior of the base lubricant, whereas for concentrations greater than 2% weight/weight and up to 3% weight/weight, the aforementioned rheopectic behavior will be observed.

This patent relates to a lubricating oil with added decorated graphene nanoparticles, which is called nanolubricant. This nanolubricant has automotive and industrial applications and offers as major benefits, simultaneous improvements in the thermal, rheological and tribological properties of the lubricant used as base fluid. Additionally, this nanolubricant offers a rheopectic behavior from a specific concentration, the same behavior that gives it the ability to increase its viscosity over time provided it is subjected to a constant cutting rate. Finally, the decorated graphene may include metallic, ceramic or polymeric nanoparticles, in a concentration range of 0.5% weight/weight to 2% w/w without changing the newtonian fluid behavior of the base lubricant, whereas for concentrations greater than 2% weight/weight and up to 3% weight/weight, the aforementioned rheopectic behavior will be observed.